{"id":23877,"date":"2019-02-22T11:40:22","date_gmt":"2019-02-22T08:40:22","guid":{"rendered":"http:\/\/ihcoedu.uobaghdad.edu.iq\/?p=23877"},"modified":"2019-02-26T10:25:59","modified_gmt":"2019-02-26T07:25:59","slug":"%d8%a7%d8%b7%d8%b1%d9%88%d8%ad%d8%a9-%d8%af%d9%83%d8%aa%d9%88%d8%b1%d8%a7%d9%87-%d9%81%d9%8a-%d9%82%d8%b3%d9%85-%d8%a7%d9%84%d9%83%d9%8a%d9%85%d9%8a%d8%a7%d8%a1-%d8%aa%d8%a8%d8%ad%d8%ab-%d9%81%d9%8a","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=23877","title":{"rendered":"\u0627\u0637\u0631\u0648\u062d\u0629 \u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0641\u064a \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u062a\u0628\u062d\u062b \u0641\u064a ” \u062a\u062d\u0636\u064a\u0631 \u0648 \u062a\u0634\u062e\u064a\u0635 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0641\u0644\u0632\u064a\u0629 \u0645\u062e\u062a\u0644\u0637\u0629 \u0644\u0639\u062f\u062f \u0645\u0646 \u0627\u0644\u0623\u062f\u0648\u064a\u0629”"},"content":{"rendered":"

\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 ” \u062a\u062d\u0636\u064a\u0631\u060c\u062a\u0634\u062e\u064a\u0635 \u0648\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0641\u0644\u0632\u064a\u0629 \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639 \u0642\u0648\u0627\u0639\u062f \u0634\u0641 \u0644\u0644\u0623\u062f\u0648\u064a\u0629 \u0627\u0644\u0645\u062e\u062a\u0627\u0631\u0629 ” \u0644\u0644\u0637\u0627\u0644\u0628\u0629 (\u063a\u064a\u062f\u0627\u0621 \u0639\u062f\u0646\u0627\u0646 \u062a\u0648\u0641\u064a\u0642) \u0627\u0644\u062a\u064a \u0627\u0646\u062c\u0632\u062a \u062a\u062d\u062a \u0627\u0634\u0631\u0627\u0641 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a\u0629 \u0641\u064a \u0627\u0644\u0642\u0633\u0645 (\u0623.\u062f. \u062a\u063a\u0631\u064a\u062f \u0647\u0627\u0634\u0645 \u0627\u0644\u0646\u0648\u0631).<\/span><\/h4>\n

\u0648\u064a\u0647\u062f\u0641 \u0627\u0644\u0628\u062d\u062b \u0627\u0644\u0649 \u0623\u062e\u062a\u0628\u0627\u0631 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0627\u0644\u0645\u0636\u0627\u062f\u0629 \u0644\u0644\u0628\u0643\u062a\u0631\u064a\u0627\u00a0 \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a\u00a0 \u0627\u0644\u062d\u0631\u0629 \u0645\u0639\u00a0 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u062a\u062c\u0627\u0647 \u0639\u062f\u062f \u0645\u0646 \u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u0647\u064a\u00a0 :\u00a0 Bacillus Subitils , Esherichia Coli\u00a0\u00a0\u00a0 \u0648\u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a: Candida albicans<\/span><\/h4>\n

\u062d\u064a\u062b \u062a\u0646\u0627\u0648\u0644 \u0647\u0630\u0627 \u0627\u0644\u0639\u0645\u0644 \u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0627\u062b\u0646\u0627\u0646\u00a0 \u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a\u00a0 \u0642\u0648\u0627\u0639\u062f \u0634\u0641 (HL1&HL2) \u0645\u0634\u062a\u0642\u0629 \u0645\u0646 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0627\u0645\u064a\u0646\u064a (L-Phenyl alanine) \u0645\u0639 (4-chlorobenzophenone) \u0648 (Curcumin) \u0645\u062a\u0636\u0645\u0646\u0647 (N,O) \u0643\u0630\u0631\u0627\u062a \u0648\u0627\u0647\u0628\u0629 \u0645\u0628\u064a\u0646\u0647 \u0641\u064a \u0627\u0644\u062c\u062f\u0648\u0644 \u0627\u062f\u0646\u0627\u0647 :<\/span><\/h4>\n

