{"id":25697,"date":"2019-04-24T23:22:11","date_gmt":"2019-04-24T20:22:11","guid":{"rendered":"http:\/\/ihcoedu.uobaghdad.edu.iq\/?p=25697"},"modified":"2019-04-25T08:59:35","modified_gmt":"2019-04-25T05:59:35","slug":"%d9%82%d8%b3%d9%85-%d8%a7%d9%84%d9%83%d9%8a%d9%85%d9%8a%d8%a7%d8%a1-%d9%8a%d9%86%d8%a7%d9%82%d8%b4-%d8%b1%d8%b3%d8%a7%d9%84%d8%a9-%d9%85%d8%a7%d8%ac%d8%b3%d8%aa%d9%8a%d8%b1-%d8%aa%d8%a8%d8%ad%d8%ab-2","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=25697","title":{"rendered":"\u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u064a\u0646\u0627\u0642\u0634 \u0631\u0633\u0627\u0644\u0629 \u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u062a\u0628\u062d\u062b \u0641\u064a \u062a\u062d\u0636\u064a\u0631 \u062c\u062f\u064a\u062f \u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0627\u0633\u0643\u0648\u0631\u0628\u064a\u0643 \u0645\u0646 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u064a\u0632\u064a\u0629"},"content":{"rendered":"<h4><\/h4>\n<h4><span style=\"color: #000080\">\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0645\u0631\u0643\u0628 \u062c\u062f\u064a\u062f \u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0623\u0633\u0643\u0648\u0631\u0628\u064a\u0643 \u0645\u0639 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629) \u0641\u064a \u062a\u062e\u0635\u0635 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0627\u0644\u0644\u0627\u0639\u0636\u0648\u064a\u0629 \u0644\u0644\u0637\u0627\u0644\u0628 (\u0639\u0644\u0627\u0621 \u062d\u0633\u0646 \u062d\u0633\u0646) \u0648 \u0627\u0644\u062a\u064a \u0627\u0646\u062c\u0632\u062a \u0628\u0627\u0634\u0631\u0627\u0641 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a \u0641\u064a \u0627\u0644\u0642\u0633\u0645 (\u0623.\u0645.\u062f. \u0648\u0644\u064a\u062f \u062e\u0627\u0644\u062f \u0645\u0647\u062f\u064a) \u0648\u0646\u0648\u0642\u0634\u062a \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a\u064a\u0646 :<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0627. \u062f. \u0628\u0627\u0633\u0645\u0629 \u0645\u062d\u0633\u0646 \u0633\u0631\u062d\u0627\u0646\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0631\u0626\u064a\u0633\u0627\u064b)<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0627.\u062f. \u0645\u062d\u0645\u0648\u062f \u0646\u062c\u0645 \u0639\u0628\u062f\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627\u064b)<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0645. \u062f. \u0627\u064a\u0646\u0627\u0633 \u062c\u0627\u0633\u0645 \u0648\u062d\u064a\u062f\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627\u064b)<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0627. \u0645. \u062f. \u0648\u0644\u064a\u062f \u062e\u0627\u0644\u062f \u0645\u0647\u062f\u064a \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (\u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627)<\/span><\/h4>\n<div id='gallery-1' class='gallery galleryid-25697 gallery-columns-2 gallery-size-large'><figure class='gallery-item'>\n\t\t\t<div class='gallery-icon landscape'>\n\t\t\t\t<img loading=\"lazy\" decoding=\"async\" width=\"800\" height=\"533\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/DSC_0782.jpg\" class=\"attachment-large size-large\" alt=\"\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/DSC_0782.jpg 800w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/DSC_0782-300x200.jpg 300w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/DSC_0782-768x512.jpg 768w\" sizes=\"auto, (max-width: 800px) 100vw, 800px\" \/>\n\t\t\t<\/div><\/figure><figure class='gallery-item'>\n\t\t\t<div class='gallery-icon landscape'>\n\t\t\t\t<img loading=\"lazy\" decoding=\"async\" width=\"800\" height=\"533\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/DSC_0785.jpg\" class=\"attachment-large