![\"\"](\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/03\/DSC_0092-1.jpg\")
<\/p>\n
\u0648\u062a\u0647\u062f\u0641 \u0627\u0644\u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u0649 :<\/span><\/h4>\n\n- \n
\u062a\u062d\u0636\u064a\u0631 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062c\u062f\u064a\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0645\u062e\u0644\u0628 (BMT) (CBT)\u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0630\u0631\u0627\u062a \u0645\u0627\u0646\u062d\u0629 (O , S) \u0648\u0630\u0644\u0643 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0645\u0641\u0627\u0639\u0644\u0629 \u0627\u0644\u0645\u0648\u0627\u062f \u0627\u0644\u0623\u0648\u0644\u064a\u0629 \u0648\u0647\u064a 4- \u0628\u0631\u0648\u0645\u0648 -2- \u0645\u064a\u062b\u0644 \u0627\u0646\u0644\u064a\u0646\u00a0 (4-bromo -2- methyel anilin)\u00a0 \u0645\u0639 \u0643\u0644\u0648\u0631\u0648\u0627 \u0623\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (chloro acetyl chloride)\u00a0 \u06484- \u0645\u064a\u062b\u0648\u0643\u0633\u064a \u0628\u0646\u0632\u0648\u064a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (4- methoxy benzoyl chloride)\u00a0 \u0648\u062b\u0627\u064a\u0648\u0633\u064a\u0646\u0627\u062a \u0627\u0644\u0623\u0645\u0648\u0646\u064a\u0648\u0645 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u062d\u0636\u064a\u0631 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062c\u062f\u064a\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u0645\u062e\u0644\u0628 (AHB) ( HNB) \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0630\u0631\u0627\u062a \u0645\u0627\u0646\u062d\u0629 (N , O ) \u0648\u0630\u0644\u0643 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0645\u0641\u0627\u0639\u0644\u0629 \u0627\u0644\u0645\u0627\u062f\u0629 \u0627\u0644\u0623\u0648\u0644\u064a\u0629 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 \u0645\u0639 \u0627\u0644\u0623\u0633\u064a\u062a\u064a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f ((Acetyl chloride \u0648 4- \u0646\u0627\u064a\u062a\u0631\u0648 \u0628\u0646\u0632\u0648\u064a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (4- nitro bnzoyl chloride) \u0648\u062b\u0627\u064a\u0648\u0633\u064a\u0646\u0627\u062a \u0627\u0644\u0623\u0645\u0648\u0646\u064a\u0648\u0645 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0628\u0648\u0633\u0627\u0637\u0629 \u0645\u0641\u0627\u0639\u0644\u0629 (2 \u0645\u0648\u0644) \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0639 \u0645\u0648\u0644 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0623\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0644\u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624 (M+2 = VO, Mn, Cu ,Cd, Ni, Co, Zn\u00a0 and Hg)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u062e\u064a\u0635 \u062c\u0645\u064a\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0630\u0644\u0643 \u0628\u0623\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0627\u062a \u0645\u062e\u062a\u0644\u0641\u0629 \u0645\u0646 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 FT-IR \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629\u00a0 \u0648\u0637\u064a\u0641 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0648\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633 1HNMR, 13C \u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 H.N.S.<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u062e\u064a\u0635 \u062c\u0645\u064a\u0639 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0623\u0642\u062a\u0631\u0627\u062d \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0644\u0647\u0627 \u0627\u0639\u062a\u0645\u0627\u062f\u0622 \u0639\u0644\u0649 \u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 (FT-IR) \u0648\u0627\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0648\u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0623\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062e\u0648\u0627\u0635 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0623\u062d\u062f \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u062d\u0633\u0627\u0628 \u0394H, \u0394S, \u0394G \u0648\u062b\u0648\u0627\u0628\u062a \u0623\u0633\u062a\u0642\u0631\u0627\u0631\u064a\u0629 \u062a\u0643\u0648\u064a\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0648\u0645\u0639\u0627\u0645\u0644\u0627\u062a \u0623\u0631\u064a\u0646\u0648\u0633\u00a0 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629\u00a0 \u0639\u0646\u062f \u062f\u0631\u062c\u0627\u062a \u062d\u0631\u0627\u0631\u064a\u0629 \u0645\u062e\u062a\u0644\u0641\u0629 \u0648\u062a\u0631\u0627\u0643\u064a\u0632 \u0645\u062e\u062a\u0644\u0641\u0629 .<\/span><\/h4>\n<\/li>\n<\/ol>\n<\/h4>\n\u0648\u062a\u0636\u0645\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0627\u0633\u062a\u0639\u0645\u0627\u0644\u00a0 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine ) \u00a0\u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0629 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646\u00a0 (AHB)\u00a0 \u0648 (HNB) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine) \u00a0\u00a0\u0645\u0639 \u0623\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (Acetyl chloride) (AHB) \u0648 (4-\u0646\u0627\u064a\u062a\u0631\u0648 \u0628\u0646\u0632\u0648\u064a\u0644) (4-Nitrobenzoyl) HNB) ) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0648\u0647\u064a:<\/span><\/h4>\n\u00a0(AHB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 = (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid\u00a0<\/span><\/h4>\n(HNB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 =(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.\u00a0\u00a0<\/span><\/h4>\n\u00a0\u00a0 \u00a0\u00a0<\/span><\/h4>\n\u0648\u0643\u0630\u0644\u0643 \u0627\u0633\u062a\u0639\u0645\u0644 (4-Bromo-2-methylaniline) \u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0647 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0633\u0646 (BMT) \u0648 (CBT) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u0645\u0641\u0627\u0639\u0644\u0629\u00a0 \u0645\u0639 \u00a0chloride) (4-methoxbenzoyly \u00a0(BMT) (chloro acetyl chloride) \u00a0\u00a0(CBT) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0645\u064a\u062b\u0627\u0646\u0648\u0644 \u0648\u0647\u064a: \u00a0(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea]<\/span><\/h4>\n(CBT )\u00a0 =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h4>\n<\/h4>\n\u0648\u062e\u0635\u0635\u062a \u0623\u0631\u0628\u0639\u0629 \u0623\u0646\u0648\u0627\u0639 \u062c\u062f\u064a\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062f\u0631\u0627\u0633\u0627\u062a (FT-IR , UV-Vis , 13CNMR \u00a0(1H,\u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0645\u062d\u062f\u0648\u062f\u0629 (C.H.N.S) \u060c \u0627\u0644\u062a\u064a \u0627\u0643\u062a\u0634\u0641\u062a \u0627\u0644\u0645\u0637\u0627\u0628\u0642\u0629 \u0627\u0644\u0645\u0633\u0628\u0642\u0629 \u0645\u0639 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a.<\/span><\/h4>\n\u0648\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (\u062b\u0645\u0627\u0646\u064a \u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0643\u0644 \u0644\u064a\u0643\u0627\u0646\u062f) \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0648\u0636\u0639\u00a0 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (VO =M+2 \u0648 Mn\u0648 Co\u0648 Ni\u0648 Cu\u0648Zn\u0648 Cd\u0648Hg)\u00a0 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:-<\/span><\/h4>\n<\/h4>\n\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n![\"\"](\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/03\/2.jpg\")
