{"id":19483,"date":"2018-11-22T11:51:30","date_gmt":"2018-11-22T08:51:30","guid":{"rendered":"http:\/\/ihcoedu.uobaghdad.edu.iq\/?p=19483"},"modified":"2018-11-25T11:22:46","modified_gmt":"2018-11-25T08:22:46","slug":"%d9%85%d9%86%d8%a7%d9%82%d8%b4%d8%a9-%d8%b1%d8%b3%d8%a7%d9%84%d8%a9-%d8%b7%d8%a7%d9%84%d8%a8%d8%a9-%d8%a7%d9%84%d9%85%d8%a7%d8%ac%d8%b3%d8%aa%d9%8a%d8%b1-%d9%84%d9%85%d9%89-%d9%85%d8%b5%d8%b9%d8%a8","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=19483","title":{"rendered":"\u0645\u0646\u0627\u0642\u0634\u0629 \u0631\u0633\u0627\u0644\u0629 \u0637\u0627\u0644\u0628\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0644\u0645\u0649 \u0645\u0635\u0639\u0628 \u0639\u0628\u062f \u0645\u0646 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621"},"content":{"rendered":"

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\"\"<\/span><\/h4>\n
\n

 <\/p>\n

The MSc thesis discussion of student Luma Mousa’ab Abid from department of Chemistry<\/span><\/h3>\n

At the hall f the late prof.Dr.Salim Abdulhameed, the MSc thesis discussion of student Luma Mousa’ab Abid from department of Chemistry entitled (physical properties study of compounds which have ability to Removal of heavy ions from The solutions) has been discussed<\/span><\/h3>\n

The discussion committee<\/span><\/h3>\n

Prof.Dr.Ahmed Najim Abid\u00a0\u00a0\u00a0\u00a0 Haed<\/span><\/h3>\n

Asst.prof.Dr.Akram Raheem Jabur\u00a0\u00a0\u00a0 member<\/span><\/h3>\n

Asst.prof.Dr.Amar Jasim Al-Zaidi\u00a0\u00a0\u00a0 member<\/span><\/h3>\n

Asst.pof.Dr.Entisar Olawi Luabi\u00a0\u00a0\u00a0 supervisor member<\/span><\/h3>\n

The Abstract<\/span><\/h3>\n

\u00a0This study deals with the MNPs were synthesized by co-precipitation method\u00a0 of ferric and ferrous ions in alkaline solution.Different amounts of dextrin were selected to functionalize the MNPs .The samples were characterized by several techniques: XRD, FTIR,\u00a0 AFM, and SEM.The study of the adsorption of the methylene blue dye on the coated magnetite with weight ratio of dextrin(1-2),(1-4),(1-8) as to determine the effectiveness of these surfaces and the possibility of using them as adsorbents in order to treat such contamination. UV-vis spectroscopy was used to determination of adsorption capacities. Isotherms of adsorption were studied at different conditions of temperature, pH, weight of adsorbent and weight of dextrin in adsorbents. This study exhibited the following results:The shapes of isotherms , shows that the methyl green dye on all surfaces follows the Langmayer and freundlish equations in all conditions, and the curved type (S) according to Giles classification. This type of isotherms is achieved in the case of heterogeneous surfaces. factors coated magnetite with weight ratio of dextrin(1-8) as surface showed higher ability from other surfaces\u00a0 for methyl green adsorption. This arrangement did not change in efficacy as the conditions of the adsorption process changed. Depending \u00a0on the increase in the amount of the adsorb ate with increasing concentration or temperature. The study of the adsorption process at different temperatures (318,308,283) K, the results showed that the amount of adsorption of methyl green dye on the above increased by increasing the temperature ( the processes are endothermic ).By adsorption isotherms, the change in the basic thermodynamic values of the adsorption process, such as the Enthalpy (\u2206H), was positive, indicating that the adsorption process is endothermic, while the (\u2206G) is negative, indicating the spontaneous adsorption process\u00a0 and the Entropy (\u2206S) was positive, indicating the irregularity of adsorption processes on all surfaces under study. The study of the adsorption of the heavy metals like lead and chrome from aqueous solution on the coated magnetite with weight ratio of dextrin(1-2), as<\/span><\/h3>\n

\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 to determine the effectiveness of this\u00a0 surface and the possibility of using it as adsorbent in order to treat such contamination. Atomic analysis spectroscopy was used to determination of adsorption capacities. Isotherms of adsorption were studied at different conditions of temperature, pH, and weight of adsorbents. This study exhibited the following results: The shapes of isotherms, shows that the heavy metals (lead and chrome ions) from aqueous solution on all surfaces follows the Langmayer and freundlish equations in all conditions, and the curved type (S) according to Giles classification. This type of isotherms is achieved in the case of heterogeneous surfaces. The data obtained from this study revealed that higher efficiency was observed with lead ion whereas the lower with chrome ion. The study of the adsorption process at different temperatures (318,308,298) K, the results showed that the amount of adsorption of the heavy metals (lead and chrome ions) on the above increased by increasing the temperature ( the processes are endothermic\u00a0<\/span><\/h3>\n

\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 By adsorption isotherms, the change in the basic thermodynamic values of the lead ions adsorption process, such as the Enthalpy (\u2206H), was positive, indicating that the adsorption process is endothermic, the (\u2206G) is negative, indicating the spontaneous adsorption process\u00a0 and the Entropy (\u2206S) was negative, indicating the irregularity of adsorption processes on above surface. By adsorption isotherms, while the change in the basic thermodynamic values of the chrome\u00a0 ions adsorption process, the Enthalpy (\u2206H), was positive, indicating that the adsorption process is endothermic, the (\u2206G) is positive, indicating the non- spontaneous adsorption process\u00a0 and the Entropy (\u2206S) was positive, indicating the regularity of adsorption processes on above surface. As the pH of the solution increases, the amount of adsorption of two ions on the coated magnetite with weight ratio of dextrin (1-2) as surface adsorbent\u00a0 \u00a0are<\/span>\u00a0increased<\/span><\/h3>\n","protected":false},"excerpt":{"rendered":"

\u062c\u0631\u062a \u0639\u0644\u0649 \u00a0\u0642\u0627\u0639\u0629 \u0627\u0644\u0645\u0631\u062d\u0648\u0645 \u0627\u0644\u0627\u0633\u062a\u0627\u0630 \u0633\u0627\u0644\u0645 \u0639\u0628\u062f\u0627\u0644\u062d\u0645\u064a\u062f \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u0639\u0644\u0646\u064a\u0629 \u0644\u0631\u0633\u0627\u0644\u0629 \u0637\u0627\u0644\u0628\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0644\u0645\u0649 \u0645\u0635\u0639\u0628 \u0639\u0628\u062f\u00a0 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 : \u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062e\u0648\u0627\u0635 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":19484,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-19483","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/19483","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=19483"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/19483\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/19484"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=19483"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=19483"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=19483"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}