<\/h4>\n\n\n\n\n\n
\n

Symbol<\/span><\/h4>\n<\/td>\n

\n

Chemical formula<\/span><\/h4>\n<\/td>\n

\n

Schiff \u00a0bases derives form<\/span><\/h4>\n<\/td>\n<\/tr>\n

\n

HL1<\/span><\/h4>\n<\/td>\n

\n

C22H18ClNO2<\/span><\/h4>\n<\/td>\n

\n

L-Phenyl alanine + 4-Chlorobenzophenone<\/span><\/h4>\n<\/td>\n<\/tr>\n

\n

HL2<\/span><\/h4>\n<\/td>\n

\n

C30H29NO7<\/span><\/h4>\n<\/td>\n

\n

L-Phenyl alanine + curcumin<\/span><\/h4>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

<\/h4>\n

\u00a0\u00a0 \u0648 \u062a\u0645 \u062a\u0634\u062e\u064a\u0635 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a (HL1&HL2) \u00a0\u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621(FT-IR) \u0648\u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629(U.V\u2013vis), \u0637\u064a\u0641 1H NMR)), \u00a0(13C-NMR)\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631,(C.H.N) \u0645\u0639 \u062f\u0631\u062c\u0629 \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631 \u0645\u0639 \u0631\u0633\u0645 \u0623\u0634\u0643\u0627\u0644 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0644\u0631\u0646\u0627\u0645\u062c \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a \u0627\u0644\u062c\u0627\u0647\u0632 \u0643\u064a\u0645 \u0627\u0648\u0641\u064a\u0633 3DX (2006) ,\u0648\u0643\u0645\u0627 \u0645\u0628\u064a\u0646 \u0641\u064a \u0627\u0644\u0627\u0634\u0643\u0627\u0644 \u0627\u0644\u0627\u062a\u064a\u0629 :<\/span><\/h4>\n

\"\"<\/span><\/h4>\n

\"\"<\/span><\/h4>\n

<\/h4>\n

\u062a\u062d\u0636\u064a\u0631 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f :<\/span><\/h4>\n

\u0623\u0648\u0644\u0627 \u00a0(\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0642\u0648\u0627\u0639\u062f \u0634\u0641 (HL1&HL2) \u0643\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0627\u0648\u0644\u064a\u0629 \u0645\u0639\u00a0 \u00a0(Anth.H) Anthranilic acid , \u0643\u0644\u064a\u0643\u0627\u0646\u062f \u062b\u0627\u0646\u0648\u064a \u0645\u0639 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a M(II) , M(III) \u0648\u0643\u0645\u0627 \u0641\u064a \u0627\u0644\u062c\u062f\u0648\u0644 \u0627\u0644\u062a\u0627\u0644\u064a :<\/span><\/h4>\n\n\n\n\n\n
\n

Schiff bases ligands<\/span><\/h4>\n<\/td>\n

\n

Mixed ligand-Metals Complexes<\/span><\/h4>\n<\/td>\n

\n

Compositions<\/span><\/h4>\n<\/td>\n<\/tr>\n

\n

Schiff bases ligand HL1 +Anthranilic acid + Metal Chloride<\/span><\/h4>\n<\/td>\n

\n

K[M(L1)(Anth)2]<\/span><\/h4>\n

M= Mn(II), Co(II), Ni(II), Cu(II) Zn(II), Cd(II), Hg(II) .<\/span><\/h4>\n

[M(L1)( Anth)2]<\/span><\/h4>\n

M\u2019= Cr(III) &. Fe(III).<\/span><\/h4>\n<\/td>\n<\/tr>\n

\n

Schiff bases ligand HL2 +Anthranilic acid + Metal Chloride<\/span><\/h4>\n<\/td>\n

\n

[K[M(L2)(Anth)2]<\/span><\/h4>\n

M= Mn(II), Co(II), Ni(II), Cu(II) Zn(II), Cd(II), Hg(II) .<\/span><\/h4>\n

[M(L2)( Anth)2]<\/span><\/h4>\n

M\u2019= Cr(III) &. Fe(III).<\/span><\/h4>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

<\/h4>\n

\u062b\u0627\u0646\u064a\u0627 ) \u0627\u0633\u062a\u0639\u0645\u0627\u0644 (CUM) Curcumin \u0643\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0648\u0644\u064a \u0645\u0639 Anthranilic acid Anth.H)) \u0648 1,10-Phenanthroline, (Phen) \u0643\u0644\u064a\u0643\u0627\u0646\u062f \u062b\u0627\u0646\u0648\u064a \u0645\u0639 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a M(II) , M(III) \u0648\u0643\u0645\u0627 \u0641\u064a \u0627\u0644\u062c\u062f\u0648\u0644 \u0627\u0644\u0627\u062a\u064a :<\/span><\/h4>\n