<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\u062a\u062d\u0636\u064a\u0631 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062c\u062f\u064a\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0645\u062e\u0644\u0628 (BMT) (CBT)\u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0630\u0631\u0627\u062a \u0645\u0627\u0646\u062d\u0629 (O , S) \u0648\u0630\u0644\u0643 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0645\u0641\u0627\u0639\u0644\u0629 \u0627\u0644\u0645\u0648\u0627\u062f \u0627\u0644\u0623\u0648\u0644\u064a\u0629 \u0648\u0647\u064a 4- \u0628\u0631\u0648\u0645\u0648 -2- \u0645\u064a\u062b\u0644 \u0627\u0646\u0644\u064a\u0646\u00a0 (4-bromo -2- methyel anilin)\u00a0 \u0645\u0639 \u0643\u0644\u0648\u0631\u0648\u0627 \u0623\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (chloro acetyl chloride)\u00a0 \u06484- \u0645\u064a\u062b\u0648\u0643\u0633\u064a \u0628\u0646\u0632\u0648\u064a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (4- methoxy benzoyl chloride)\u00a0 \u0648\u062b\u0627\u064a\u0648\u0633\u064a\u0646\u0627\u062a \u0627\u0644\u0623\u0645\u0648\u0646\u064a\u0648\u0645 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u062d\u0636\u064a\u0631 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062c\u062f\u064a\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u0645\u062e\u0644\u0628 (AHB) ( HNB) \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0630\u0631\u0627\u062a \u0645\u0627\u0646\u062d\u0629 (N , O ) \u0648\u0630\u0644\u0643 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0645\u0641\u0627\u0639\u0644\u0629 \u0627\u0644\u0645\u0627\u062f\u0629 \u0627\u0644\u0623\u0648\u0644\u064a\u0629 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 \u0645\u0639 \u0627\u0644\u0623\u0633\u064a\u062a\u064a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f ((Acetyl chloride \u0648 4- \u0646\u0627\u064a\u062a\u0631\u0648 \u0628\u0646\u0632\u0648\u064a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (4- nitro bnzoyl chloride) \u0648\u062b\u0627\u064a\u0648\u0633\u064a\u0646\u0627\u062a \u0627\u0644\u0623\u0645\u0648\u0646\u064a\u0648\u0645 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0628\u0648\u0633\u0627\u0637\u0629 \u0645\u0641\u0627\u0639\u0644\u0629 (2 \u0645\u0648\u0644) \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0639 \u0645\u0648\u0644 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0623\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0644\u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624 (M+2 = VO, Mn, Cu ,Cd, Ni, Co, Zn\u00a0 and Hg)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u062e\u064a\u0635 \u062c\u0645\u064a\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0630\u0644\u0643 \u0628\u0623\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0627\u062a \u0645\u062e\u062a\u0644\u0641\u0629 \u0645\u0646 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 FT-IR \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629\u00a0 \u0648\u0637\u064a\u0641 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0648\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633 1HNMR, 13C \u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 H.N.S.<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u062e\u064a\u0635 \u062c\u0645\u064a\u0639 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0623\u0642\u062a\u0631\u0627\u062d \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0644\u0647\u0627 \u0627\u0639\u062a\u0645\u0627\u062f\u0622 \u0639\u0644\u0649 \u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 (FT-IR) \u0648\u0627\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0648\u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0623\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062e\u0648\u0627\u0635 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0623\u062d\u062f \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u062d\u0633\u0627\u0628 \u0394H, \u0394S, \u0394G \u0648\u062b\u0648\u0627\u0628\u062a \u0623\u0633\u062a\u0642\u0631\u0627\u0631\u064a\u0629 \u062a\u0643\u0648\u064a\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0648\u0645\u0639\u0627\u0645\u0644\u0627\u062a \u0623\u0631\u064a\u0646\u0648\u0633\u00a0 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629\u00a0 \u0639\u0646\u062f \u062f\u0631\u062c\u0627\u062a \u062d\u0631\u0627\u0631\u064a\u0629 \u0645\u062e\u062a\u0644\u0641\u0629 \u0648\u062a\u0631\u0627\u0643\u064a\u0632 \u0645\u062e\u062a\u0644\u0641\u0629 .<\/span><\/h4>\n<\/li>\n<\/ol>\n<\/h4>\n\u0648\u062a\u0636\u0645\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0627\u0633\u062a\u0639\u0645\u0627\u0644\u00a0 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine ) \u00a0\u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0629 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646\u00a0 (AHB)\u00a0 \u0648 (HNB) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine) \u00a0\u00a0\u0645\u0639 \u0623\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (Acetyl chloride) (AHB) \u0648 (4-\u0646\u0627\u064a\u062a\u0631\u0648 \u0628\u0646\u0632\u0648\u064a\u0644) (4-Nitrobenzoyl) HNB) ) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0648\u0647\u064a:<\/span><\/h4>\n\u00a0(AHB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 = (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid\u00a0<\/span><\/h4>\n(HNB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 =(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.\u00a0\u00a0<\/span><\/h4>\n\u00a0\u00a0 \u00a0\u00a0<\/span><\/h4>\n\u0648\u0643\u0630\u0644\u0643 \u0627\u0633\u062a\u0639\u0645\u0644 (4-Bromo-2-methylaniline) \u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0647 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0633\u0646 (BMT) \u0648 (CBT) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u0645\u0641\u0627\u0639\u0644\u0629\u00a0 \u0645\u0639 \u00a0chloride) (4-methoxbenzoyly \u00a0(BMT) (chloro acetyl chloride) \u00a0\u00a0(CBT) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0645\u064a\u062b\u0627\u0646\u0648\u0644 \u0648\u0647\u064a: \u00a0(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea]<\/span><\/h4>\n(CBT )\u00a0 =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h4>\n<\/h4>\n\u0648\u062e\u0635\u0635\u062a \u0623\u0631\u0628\u0639\u0629 \u0623\u0646\u0648\u0627\u0639 \u062c\u062f\u064a\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062f\u0631\u0627\u0633\u0627\u062a (FT-IR , UV-Vis , 13CNMR \u00a0(1H,\u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0645\u062d\u062f\u0648\u062f\u0629 (C.H.N.S) \u060c \u0627\u0644\u062a\u064a \u0627\u0643\u062a\u0634\u0641\u062a \u0627\u0644\u0645\u0637\u0627\u0628\u0642\u0629 \u0627\u0644\u0645\u0633\u0628\u0642\u0629 \u0645\u0639 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a.<\/span><\/h4>\n\u0648\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (\u062b\u0645\u0627\u0646\u064a \u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0643\u0644 \u0644\u064a\u0643\u0627\u0646\u062f) \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0648\u0636\u0639\u00a0 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (VO =M+2 \u0648 Mn\u0648 Co\u0648 Ni\u0648 Cu\u0648Zn\u0648 Cd\u0648Hg)\u00a0 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:-<\/span><\/h4>\n<\/h4>\n\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\u062a\u062d\u0636\u064a\u0631 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062c\u062f\u064a\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u0645\u062e\u0644\u0628 (AHB) ( HNB) \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0630\u0631\u0627\u062a \u0645\u0627\u0646\u062d\u0629 (N , O ) \u0648\u0630\u0644\u0643 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0645\u0641\u0627\u0639\u0644\u0629 \u0627\u0644\u0645\u0627\u062f\u0629 \u0627\u0644\u0623\u0648\u0644\u064a\u0629 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 \u0645\u0639 \u0627\u0644\u0623\u0633\u064a\u062a\u064a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f ((Acetyl chloride \u0648 4- \u0646\u0627\u064a\u062a\u0631\u0648 \u0628\u0646\u0632\u0648\u064a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (4- nitro bnzoyl chloride) \u0648\u062b\u0627\u064a\u0648\u0633\u064a\u0646\u0627\u062a \u0627\u0644\u0623\u0645\u0648\u0646\u064a\u0648\u0645 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0628\u0648\u0633\u0627\u0637\u0629 \u0645\u0641\u0627\u0639\u0644\u0629 (2 \u0645\u0648\u0644) \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0639 \u0645\u0648\u0644 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0623\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0644\u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624 (M+2 = VO, Mn, Cu ,Cd, Ni, Co, Zn\u00a0 and Hg)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u062e\u064a\u0635 \u062c\u0645\u064a\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0630\u0644\u0643 \u0628\u0623\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0627\u062a \u0645\u062e\u062a\u0644\u0641\u0629 \u0645\u0646 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 FT-IR \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629\u00a0 \u0648\u0637\u064a\u0641 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0648\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633 1HNMR, 13C \u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 H.N.S.