size-large\" alt=\"\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/DSC_0785.jpg 800w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/DSC_0785-300x200.jpg 300w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/DSC_0785-768x512.jpg 768w\" sizes=\"auto, (max-width: 800px) 100vw, 800px\" \/>\n\t\t\t<\/div><\/figure>\n\t\t<\/div>\n\n<h4><span style=\"color: #000080\">\u0648\u062a\u0647\u062f\u0641 \u0627\u0644\u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0649\u00a0<\/span><span style=\"color: #000080\">\u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0645\u0631\u0643\u0628 \u062c\u062f\u064a\u062f \u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0623\u0633\u0643\u0648\u0631\u0628\u064a\u0643 \u0645\u0639 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629.<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0648\u062a\u0636\u0645\u0646\u062a \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062d\u0627\u0644\u064a\u0629 \u062a\u062d\u0636\u064a\u0631 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0644\u0639\u0646\u0642\u0648\u062f\u064a \u0627\u0644\u062a\u0646\u0627\u0633\u0642\u064a \u0627\u0644\u062c\u062f\u064a\u062f \u062b\u0644\u0627\u062b\u064a \u0627\u0644\u0646\u0648\u0627\u0629 \u062d\u0633\u0628 \u0627\u0644\u0637\u0631\u064a\u0642\u0629 \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u062d\u0636\u0631 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f ( (L-AZD\u0627\u0644\u0639\u0646\u0642\u0648\u062f\u064a \u0645\u0646 \u062a\u0641\u0627\u0639\u0644 L-AsCl2 \u0645\u0639 \u0633\u062a\u0629 \u0645\u0648\u0644\u0627\u062a \u0645\u0646 \u0623\u0632\u064a\u062f \u0627\u0644\u0635\u0648\u062f\u064a\u0648\u0645 \u0641\u064a\u00a0 \u0627\u0644\u0627\u064a\u062b\u0627\u0646\u0648\u0644 \u0645\u0639 \u0642\u0637\u0631\u0627\u062a \u0645\u0646 \u0627\u0644\u0645\u0627\u0621 \u0648\u0643\u0627\u0646 \u0627\u0644\u0646\u0627\u062a\u062c \u0630\u064a \u0627\u0644\u0635\u064a\u063a\u0629 \u0627\u0644\u062a\u062c\u0631\u064a\u0628\u064a\u0629 \u0627\u0644\u062a\u0627\u0644\u064a\u0629 : C13H16N18O9\u00a0 \u0648\u0634\u062e\u0635 \u0627\u0644 ( (L-AZD \u0628\u0648\u0627\u0633\u0637\u0629 \u0643\u0631\u0648\u0645\u0648\u062a\u0648\u063a\u0631\u0627\u0641\u064a\u0627 \u0627\u0644\u0637\u0628\u0642\u0629 \u0627\u0644\u0631\u0642\u064a\u0642\u0629 (TLC) \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0635\u0631\u064a \u0627\u0644\u062f\u0642\u064a\u0642 (C.H.N) \u060c \u0623\u0637\u064a\u0627\u0641 \u0628\u0631\u0648\u062a\u0648\u0646-\u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0648\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a 1H-NMR \u0639\u0645\u0644\u064a\u0627\u064b \u0648\u0646\u0638\u0631\u064a\u0627\u064b \u062d\u0633\u0628 \u0628\u0631\u0646\u0627\u0645\u062c \u00a0(\u0627\u0644\u0645\u062a\u0639\u0644\u0642 \u0628\u0627\u0644\u0643\u064a\u0645\u064a\u0627\u06212016) \u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0627\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 (FT-IR) \u060c \u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0627\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0648\u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0643\u062a\u0644\u0629 \u060c \u0643\u0645\u0627 \u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0645\u0639\u0642\u062f\u0627\u062a \u0639\u0646\u0642\u0648\u062f\u064a\u0629 \u062c\u062f\u064a\u062f\u0629 \u0644\u0644\u064a\u0643\u0627\u0646\u062f ( (L-AZD \u0645\u0639 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 :<\/span><\/h4>\n<h4><span style=\"color: #000080\">VO(II) ,Cr(III), Mn(II),Co(II) ,Ni(II),Cu(II),Zn(II),Cd(II), and