<\/h4>\n\n\n\n\n\n
\n

Curcumin<\/span><\/h4>\n

(CUM)<\/span><\/h4>\n<\/td>\n

\n

Mixed ligand-Metals Complexes<\/span><\/h4>\n<\/td>\n

\n

Compositions<\/span><\/h4>\n<\/td>\n<\/tr>\n

\n

Currcumin+<\/span><\/h4>\n

Anthranilic acid + Metal Chloride<\/span><\/h4>\n<\/td>\n

\n

[M(CUM)(Anth)2]<\/span><\/h4>\n

M= Mn(II), Co(II), Ni(II), Cu(II) Zn(II), Cd(II), Hg(II) .<\/span><\/h4>\n

[M(CUM)( Anth)2]Cl<\/span><\/h4>\n

M\u2019= Cr(III) &. Fe(III).<\/span><\/h4>\n<\/td>\n<\/tr>\n

\n

Currcumin +<\/span><\/h4>\n

1,10-Phenanthroline\u00a0 + Metal Chloride<\/span><\/h4>\n<\/td>\n

\n

[M (CUM)(Phen)2]Cl<\/span><\/h4>\n

M= Mn(II), Co(II), Ni(II), Cu(II) Zn(II), Cd(II), Hg(II) .<\/span><\/h4>\n

[M (CUM)(Phen)2]Cl2<\/span><\/h4>\n

M\u2019= Cr(III) &. Fe(III).<\/span><\/h4>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

<\/h4>\n

\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0628\u0644\u0648\u0631\u0627\u062a \u0635\u0644\u0628\u0629 \u062f\u0631\u0633\u062a \u0645\u0646 \u0627\u0644\u0646\u0648\u0627\u062d\u064a \u0627\u0644\u0622\u062a\u064a\u0629: \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629\u060c \u0627\u0644\u062f\u0631\u0627\u0633\u0627\u062a \u0627\u0644\u0637\u064a\u0641\u064a\u0629 (\u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621\u060c \u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629\u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648 \u0645\u0637\u064a\u0627\u0641\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a) \u0641\u0636\u0644\u0627 \u0639\u0646 \u0642\u064a\u0627\u0633\u0627\u062a \u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0643\u0644\u0648\u0631) \u0645\u0639 \u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0628\u0631\u0646\u0627\u0645\u062c \u00a0\u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a\u00a0(Chem Office\u2013 Cs. chem\u2013 3D pro 2006) \u0641\u064a \u0631\u0633\u0645 \u0627\u0634\u0643\u0627\u0644 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a.<\/span><\/h4>\n

\u00a0\u0642\u064a\u0645 \u0627\u0644\u0639\u0632\u0648\u0645 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u0627\u0644\u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0627\u0644\u0643\u062a\u0631\u0648\u0646\u064a\u0629 \u0644\u062c\u0645\u064a\u0639 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u062f\u0644\u062a \u0639\u0644\u0649 \u0623\u0646 \u062c\u0645\u064a\u0639 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0647\u0627 \u0628\u0646\u064a\u0629 \u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d .<\/span><\/h4>\n

\u00a0\u00a0 \u0648\u064a\u062a\u0636\u0645\u0646 \u0627\u0644\u0628\u062d\u062b \u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0644\u0623\u0635\u0628\u0627\u063a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0639\u0644\u0649 \u0645\u062e\u062a\u0644\u0641 (\u062e\u064a\u0648\u0637 \u0623\u0644\u064a\u0627\u0641 \u0627\u0644\u0642\u0637\u0646) \u062f\u0648\u0646 \u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0644\u0645\u062b\u0628\u062a\u0627\u062a.<\/span><\/h4>\n

<\/h4>\n

\"\"<\/span><\/h4>\n

\u0648\u0645\u0646\u062d\u062a \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u0645\u062f\u0631\u062c\u0629 \u0627\u0633\u0645\u0627\u0626\u0647\u0645 \u0641\u064a\u0645\u0627 \u064a\u0644\u064a \u062a\u0642\u062f\u064a\u0631 \u0627\u0644\u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u0644\u0637\u0627\u0644\u0628 :<\/span><\/h4>\n