<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u062e\u064a\u0635 \u062c\u0645\u064a\u0639 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0623\u0642\u062a\u0631\u0627\u062d \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0644\u0647\u0627 \u0627\u0639\u062a\u0645\u0627\u062f\u0622 \u0639\u0644\u0649 \u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 (FT-IR) \u0648\u0627\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0648\u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0623\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062e\u0648\u0627\u0635 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0623\u062d\u062f \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u062d\u0633\u0627\u0628 \u0394H, \u0394S, \u0394G \u0648\u062b\u0648\u0627\u0628\u062a \u0623\u0633\u062a\u0642\u0631\u0627\u0631\u064a\u0629 \u062a\u0643\u0648\u064a\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0648\u0645\u0639\u0627\u0645\u0644\u0627\u062a \u0623\u0631\u064a\u0646\u0648\u0633\u00a0 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629\u00a0 \u0639\u0646\u062f \u062f\u0631\u062c\u0627\u062a \u062d\u0631\u0627\u0631\u064a\u0629 \u0645\u062e\u062a\u0644\u0641\u0629 \u0648\u062a\u0631\u0627\u0643\u064a\u0632 \u0645\u062e\u062a\u0644\u0641\u0629 .<\/span><\/h4>\n<\/li>\n<\/ol>\n<\/h4>\n\u0648\u062a\u0636\u0645\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0627\u0633\u062a\u0639\u0645\u0627\u0644\u00a0 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine ) \u00a0\u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0629 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646\u00a0 (AHB)\u00a0 \u0648 (HNB) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine) \u00a0\u00a0\u0645\u0639 \u0623\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (Acetyl chloride) (AHB) \u0648 (4-\u0646\u0627\u064a\u062a\u0631\u0648 \u0628\u0646\u0632\u0648\u064a\u0644) (4-Nitrobenzoyl) HNB) ) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0648\u0647\u064a:<\/span><\/h4>\n\u00a0(AHB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 = (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid\u00a0<\/span><\/h4>\n(HNB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 =(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.\u00a0\u00a0<\/span><\/h4>\n\u00a0\u00a0 \u00a0\u00a0<\/span><\/h4>\n\u0648\u0643\u0630\u0644\u0643 \u0627\u0633\u062a\u0639\u0645\u0644 (4-Bromo-2-methylaniline) \u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0647 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0633\u0646 (BMT) \u0648 (CBT) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u0645\u0641\u0627\u0639\u0644\u0629\u00a0 \u0645\u0639 \u00a0chloride) (4-methoxbenzoyly \u00a0(BMT) (chloro acetyl chloride) \u00a0\u00a0(CBT) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0645\u064a\u062b\u0627\u0646\u0648\u0644 \u0648\u0647\u064a: \u00a0(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea]<\/span><\/h4>\n(CBT )\u00a0 =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h4>\n<\/h4>\n\u0648\u062e\u0635\u0635\u062a \u0623\u0631\u0628\u0639\u0629 \u0623\u0646\u0648\u0627\u0639 \u062c\u062f\u064a\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062f\u0631\u0627\u0633\u0627\u062a (FT-IR , UV-Vis , 13CNMR \u00a0(1H,\u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0645\u062d\u062f\u0648\u062f\u0629 (C.H.N.S) \u060c \u0627\u0644\u062a\u064a \u0627\u0643\u062a\u0634\u0641\u062a \u0627\u0644\u0645\u0637\u0627\u0628\u0642\u0629 \u0627\u0644\u0645\u0633\u0628\u0642\u0629 \u0645\u0639 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a.<\/span><\/h4>\n\u0648\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (\u062b\u0645\u0627\u0646\u064a \u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0643\u0644 \u0644\u064a\u0643\u0627\u0646\u062f) \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0648\u0636\u0639\u00a0 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (VO =M+2 \u0648 Mn\u0648 Co\u0648 Ni\u0648 Cu\u0648Zn\u0648 Cd\u0648Hg)\u00a0 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:-<\/span><\/h4>\n<\/h4>\n\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0628\u0648\u0633\u0627\u0637\u0629 \u0645\u0641\u0627\u0639\u0644\u0629 (2 \u0645\u0648\u0644) \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0639 \u0645\u0648\u0644 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0623\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0644\u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624 (M+2 = VO, Mn, Cu ,Cd, Ni, Co, Zn\u00a0 and Hg)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u062e\u064a\u0635 \u062c\u0645\u064a\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0630\u0644\u0643 \u0628\u0623\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0627\u062a \u0645\u062e\u062a\u0644\u0641\u0629 \u0645\u0646 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 FT-IR \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629\u00a0 \u0648\u0637\u064a\u0641 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0648\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633 1HNMR, 13C \u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 H.N.S.<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u062e\u064a\u0635 \u062c\u0645\u064a\u0639 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0623\u0642\u062a\u0631\u0627\u062d \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0644\u0647\u0627 \u0627\u0639\u062a\u0645\u0627\u062f\u0622 \u0639\u0644\u0649 \u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 (FT-IR) \u0648\u0627\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0648\u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0623\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062e\u0648\u0627\u0635 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0623\u062d\u062f \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u062d\u0633\u0627\u0628 \u0394H, \u0394S, \u0394G \u0648\u062b\u0648\u0627\u0628\u062a \u0623\u0633\u062a\u0642\u0631\u0627\u0631\u064a\u0629 \u062a\u0643\u0648\u064a\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0648\u0645\u0639\u0627\u0645\u0644\u0627\u062a \u0623\u0631\u064a\u0646\u0648\u0633\u00a0 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629\u00a0 \u0639\u0646\u062f \u062f\u0631\u062c\u0627\u062a \u062d\u0631\u0627\u0631\u064a\u0629 \u0645\u062e\u062a\u0644\u0641\u0629 \u0648\u062a\u0631\u0627\u0643\u064a\u0632 \u0645\u062e\u062a\u0644\u0641\u0629 .<\/span><\/h4>\n<\/li>\n<\/ol>\n<\/h4>\n\u0648\u062a\u0636\u0645\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0627\u0633\u062a\u0639\u0645\u0627\u0644\u00a0 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine ) \u00a0\u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0629 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646\u00a0 (AHB)\u00a0 \u0648 (HNB) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine) \u00a0\u00a0\u0645\u0639 \u0623\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (Acetyl chloride) (AHB) \u0648 (4-\u0646\u0627\u064a\u062a\u0631\u0648 \u0628\u0646\u0632\u0648\u064a\u0644) (4-Nitrobenzoyl) HNB) ) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0648\u0647\u064a:<\/span><\/h4>\n\u00a0(AHB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 = (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid\u00a0<\/span><\/h4>\n(HNB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 =(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.