Hg(II)<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u00a0\u0648\u0630\u0644\u0643 \u0645\u0646 \u062a\u0641\u0627\u0639\u0644 \u0643\u0644\u0648\u0631\u064a\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0645\u0627 \u0639\u062f\u0627 VOSO4.H2O \u0648\u0628\u0646\u0633\u0628\u0629 (M:L) (3:1) \u0645\u0639\u0637\u064a\u0629 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/h4>\n<h4><span style=\"color: #000080\">[(VO)3 (L-AZD)(H2O)2(SO4)2]SO4.3H2O<\/span><\/h4>\n<h4><span style=\"color: #000080\">[Cr3(L-AZD)(H2O)2Cl8]Cl.2H2O.C2H5OH<\/span><\/h4>\n<h4><span style=\"color: #000080\">[Mn3(L-AZD)(H2O)5Cl5]Cl.4H2O.2C2H5OH<\/span><\/h4>\n<h4><span style=\"color: #000080\">[Co3(L-AZD)(H2O)5Cl5]Cl. H2O.2C2H5OH<\/span><\/h4>\n<h4><span style=\"color: #000080\">[Ni3(L-AZD)(H2O)5Cl5]Cl<\/span><\/h4>\n<h4><span style=\"color: #000080\">[Cu3(L-AZD)(H2O) Cl5]Cl. 4H2O<\/span><\/h4>\n<h4><span style=\"color: #000080\">[Zn3(L-AZD)Cl5]Cl<\/span><\/h4>\n<h4><span style=\"color: #000080\">[Cd3(L-AZD)(H2O) Cl5]Cl<\/span><\/h4>\n<h4><span style=\"color: #000080\">[Hg3(L-AZD)(H2O)Cl5]Cl.25H2O<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0634\u062e\u0635\u062a \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0639\u0646\u0642\u0648\u062f\u064a\u0629 \u0627\u0644\u062c\u062f\u064a\u062f\u0629 \u0639\u0644\u0649 \u0623\u0633\u0627\u0633 \u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0627\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0648\u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u060c \u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0627\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 (RT-IR) \u0648 \u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0628\u062f\u0631\u062c\u0629 \u062d\u0631\u0627\u0631\u0629 \u0627\u0644\u063a\u0631\u0641\u0629 \u0648\u0627\u0644\u0646\u0633\u0628\u0629 \u0627\u0644\u0645\u0648\u0644\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a :\u00a0<\/span><span style=\"color: #000080\">VO(II) ,Cr(III), Mn(II), Cu(II),Zn(II),Cd(II), and Hg(II)\u00a0\u00a0<\/span><span style=\"color: #000080\">\u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0648\u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0644\u0645\u0639\u0631\u0641\u0629 \u0627\u0644\u0646\u0633\u0628\u0629 \u0627\u0644\u0645\u0626\u0648\u064a\u0629 \u0644\u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0641\u0644\u0632 \u0641\u064a \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0648\u0642\u062f \u0623\u0633\u062a\u0646\u062a\u062c \u060c \u0628\u0623\u0646 \u062c\u0645\u064a\u0639 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0644( (L-AZD \u064a\u062a\u0646\u0627\u0633\u0642 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0646 \u062e\u0644\u0627\u0644 \u0627\u0644\u0627\u0632\u064a\u062f\u0648 \u0627\u0644\u0637\u0631\u0641\u064a\u0629 \u0648\u0645\u062c\u0627\u0645\u064a\u0639 \u0627\u0644\u0643\u0627\u0631\u0628\u0648\u0646\u064a\u0644 \u0623\u0632\u064a\u062f \u00a0Cr(III), Mn(II),Co(II) ,Ni(II)\u0645\u0627 \u0639\u062f\u0627 \u0645\u0639\u0642\u062f\u0627\u062a\u00a0 VO(II), Zn(II),Cd(II),Hg(II) \u062a\u062a\u0646\u0627\u0633\u0642 \u0645\u0646 \u062e\u0644\u0627\u0644\u00a0 \u0627\u0644\u0623\u0632\u064a\u062f\u0648. \u0648\u0642\u062f \u0648\u062c\u062f \u0623\u0646 \u0643\u0644 \u0645\u0646 Ni(II) Mn(II) and Cr(III) \u00a0Co(II),\u062a\u0645\u062a\u0644\u0643 \u0627\u0644\u0634\u0643\u0644 \u0627\u0644\u0647\u0646\u062f\u0633\u064a (\u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d) \u0648\u0627\u0644 VO(II) \u064a\u0645\u062a\u0644\u0643 \u0634\u0643\u0644\u0627\u064b \u0647\u0646\u062f\u0633\u064a\u0627\u064b \u0647\u0648 (\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629) \u060c \u0648\u0641\u064a \u062d\u064a\u0646 \u0645\u0639\u0642\u062f\u0627\u062a Zn(II),Cd(II),Hg(II) \u062a\u0639\u0637\u064a \u0634\u0643\u0644\u0627\u064b \u0647\u0646\u062f\u0633\u064a\u0627\u064b \u0647\u0648 \u0631\u0628\u0627\u0639\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0648 Cu(II) \u064a\u0645\u062a\u0644\u0643 \u0634\u0643\u0644\u0627 \u0647\u0646\u062f\u0633\u064a\u0646\u0627 \u0647\u0648 (\u0645\u0631\u0628\u0639 \u0645\u0633\u062a\u0648\u064a) \u060c \u062a\u0645 \u0623\u0646\u062c\u0627\u0632 \u0627\u0644\u0628\u0646\u064a\u0629 \u0627\u0644\u0627\u0644\u0643\u062a\u0631\u0648\u0646\u064a\u0629 \u0627\u0644\u0646\u0638\u0631\u064a\u0629 \u0644 ( (L-AZD\u0648\u0630\u0644\u0643 \u0645\u0646 \u062e\u0644\u0627\u0644 \u062a\u0637\u0628\u064a\u0642 \u0627\u0644\u0628\u0631\u0646\u0627\u0645\u062c \u0627\u0644\u0645\u062a\u0639\u0644\u0642 \u0641\u064a \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 (3DX.2016) \u00a0. \u0644\u062a\u0635\u0648\u0631 \u0634\u0643\u0644 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0645\u0639\u0642\u062f\u0627\u062a\u0647 \u0648\u0627\u062d\u062a\u0645\u0627\u0644\u064a\u0629 \u0645\u0648\u0627\u0642\u0639 \u0627\u0644\u062a\u0646\u0627\u0633\u0642 \u0648\u0643\u0645\u0627 \u0645\u0648\u0636\u062d \u0641\u064a \u0627\u0644\u0627\u0634\u0643\u0627\u0644 \u0627\u062f\u0646\u0627\u0647 :-<\/span><\/h4>\n<h4><span style=\"color: #000080\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-25707\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig1.jpg\" alt=\"\" width=\"582\" height=\"387\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig1.jpg 582w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig1-300x199.jpg 300w\" sizes=\"auto, (max-width: 582px) 100vw, 582px\" \/><\/span><\/h4>\n<h4 style=\"text-align: center\"><span style=\"color: #000080\">\u0627\u0644\u0634\u0643\u0644 (1) \u0627\u0644\u0647\u064a\u0643\u0644 \u0627\u0644\u062c\u0632\u064a\u0626\u064a \u0627\u0644\u0645\u0642\u062a\u0631\u062d \u0644\u0640(L-AZD)<\/span><\/h4>\n<h4 style=\"text-align: center\"><span style=\"color: #000080\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-25706\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig2.jpg\" alt=\"\" width=\"562\" height=\"755\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig2.jpg 562w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig2-223x300.jpg 223w\" sizes=\"auto, (max-width: 562px) 100vw, 562px\" \/>\u0627\u0644\u0634\u0643\u0644 (2) \u0627\u0644\u0635\u064a\u063a\u0629 \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0644\u0645\u0639\u0642\u062f \u0627\u064a\u0648\u0646 (VO(II)<\/span><\/h4>\n<h4 style=\"text-align: center\"><span style=\"color: #000080\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-25705\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig3.jpg\" alt=\"\" width=\"549\" height=\"731\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig3.jpg 549w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig3-225x300.jpg 225w\" sizes=\"auto, (max-width: 549px) 100vw, 549px\" \/>\u0627\u0644\u0634\u0643\u0644 (3) \u0627\u0644\u0635\u064a\u063a\u0629 \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0644\u0645\u0639\u0642\u062f \u0627\u064a\u0648\u0646 (Cr(III))<\/span><\/h4>\n<h4 style=\"text-align: center\"><span style=\"color: #000080\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-25704\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig4.jpg\" alt=\"\" width=\"586\" height=\"767\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig4.jpg 586w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig4-229x300.jpg 229w\" sizes=\"auto, (max-width: 586px) 100vw, 586px\" \/>\u0627\u0644\u0634\u0643\u0644 (4) \u0627\u0644\u0635\u064a\u063a\u0629 \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a Mn(II), Co(II) and Ni(II) \u00a0\u060c (1).M=Mn.