\u0648\u062a\u0623\u0644\u0641\u062a \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0645\u0646 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a\u064a\u0646 \u0627\u0644\u0623\u0641\u0627\u0636\u0644 :<\/span><\/h4>\n

\u0627.\u062f. \u0627\u062d\u0645\u062f \u062b\u0627\u0628\u062a \u0646\u0639\u0645\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u0631\u0626\u064a\u0633\u0627<\/span><\/h4>\n

\u0627.\u062f. \u0641\u0627\u0636\u0644 \u0645\u062d\u0633\u0646 \u0639\u0628\u062f\u00a0\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u0639\u0636\u0648\u0627<\/span><\/h4>\n

\u0627.\u062f. \u0639\u0645\u0631 \u062d\u0645\u062f \u0634\u0647\u0627\u0628\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u0639\u0636\u0648\u0627<\/span><\/h4>\n

\u0627.\u0645.\u062f. \u0627\u0646\u062a\u0638\u0627\u0631 \u062f\u0627\u0648\u062f \u0633\u0644\u064a\u0645\u0627\u0646\u00a0\u00a0\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u0639\u0636\u0648\u0627<\/span><\/h4>\n

\u0627.\u0645.\u062f. \u062d\u064a\u062f\u0631 \u062d\u0645\u064a\u062f \u0627\u0644\u0645\u062d\u0645\u062f\u0627\u0648\u064a\u00a0\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u0639\u0636\u0648\u0627<\/span><\/h4>\n

\u0627.\u062f. \u062a\u063a\u0631\u064a\u062f \u0647\u0627\u0634\u0645 \u0627\u0644\u0646\u0648\u0631\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u0639\u0636\u0648\u0627 \u0648\u0645\u0634\u0631\u0641\u0627<\/span><\/h3>\n
\n

PhD. Dissertation in department of Chemistry on Synthesis, Characterization and Biological Studies on Mixed Ligand Metals Complexes with Schiff Bases for Drugs Selected<\/span><\/h3>\n

The PhD.Dissertation of student Ghaida’a Adnan Tawfeeq on Synthesis, Characterization and Biological Studies on Mixed Ligand Metals Complexes with Schiff Bases for Drugs Selected supervised by prof.Dr.Tagreed Hashim Al-Noor was discussed in department of Chemistry in our college<\/span><\/h3>\n

The discussion committee<\/span><\/h3>\n

Prof.Dr.Ahmed Thabit Nuaman\u00a0\u00a0 head<\/span><\/h3>\n

Prof.Dr.Fadhil Mouhsen Abid\u00a0\u00a0 member<\/span><\/h3>\n

Prof.Dr.Omar Hamad Shihab\u00a0\u00a0 member<\/span><\/h3>\n

Asst.prof.Dr.Entidhar Dawood Sulaiman\u00a0\u00a0 member<\/span><\/h3>\n

Asst.prof.Dr.Haidar Hameed Al-Mohamadawi\u00a0\u00a0 member<\/span><\/h3>\n

Prof.Dr.Tagreed Hashim Al-Noor\u00a0\u00a0 supervisor member<\/span><\/h3>\n

The Abstract<\/span><\/h3>\n

\u00a0\u00a0 \u00a0This work prescribed the synthesis and characterization of the two\u00a0 biidentate Schiff\u00a0 bases ligands (HL1& HL2) derived from \u00a0selected Amino acid (L-Phenyl alanine ) with 4-chlorobenzophenone and Curcumin con Products were found to be solid crystalline complexes, which have been characterized through the following techniques<\/span><\/h3>\n

Molar conductivity .Spectroscopic Method [FT-IR UV-Vis and AA] and additional \u00a0measurement magnetic susceptibility, Chloride content.<\/span><\/h3>\n

The measurement magnetic susceptibility with the electronic spectra data suggested an octahedral geometry for all the complexes<\/span><\/h3>\n

The investigation includes the produced\u00a0 dyes were applied to different (Yarn fibers of\u00a0 Cotton ) without Mordant<\/span><\/h3>\n

Our research includes studying the bio\u2013activity of the complexes<\/span><\/h3>\n

The free ligands and their metal complexes have been tested in vitro against a number of bacteria:\u00a0 Bacillus Subitils , Esherichia Coli and fungal Candida albican,. In order to assess their antimicrobial<\/span><\/h3>\n

<\/h3>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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