\u00a0\u00a0<\/span><\/h4>\n\u00a0\u00a0 \u00a0\u00a0<\/span><\/h4>\n\u0648\u0643\u0630\u0644\u0643 \u0627\u0633\u062a\u0639\u0645\u0644 (4-Bromo-2-methylaniline) \u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0647 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0633\u0646 (BMT) \u0648 (CBT) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u0645\u0641\u0627\u0639\u0644\u0629\u00a0 \u0645\u0639 \u00a0chloride) (4-methoxbenzoyly \u00a0(BMT) (chloro acetyl chloride) \u00a0\u00a0(CBT) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0645\u064a\u062b\u0627\u0646\u0648\u0644 \u0648\u0647\u064a: \u00a0(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea]<\/span><\/h4>\n(CBT )\u00a0 =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h4>\n<\/h4>\n\u0648\u062e\u0635\u0635\u062a \u0623\u0631\u0628\u0639\u0629 \u0623\u0646\u0648\u0627\u0639 \u062c\u062f\u064a\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062f\u0631\u0627\u0633\u0627\u062a (FT-IR , UV-Vis , 13CNMR \u00a0(1H,\u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0645\u062d\u062f\u0648\u062f\u0629 (C.H.N.S) \u060c \u0627\u0644\u062a\u064a \u0627\u0643\u062a\u0634\u0641\u062a \u0627\u0644\u0645\u0637\u0627\u0628\u0642\u0629 \u0627\u0644\u0645\u0633\u0628\u0642\u0629 \u0645\u0639 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a.<\/span><\/h4>\n\u0648\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (\u062b\u0645\u0627\u0646\u064a \u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0643\u0644 \u0644\u064a\u0643\u0627\u0646\u062f) \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0648\u0636\u0639\u00a0 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (VO =M+2 \u0648 Mn\u0648 Co\u0648 Ni\u0648 Cu\u0648Zn\u0648 Cd\u0648Hg)\u00a0 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:-<\/span><\/h4>\n<\/h4>\n\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\u062a\u0634\u062e\u064a\u0635 \u062c\u0645\u064a\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0630\u0644\u0643 \u0628\u0623\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0627\u062a \u0645\u062e\u062a\u0644\u0641\u0629 \u0645\u0646 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 FT-IR \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629\u00a0 \u0648\u0637\u064a\u0641 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0648\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633 1HNMR, 13C \u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 H.N.S.<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u062e\u064a\u0635 \u062c\u0645\u064a\u0639 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0623\u0642\u062a\u0631\u0627\u062d \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0644\u0647\u0627 \u0627\u0639\u062a\u0645\u0627\u062f\u0622 \u0639\u0644\u0649 \u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 (FT-IR) \u0648\u0627\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0648\u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0623\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062e\u0648\u0627\u0635 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0623\u062d\u062f \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u062d\u0633\u0627\u0628 \u0394H, \u0394S, \u0394G \u0648\u062b\u0648\u0627\u0628\u062a \u0623\u0633\u062a\u0642\u0631\u0627\u0631\u064a\u0629 \u062a\u0643\u0648\u064a\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0648\u0645\u0639\u0627\u0645\u0644\u0627\u062a \u0623\u0631\u064a\u0646\u0648\u0633\u00a0 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629\u00a0 \u0639\u0646\u062f \u062f\u0631\u062c\u0627\u062a \u062d\u0631\u0627\u0631\u064a\u0629 \u0645\u062e\u062a\u0644\u0641\u0629 \u0648\u062a\u0631\u0627\u0643\u064a\u0632 \u0645\u062e\u062a\u0644\u0641\u0629 .<\/span><\/h4>\n<\/li>\n<\/ol>\n<\/h4>\n\u0648\u062a\u0636\u0645\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0627\u0633\u062a\u0639\u0645\u0627\u0644\u00a0 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine ) \u00a0\u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0629 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646\u00a0 (AHB)\u00a0 \u0648 (HNB) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine) \u00a0\u00a0\u0645\u0639 \u0623\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (Acetyl chloride) (AHB) \u0648 (4-\u0646\u0627\u064a\u062a\u0631\u0648 \u0628\u0646\u0632\u0648\u064a\u0644) (4-Nitrobenzoyl) HNB) ) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0648\u0647\u064a:<\/span><\/h4>\n\u00a0(AHB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 = (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid\u00a0<\/span><\/h4>\n(HNB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 =(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.\u00a0\u00a0<\/span><\/h4>\n\u00a0\u00a0 \u00a0\u00a0<\/span><\/h4>\n\u0648\u0643\u0630\u0644\u0643 \u0627\u0633\u062a\u0639\u0645\u0644 (4-Bromo-2-methylaniline) \u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0647 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0633\u0646 (BMT) \u0648 (CBT) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u0645\u0641\u0627\u0639\u0644\u0629\u00a0 \u0645\u0639 \u00a0chloride) (4-methoxbenzoyly \u00a0(BMT) (chloro acetyl chloride) \u00a0\u00a0(CBT) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0645\u064a\u062b\u0627\u0646\u0648\u0644 \u0648\u0647\u064a: \u00a0(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea]<\/span><\/h4>\n(CBT )\u00a0 =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h4>\n<\/h4>\n\u0648\u062e\u0635\u0635\u062a \u0623\u0631\u0628\u0639\u0629 \u0623\u0646\u0648\u0627\u0639 \u062c\u062f\u064a\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062f\u0631\u0627\u0633\u0627\u062a (FT-IR , UV-Vis , 13CNMR \u00a0(1H,\u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0645\u062d\u062f\u0648\u062f\u0629 (C.H.N.S) \u060c \u0627\u0644\u062a\u064a \u0627\u0643\u062a\u0634\u0641\u062a \u0627\u0644\u0645\u0637\u0627\u0628\u0642\u0629 \u0627\u0644\u0645\u0633\u0628\u0642\u0629 \u0645\u0639 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a.<\/span><\/h4>\n\u0648\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (\u062b\u0645\u0627\u0646\u064a \u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0643\u0644 \u0644\u064a\u0643\u0627\u0646\u062f) \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0648\u0636\u0639\u00a0 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (VO =M+2 \u0648 Mn\u0648 Co\u0648 Ni\u0648 Cu\u0648Zn\u0648 Cd\u0648Hg)\u00a0 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:-<\/span><\/h4>\n<\/h4>\n\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\u062a\u0634\u062e\u064a\u0635 \u062c\u0645\u064a\u0639 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0623\u0642\u062a\u0631\u0627\u062d \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0644\u0647\u0627 \u0627\u0639\u062a\u0645\u0627\u062f\u0622 \u0639\u0644\u0649 \u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 (FT-IR) \u0648\u0627\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0648\u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0623\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062e\u0648\u0627\u0635 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0623\u062d\u062f \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u062d\u0633\u0627\u0628 \u0394H, \u0394S, \u0394G \u0648\u062b\u0648\u0627\u0628\u062a \u0623\u0633\u062a\u0642\u0631\u0627\u0631\u064a\u0629 \u062a\u0643\u0648\u064a\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0648\u0645\u0639\u0627\u0645\u0644\u0627\u062a \u0623\u0631\u064a\u0646\u0648\u0633\u00a0 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629\u00a0 \u0639\u0646\u062f \u062f\u0631\u062c\u0627\u062a \u062d\u0631\u0627\u0631\u064a\u0629 \u0645\u062e\u062a\u0644\u0641\u0629 \u0648\u062a\u0631\u0627\u0643\u064a\u0632 \u0645\u062e\u062a\u0644\u0641\u0629 .<\/span><\/h4>\n<\/li>\n<\/ol>\n<\/h4>\n\u0648\u062a\u0636\u0645\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0627\u0633\u062a\u0639\u0645\u0627\u0644\u00a0 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine ) \u00a0\u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0629 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646\u00a0 (AHB)\u00a0 \u0648 (HNB) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine) \u00a0\u00a0\u0645\u0639 \u0623\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (Acetyl chloride) (AHB) \u0648 (4-\u0646\u0627\u064a\u062a\u0631\u0648 \u0628\u0646\u0632\u0648\u064a\u0644) (4-Nitrobenzoyl) HNB) ) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0648\u0647\u064a:<\/span><\/h4>\n\u00a0(AHB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 = (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid\u00a0<\/span><\/h4>\n(HNB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 =(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.\u00a0\u00a0<\/span><\/h4>\n\u00a0\u00a0 \u00a0\u00a0<\/span><\/h4>\n\u0648\u0643\u0630\u0644\u0643 \u0627\u0633\u062a\u0639\u0645\u0644 (4-Bromo-2-methylaniline) \u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0647 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0633\u0646 (BMT) \u0648 (CBT) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u0645\u0641\u0627\u0639\u0644\u0629\u00a0 \u0645\u0639 \u00a0chloride) (4-methoxbenzoyly \u00a0(BMT) (chloro acetyl chloride) \u00a0\u00a0(CBT) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0645\u064a\u062b\u0627\u0646\u0648\u0644 \u0648\u0647\u064a: \u00a0(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea]<\/span><\/h4>\n(CBT )\u00a0 =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h4>\n<\/h4>\n\u0648\u062e\u0635\u0635\u062a \u0623\u0631\u0628\u0639\u0629 \u0623\u0646\u0648\u0627\u0639 \u062c\u062f\u064a\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062f\u0631\u0627\u0633\u0627\u062a (FT-IR , UV-Vis , 13CNMR \u00a0(1H,\u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0645\u062d\u062f\u0648\u062f\u0629 (C.H.N.S) \u060c \u0627\u0644\u062a\u064a \u0627\u0643\u062a\u0634\u0641\u062a \u0627\u0644\u0645\u0637\u0627\u0628\u0642\u0629 \u0627\u0644\u0645\u0633\u0628\u0642\u0629 \u0645\u0639 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a.<\/span><\/h4>\n\u0648\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (\u062b\u0645\u0627\u0646\u064a \u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0643\u0644 \u0644\u064a\u0643\u0627\u0646\u062f) \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0648\u0636\u0639\u00a0 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (VO =M+2 \u0648 Mn\u0648 Co\u0648 Ni\u0648 Cu\u0648Zn\u0648 Cd\u0648Hg)\u00a0 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:-<\/span><\/h4>\n<\/h4>\n\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062e\u0648\u0627\u0635 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0623\u062d\u062f \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u062d\u0633\u0627\u0628 \u0394H, \u0394S, \u0394G \u0648\u062b\u0648\u0627\u0628\u062a \u0623\u0633\u062a\u0642\u0631\u0627\u0631\u064a\u0629 \u062a\u0643\u0648\u064a\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0648\u0645\u0639\u0627\u0645\u0644\u0627\u062a \u0623\u0631\u064a\u0646\u0648\u0633\u00a0 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629\u00a0 \u0639\u0646\u062f \u062f\u0631\u062c\u0627\u062a \u062d\u0631\u0627\u0631\u064a\u0629 \u0645\u062e\u062a\u0644\u0641\u0629 \u0648\u062a\u0631\u0627\u0643\u064a\u0632 \u0645\u062e\u062a\u0644\u0641\u0629 .<\/span><\/h4>\n<\/li>\n<\/ol>\n<\/h4>\n\u0648\u062a\u0636\u0645\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0627\u0633\u062a\u0639\u0645\u0627\u0644\u00a0 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine ) \u00a0\u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0629 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646\u00a0 (AHB)\u00a0 \u0648 (HNB) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine) \u00a0\u00a0\u0645\u0639 \u0623\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (Acetyl chloride) (AHB) \u0648 (4-\u0646\u0627\u064a\u062a\u0631\u0648 \u0628\u0646\u0632\u0648\u064a\u0644) (4-Nitrobenzoyl) HNB) ) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0648\u0647\u064a:<\/span><\/h4>\n\u00a0(AHB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 = (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid\u00a0<\/span><\/h4>\n(HNB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 =(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.\u00a0\u00a0<\/span><\/h4>\n\u00a0\u00a0 \u00a0\u00a0<\/span><\/h4>\n\u0648\u0643\u0630\u0644\u0643 \u0627\u0633\u062a\u0639\u0645\u0644 (4-Bromo-2-methylaniline) \u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0647 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0633\u0646 (BMT) \u0648 (CBT) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u0645\u0641\u0627\u0639\u0644\u0629\u00a0 \u0645\u0639 \u00a0chloride) (4-methoxbenzoyly \u00a0(BMT) (chloro acetyl chloride) \u00a0\u00a0(CBT) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0645\u064a\u062b\u0627\u0646\u0648\u0644 \u0648\u0647\u064a: \u00a0(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea]<\/span><\/h4>\n(CBT )\u00a0 =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h4>\n<\/h4>\n\u0648\u062e\u0635\u0635\u062a \u0623\u0631\u0628\u0639\u0629 \u0623\u0646\u0648\u0627\u0639 \u062c\u062f\u064a\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062f\u0631\u0627\u0633\u0627\u062a (FT-IR , UV-Vis , 13CNMR \u00a0(1H,\u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0645\u062d\u062f\u0648\u062f\u0629 (C.H.N.S) \u060c \u0627\u0644\u062a\u064a \u0627\u0643\u062a\u0634\u0641\u062a \u0627\u0644\u0645\u0637\u0627\u0628\u0642\u0629 \u0627\u0644\u0645\u0633\u0628\u0642\u0629 \u0645\u0639 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a.<\/span><\/h4>\n\u0648\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (\u062b\u0645\u0627\u0646\u064a \u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0643\u0644 \u0644\u064a\u0643\u0627\u0646\u062f) \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0648\u0636\u0639\u00a0 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (VO =M+2 \u0648 Mn\u0648 Co\u0648 Ni\u0648 Cu\u0648Zn\u0648 Cd\u0648Hg)\u00a0 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:-<\/span><\/h4>\n<\/h4>\n\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\u0648\u062a\u0636\u0645\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0627\u0633\u062a\u0639\u0645\u0627\u0644\u00a0 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine ) \u00a0\u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0629 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646\u00a0 (AHB)\u00a0 \u0648 (HNB) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 (Threonine) \u00a0\u00a0\u0645\u0639 \u0623\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f (Acetyl chloride) (AHB) \u0648 (4-\u0646\u0627\u064a\u062a\u0631\u0648 \u0628\u0646\u0632\u0648\u064a\u0644) (4-Nitrobenzoyl) HNB) ) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0648\u0647\u064a:<\/span><\/h4>\n\u00a0(AHB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 = (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid\u00a0<\/span><\/h4>\n(HNB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 =(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.\u00a0\u00a0<\/span><\/h4>\n\u00a0\u00a0 \u00a0\u00a0<\/span><\/h4>\n\u0648\u0643\u0630\u0644\u0643 \u0627\u0633\u062a\u0639\u0645\u0644 (4-Bromo-2-methylaniline) \u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0647 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0633\u0646 (BMT) \u0648 (CBT) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u0645\u0641\u0627\u0639\u0644\u0629\u00a0 \u0645\u0639 \u00a0chloride) (4-methoxbenzoyly \u00a0(BMT) (chloro acetyl chloride) \u00a0\u00a0(CBT) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0645\u064a\u062b\u0627\u0646\u0648\u0644 \u0648\u0647\u064a: \u00a0(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea]<\/span><\/h4>\n(CBT )\u00a0 =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h4>\n<\/h4>\n\u0648\u062e\u0635\u0635\u062a \u0623\u0631\u0628\u0639\u0629 \u0623\u0646\u0648\u0627\u0639 \u062c\u062f\u064a\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062f\u0631\u0627\u0633\u0627\u062a (FT-IR , UV-Vis , 13CNMR \u00a0(1H,\u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0645\u062d\u062f\u0648\u062f\u0629 (C.H.N.S) \u060c \u0627\u0644\u062a\u064a \u0627\u0643\u062a\u0634\u0641\u062a \u0627\u0644\u0645\u0637\u0627\u0628\u0642\u0629 \u0627\u0644\u0645\u0633\u0628\u0642\u0629 \u0645\u0639 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a.<\/span><\/h4>\n\u0648\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (\u062b\u0645\u0627\u0646\u064a \u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0643\u0644 \u0644\u064a\u0643\u0627\u0646\u062f) \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0648\u0636\u0639\u00a0 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (VO =M+2 \u0648 Mn\u0648 Co\u0648 Ni\u0648 Cu\u0648Zn\u0648 Cd\u0648Hg)\u00a0 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:-<\/span><\/h4>\n<\/h4>\n\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
(HNB)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 =(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.\u00a0\u00a0<\/span><\/h4>\n\u00a0\u00a0 \u00a0\u00a0<\/span><\/h4>\n\u0648\u0643\u0630\u0644\u0643 \u0627\u0633\u062a\u0639\u0645\u0644 (4-Bromo-2-methylaniline) \u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0647 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0633\u0646 (BMT) \u0648 (CBT) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u0645\u0641\u0627\u0639\u0644\u0629\u00a0 \u0645\u0639 \u00a0chloride) (4-methoxbenzoyly \u00a0(BMT) (chloro acetyl chloride) \u00a0\u00a0(CBT) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0645\u064a\u062b\u0627\u0646\u0648\u0644 \u0648\u0647\u064a: \u00a0(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea]<\/span><\/h4>\n(CBT )\u00a0 =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h4>\n<\/h4>\n\u0648\u062e\u0635\u0635\u062a \u0623\u0631\u0628\u0639\u0629 \u0623\u0646\u0648\u0627\u0639 \u062c\u062f\u064a\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062f\u0631\u0627\u0633\u0627\u062a (FT-IR , UV-Vis , 13CNMR \u00a0(1H,\u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0645\u062d\u062f\u0648\u062f\u0629 (C.H.N.S) \u060c \u0627\u0644\u062a\u064a \u0627\u0643\u062a\u0634\u0641\u062a \u0627\u0644\u0645\u0637\u0627\u0628\u0642\u0629 \u0627\u0644\u0645\u0633\u0628\u0642\u0629 \u0645\u0639 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a.<\/span><\/h4>\n\u0648\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (\u062b\u0645\u0627\u0646\u064a \u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0643\u0644 \u0644\u064a\u0643\u0627\u0646\u062f) \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0648\u0636\u0639\u00a0 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (VO =M+2 \u0648 Mn\u0648 Co\u0648 Ni\u0648 Cu\u0648Zn\u0648 Cd\u0648Hg)\u00a0 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:-<\/span><\/h4>\n<\/h4>\n\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\u0648\u0643\u0630\u0644\u0643 \u0627\u0633\u062a\u0639\u0645\u0644 (4-Bromo-2-methylaniline) \u0645\u0627\u062f\u0629 \u0627\u0648\u0644\u064a\u0629 \u0644\u0635\u064a\u0627\u063a\u0647 \u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0633\u0646 (BMT) \u0648 (CBT) \u0648\u0627\u0646\u062c\u0632 \u0639\u0646 \u0637\u0631\u064a\u0642 \u0645\u0641\u0627\u0639\u0644\u0629\u00a0 \u0645\u0639 \u00a0chloride) (4-methoxbenzoyly \u00a0(BMT) (chloro acetyl chloride) \u00a0\u00a0(CBT) \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0645\u064a\u062b\u0627\u0646\u0648\u0644 \u0648\u0647\u064a: \u00a0(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea]<\/span><\/h4>\n(CBT )\u00a0 =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h4>\n<\/h4>\n\u0648\u062e\u0635\u0635\u062a \u0623\u0631\u0628\u0639\u0629 \u0623\u0646\u0648\u0627\u0639 \u062c\u062f\u064a\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062f\u0631\u0627\u0633\u0627\u062a (FT-IR , UV-Vis , 13CNMR \u00a0(1H,\u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0645\u062d\u062f\u0648\u062f\u0629 (C.H.N.S) \u060c \u0627\u0644\u062a\u064a \u0627\u0643\u062a\u0634\u0641\u062a \u0627\u0644\u0645\u0637\u0627\u0628\u0642\u0629 \u0627\u0644\u0645\u0633\u0628\u0642\u0629 \u0645\u0639 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a.<\/span><\/h4>\n\u0648\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (\u062b\u0645\u0627\u0646\u064a \u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0643\u0644 \u0644\u064a\u0643\u0627\u0646\u062f) \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0648\u0636\u0639\u00a0 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (VO =M+2 \u0648 Mn\u0648 Co\u0648 Ni\u0648 Cu\u0648Zn\u0648 Cd\u0648Hg)\u00a0 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:-<\/span><\/h4>\n<\/h4>\n\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
<\/h4>\n\u0648\u062e\u0635\u0635\u062a \u0623\u0631\u0628\u0639\u0629 \u0623\u0646\u0648\u0627\u0639 \u062c\u062f\u064a\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062f\u0631\u0627\u0633\u0627\u062a (FT-IR , UV-Vis , 13CNMR \u00a0(1H,\u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0645\u062d\u062f\u0648\u062f\u0629 (C.H.N.S) \u060c \u0627\u0644\u062a\u064a \u0627\u0643\u062a\u0634\u0641\u062a \u0627\u0644\u0645\u0637\u0627\u0628\u0642\u0629 \u0627\u0644\u0645\u0633\u0628\u0642\u0629 \u0645\u0639 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a.<\/span><\/h4>\n\u0648\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (\u062b\u0645\u0627\u0646\u064a \u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0643\u0644 \u0644\u064a\u0643\u0627\u0646\u062f) \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0648\u0636\u0639\u00a0 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (VO =M+2 \u0648 Mn\u0648 Co\u0648 Ni\u0648 Cu\u0648Zn\u0648 Cd\u0648Hg)\u00a0 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:-<\/span><\/h4>\n<\/h4>\n\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\u0648\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (\u062b\u0645\u0627\u0646\u064a \u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0643\u0644 \u0644\u064a\u0643\u0627\u0646\u062f) \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0648\u0636\u0639\u00a0 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 (VO =M+2 \u0648 Mn\u0648 Co\u0648 Ni\u0648 Cu\u0648Zn\u0648 Cd\u0648Hg)\u00a0 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:-<\/span><\/h4>\n<\/h4>\n\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\uf0a7\u0645\u0639\u0642\u062f\u0627\u062a AHB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0647 \u0627\u0639\u0637\u062a \u0627\u0644\u0634\u0643\u0644 [M(AHB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0HNB\u0645\u0639 \u0643\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0639\u0637\u062a \u0627\u0644\u0647\u064a\u0626\u0629 \u00a0[M(HNB)2] .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a \u00a0BMT\u0644\u0647\u0627 \u0635\u064a\u063a\u0629 \u0639\u0627\u0645\u0629\u00a0 [M(BMT)2 Cl2] \u0630\u0627\u062a \u0627\u0644\u0635\u064a\u063a\u0629 SO4[M(BMT)2]\u00a0\u00a0 .<\/span><\/h4>\n\uf0a7 \u0645\u0639\u0642\u062f\u0627\u062a CBT \u0644\u0647\u0627 \u062a\u0631\u0643\u064a\u0628\u0629 \u0639\u0627\u0645\u0629 [Cl2 \u00a0M(CBT)2] \u0645\u0627\u0639\u062f\u0627 \u0645\u0639\u0642\u062f \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u0629 SO4[M(CBT)2]\u00a0\u00a0 .<\/span><\/h4>\n<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
<\/h4>\n\u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u00a0\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u00a0\u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 , \u0623\u0630 \u062e\u0635\u0635\u062a \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0639\u0646\u0627\u0635\u0631 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u0627\u0644\u0646\u0648\u0627\u062a\u062c \u0648\u0627\u0644\u062a\u0634\u062e\u064a\u0635\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0623\u0639\u0644\u0627\u0647 \u060c \u0623\u0630 \u062e\u064c\u0635\u0635\u062a \u0623\u0631\u0628\u0639 \u0647\u064a\u0626\u0627\u062a \u062a\u0631\u0643\u064a\u0628\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n\n- \n
\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n- \n
\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n- \n
\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n\n- \n
\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n- \n
\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n\n- \n
\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\nThe chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\nThe discussion committee:<\/span><\/h3>\nprof.Dr. luma Majeed Ahmed head<\/span><\/h3>\nAsst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\nAsst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\nAsst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\nProf.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\nProf.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n<\/h3>\nThe purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\nThreonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\nAnd also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\nThese new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n(AHB) = C7H12O4N2S<\/span><\/h3>\n(HNB) = C12H13O6N3S<\/span><\/h3>\n(BMT) = C16H15O2N2SBr<\/span><\/h3>\n(CBT) = C10H10N2OSBrCl<\/span><\/h3>\nA series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\nAHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\nHNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\nBMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\nCBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\nAll complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\nIn addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\nTetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\nSquare pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\nSquare planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\nThe study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\nFind the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\nThe study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\nFor its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":" \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
- \n
- \n
\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646BMT CBT,\u00a0 \u0627\u0644\u062a\u064a \u062a\u062f\u0631\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0623\u062a\u064a\u0629 :- \u00a0=M+2 \u00a0Mn, Co, Ni, Cu,Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n
- \n
\u0631\u0628\u0627\u0639\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (AHB) HNB)) \u00a0=M+2 \u00a0\u00a0Mn, Co, Ni , Zn, Cd, Hg<\/span><\/h4>\n<\/li>\n
- \n
\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0643\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629<\/span><\/h4>\n<\/li>\n
- \n
\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648 \u0644\u0645\u0639\u0642\u062f\u064a \u0627\u0644\u0646\u062d\u0627\u0633 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 , AHB HNB .<\/span><\/h4>\n<\/li>\n<\/ul>\n
<\/h4>\n
\u062f\u064b\u0631\u0633\u062a \u0627\u0644\u0645\u0632\u0627\u064a\u0627 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0647\u0648 (AHB) \u0645\u0639 \u0623\u062d\u062f \u0645\u0639\u0642\u062f\u0627\u062a\u0647 [Cd(AHB)2] \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u0648\u0635\u0644\u0646\u0627 \u0627\u0644\u0649:-<\/span><\/h4>\n
\u0627\u064a\u062c\u0627\u062f \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0645\u0639\u0642\u062f\u0647 [Cd(AHB)2].<\/span><\/h4>\n
\u062d\u0633\u0627\u0628 \u062b\u0648\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644 (DMSO) \u0648\u0641\u064a \u0646\u0637\u0627\u0642 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u062d\u0631\u0627\u0631\u0629 (25-45) C\u25e6 .<\/span><\/h4>\n
\u0628\u064a\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0623\u0646 \u062b\u0627\u0628\u062a \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (AHB) \u00a0\u00a0\u0648 \u0627\u0644\u0645\u0639\u0642\u062f \u00a0[Cd(AHB)2] \u00a0\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0623\u064a\u062f \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u064a\u062c\u0629 \u0627\u0645\u0643\u0627\u0646\u064a\u0629\u00a0 \u0623\u0646\u062b\u0627\u0644\u0628\u064a (H\u0394) \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0623\u0630 \u0643\u0627\u0646 \u0641\u064a \u0627\u0644\u062d\u0627\u0644\u062a\u064a\u0646 \u0645\u0642\u062f\u0627\u0631 (\u0645\u0648\u062c\u0628 ) \u0627\u064a \u0639\u0645\u0644\u064a\u0629 (\u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629).<\/span><\/h4>\n
\u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0623\u0646\u062a\u0631\u0648\u0628\u064a( S\u0394 ) \u0639\u0645\u0644\u064a\u0629 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0643\u0627\u0646\u062a (\u0633\u0627\u0644\u0628\u0629) \u0628\u0633\u0628\u0628 \u0632\u064a\u0627\u062f\u0629 \u0623\u0646\u062a\u0638\u0627\u0645 \u062c\u0632\u064a\u0626\u0627\u062a \u0627\u0644\u0645\u0630\u064a\u0628 \u062d\u0648\u0644 \u0627\u0644\u0622\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0645\u0646 \u062a\u0641\u0643\u0643 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n
\u0623\u0645\u0627 \u0628\u0627\u0644\u0646\u0633\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0641\u0643\u0627\u0646\u062a (\u0645\u0648\u062c\u0628\u0629 ) \u0628\u0633\u0628\u0628 \u0627\u0644\u0639\u062f\u062f \u0627\u0644\u0643\u0628\u064a\u0631 \u0644\u0644\u0641\u0635\u0627\u0626\u0644 \u0627\u0644\u0645\u062a\u0648\u0644\u062f\u0629 \u0639\u0646\u062f \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n
\u0643\u0644\u062a\u0627 \u0627\u0644\u0639\u0645\u0644\u064a\u062a\u0627\u0646 \u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n
\u0627\u0646 \u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u0645\u062d\u062f\u062f\u0629 (O\u0245) \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f(AHB) \u00a0\u0648\u0627\u0644\u0645\u0639\u0642\u062f\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0[(Cd(AHB)2]\u062a\u0632\u062f\u0627\u062f \u0628\u0632\u064a\u0627\u062f\u0629 \u062f\u0631\u062c\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u062d\u064f\u0633\u0628\u062a \u0637\u0627\u0642\u0629 \u0627\u0644\u062a\u0646\u0634\u064a\u0637 \u0648\u0645\u0639\u0627\u0645\u0644 \u062a\u0631\u062f\u062f \u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0641\u0643\u0643 .<\/span><\/h4>\n
\u0648\u0627\u0648\u0635\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0628\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n
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\u062f\u0631\u0627\u0633\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u062c\u062f\u064a\u062f\u0629 \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0645\u0633\u062a\u0639\u0645\u0644 \u0627\u0644\u062b\u0631\u064a\u0648\u0646\u064a\u0646 .<\/span><\/h4>\n<\/li>\n
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\u062a\u0634\u0643\u064a\u0644 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0647\u0630\u0647 \u0627\u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0628\u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u064a \u062a\u0635\u0644 \u0628\u0646\u0627 \u0627\u0644\u0649 \u0646\u062a\u0627\u0626\u062c \u0643\u0628\u064a\u0631\u0629 .<\/span><\/h4>\n<\/li>\n
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\u062f\u0631\u0627\u0633\u0647\u064f \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0645\u062e\u062a\u0644\u0641 \u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0647 \u0648\u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 .<\/span><\/h4>\n<\/li>\n
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\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u062f\u064a\u062f\u0629 \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0628\u0627\u0644\u0634\u0643\u0644 \u0648\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u062d\u062f\u064a\u062b\u0629.<\/span><\/h4>\n<\/li>\n
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\u0627\u062e\u062a\u0628\u0627\u0631 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0627\u062f \u0639\u0644\u0649 \u062a\u0634\u0643\u064a\u0644\u0647\u0627 \u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0627 .<\/span><\/h4>\n<\/li>\n<\/ul>\n
<\/h4>\n\u0648\u062d\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0639\u0644\u0649 \u062a\u0642\u062f\u064a\u0631 \u0627\u0645\u062a\u064a\u0627\u0632 \u0644\u062f\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u062a\u0647\u0627 \u0648\u062a\u0641\u0627\u0635\u064a\u0644 \u0628\u062d\u062b\u0647\u0627 \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0630\u0648\u0627\u062a :<\/span><\/h4>\n
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\u0623.\u062f. \u0644\u0645\u0649 \u0645\u062c\u064a\u062f \u0627\u062d\u0645\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n
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\u0623.\u0645.\u062f. \u0627\u0646\u0639\u0627\u0645 \u0627\u0633\u0645\u0627\u0639\u064a\u0644 \u064a\u0648\u0633\u0641 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n
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\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062d\u0633\u064a\u0646 \u0639\u0644\u0648\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n
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\u0623.\u0645.\u062f. \u0633\u0627\u0647\u0631\u0629 \u0635\u0627\u062f\u0642 \u0639\u0628\u062f\u0627\u0644\u0631\u0632\u0627\u0642\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n
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\u0623.\u062f. \u062a\u0642\u064a \u0627\u0644\u062f\u064a\u0646 \u0639\u0628\u062f\u0627\u0644\u0647\u0627\u062f\u064a \u062d\u0645\u062f\u0627\u0646\u00a0 \u00a0 \u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h3>\n
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\nPhD. Dissertation on Preparation and Spectroscopic and Physical Study of new Complexes Containing Ligands Derived from Amino Compsound<\/span><\/h3>\n
The chemistry department in our college discussed PhD.Dissertation discussion of student Tagreed Baqir Awan Al-Etabbi supervised by prof.Dr.Basima Mouhsen prof.Dr. Taqi Al-Deen Abdulhadi Hamdan in physical chemistry.<\/span><\/h3>\n
The discussion committee:<\/span><\/h3>\n
prof.Dr. luma Majeed Ahmed head<\/span><\/h3>\n
Asst.prof.Dr.Ana’am Ismail Yousif<\/span><\/h3>\n
Asst.prof.Dr.Liqa’a Hussein Alwan\u00a0 member<\/span><\/h3>\n
Asst.prof.Dr.Sahira Sadiq Abdulrazak\u00a0\u00a0 member<\/span><\/h3>\n
Prof.Dr.taqi Al-Deen Abdulhadi Hamdan supervisor member<\/span><\/h3>\n
Prof.Dr.Basima Mouhsen Sarhan\u00a0\u00a0 supervisor member<\/span><\/h3>\n
<\/h3>\n
The purpose of my thesis is to synthesis four new bidentate ligands which were used to prepare series of\u00a0 metal complexes by reacting the ligands with<\/span><\/h3>\n
(M+2 = Mn, Co, Ni, Cu, Zn, Cd, Hg and VO) then characterize all the prepared compounds and studying the Thermodynamics effect .<\/span><\/h3>\n
Threonine was used as starting material to synthesis two bidentate ligands (N,O) donor (AHB) and (HNB) by reaction of Threonine andammonium thiocyant\u00a0 with of acetyl chloride (AHB),and<\/span><\/h3>\n
(4-nitrobenzoyl)(HNB) \u00a0and at in acetone as a solvent, that are:<\/span><\/h3>\n
(AHB)=[ (3R)[2-(3-acetyl thioureido)-3-hydroxyl]butanoic acid<\/span><\/h3>\n
(HNB) =[(3R)[3-hydroxyl-2-(3-(4-nitro benzoyl)](thioureido) butanoic acid.<\/span><\/h3>\n
And also Uses(4-Bromo-2-methylaniline) , was used as starting material to synthesis two bidentate\u00a0 ligands (S,O) donor (BMT) and\u00a0 (CBT) by reaction of ammonium thiocyan\u00a0 With (4-methoxybenzoylchloride) (BMT) and (chloroacetylchloride) in acetone as a solvent and that are:<\/span><\/h3>\n
(BMT) =[1-(4-Bromo-2-methyl-phenyl(3(4-methoxy-benzoyl-thiourea](CBT) =[1-chloroacetyl-3-(4-bromo-2-methyl-phenyl thiourea]<\/span><\/h3>\n
These new four correlations were characterized by the spectral study (FT-IR), nuclear magnetic resonance (1H , 13C-NMR), bone analysis (CHNS), UV-Vis and molecular :<\/span><\/h3>\n
(AHB) = C7H12O4N2S<\/span><\/h3>\n
(HNB) = C12H13O6N3S<\/span><\/h3>\n
(BMT) = C16H15O2N2SBr<\/span><\/h3>\n
(CBT) = C10H10N2OSBrCl<\/span><\/h3>\n
A series of metal complexes ( containing eight complexes for each ligand ) were synthesized from adding some metal ions<\/span><\/h3>\n
(M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and\u00a0 Hg) to the ligand\u00a0 with molecular formulas:<\/span><\/h3>\n
AHB complexes with all metal ions [M(AHB)2].<\/span><\/h3>\n
HNB complexes with all metal ions [M(HNB)2]<\/span><\/h3>\n
BMT complexes with all metal ions have the formula [M(BMT)2Cl2] except VO has the molecular formula\u00a0 [VO(BMT)2]SO4.<\/span><\/h3>\n
CBT complexes with all metal ions have the formula [M(CBT)2Cl2] except VO has the molecular formula\u00a0 [VO(CBT)2]SO4..<\/span><\/h3>\n
All complexes that synthesised in this investigation were characterized by solubility, melting point besides decomposition,Fourier-transform infrared spectroscopy ,Electronic spectra, molecular conductivity, magnetic sensitivity measurements, precision analysis of elements of some compounds and atomic absorption of flame.<\/span><\/h3>\n
In addition to all these analyzes, the proposed structures include four types: Octahedral geometryfor complexes with ligands (BMT) and (CBT) contain\u00a0 (M2+ = Mn, Co, Cu, Ni, Zn, Cd and\u00a0 Hg).<\/span><\/h3>\n
Tetrahedral geometry for complexes with ligands (AHB) and (HNB)(M2+ = Mn, Co, Ni, Zn, Cd and\u00a0 Hg)<\/span><\/h3>\n
Square pyramidal geometry\u00a0 for all prepared Vanadyl complexes (VO +2) with all ligands.<\/span><\/h3>\n
Square planer geometry forthe complexes prepared cupper ion (Cu+2) with ligands (AHB) and (HNB).<\/span><\/h3>\n
The study also examined the physical properties of one type of ligand\u00a0 with one of its complexes My findings were reached:-<\/span><\/h3>\n
Find the constants of ligand dissociation ,calculation of ligand(AHB) and complexes[Cd(AHB)2] in (DMSO) solvent was calculation and in temperature range (25-45)C\u25e6 .<\/span><\/h3>\n
The study showed that constant dissociation of ligand (AHB) and complex [Cd(AHB)2] increases with increasing temperature and confirming the result of this enthalpy value ($H) ligand and complex where both were positive amount of heat absorbing process .<\/span><\/h3>\n
For its entropy value ($s) the process of dissociation of ligand (AHB) was negative due to increased uniformity of the solvent molecules and the ions resulting from the dissociation of ligand . As for the<\/span> complex was generated at<\/span> dissociation<\/span><\/h3>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"
\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062c\u062f\u064a\u062f\u0629….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":24601,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-24600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=24600"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/24600\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/24601"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=24600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=24600"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=24600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
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