\u00a0 \u00a0\u060c (2).M=Co. \u060c (3).M=Ni.<\/span><\/h4>\n<h4 style=\"text-align: center\"><span style=\"color: #000080\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-25703\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig5.jpg\" alt=\"\" width=\"561\" height=\"763\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig5.jpg 561w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig5-221x300.jpg 221w\" sizes=\"auto, (max-width: 561px) 100vw, 561px\" \/>\u0627\u0644\u0634\u0643\u0644 (5) \u0627\u0644\u0635\u064a\u063a\u0629 \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0644\u0645\u0639\u0642\u062f \u0627\u064a\u0648\u0646 (Cu(II))<\/span><\/h4>\n<h4 style=\"text-align: center\"><span style=\"color: #000080\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-25702\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig6.jpg\" alt=\"\" width=\"590\" height=\"744\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig6.jpg 590w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/04\/fig6-238x300.jpg 238w\" sizes=\"auto, (max-width: 590px) 100vw, 590px\" \/>\u0627\u0644\u0634\u0643\u0644 (6) \u0627\u0644\u0635\u064a\u063a\u0629 \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u062a\u0627\u0644\u064a\u0647 Zn(II),Cd(II), and Hg(II)\u00a0\u00a0(1).M=Zn.\u00a0(2). M=Cd.\u00a0(3). M=Hg.<\/span><\/h4>\n<hr \/>\n<h4 style=\"direction: ltr\"><\/h4>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">Preparation and identification of new compound of L-Ascorbic acid with some metal complexes<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">Ala Hussein Hassan<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">Assist.prof. Dr. Waleed K.Mahdi<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">Aim of work<\/span><\/h3>\n<ol>\n<li style=\"direction: ltr\">\n<h3><span style=\"color: #993366\">Synthesis and characterization of new azido ligand derived from L-ascorbic acid .<\/span><\/h3>\n<\/li>\n<li style=\"direction: ltr\">\n<h3><span style=\"color: #993366\">Synthesis of Clusters metal complexes [VO(II) ,Cr(III) , Mn (II) , Co(II) , Ni(II) , Cu(II) , Zn(II) , Cd(II) and Hg(II)] with new ligand (L-AZD) and their characterization by TLC, elemental analysis (C.H.N), 1H-NMR, FT-IR, UV-Vis and Mass spectra.<\/span><\/h3>\n<\/li>\n<li style=\"direction: ltr\">\n<h3><span style=\"color: #993366\">Recent studies have shown that these kinds of clusters have benefits and scientific applications for example medicine and pharmacy as drug in addition to being the best source of energy because it is containing azide group.<\/span><\/h3>\n<\/li>\n<li style=\"direction: ltr\">\n<h3><span style=\"color: #993366\">Give an interest to the future study of the biological activity of this kind of compounds and complexes because of it is good solubility in water and containing an active groups in their structure such as azide and carbonyl azide which can be effective on different kinds of bacteria.<\/span><\/h3>\n<\/li>\n<\/ol>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Abstract<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 The new tri nuclear coordination cluster in the following manner<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">\u00a0(L-AZD) was prepared via reaction of LAsCl2 with six moles of sodium azide in ethanol with drops of water. The product has empirical formula :-<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">C13H16N18O9<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 The (L-AZD) was characterized by TLC chromatography, elemental microanalysis (C.H.N), 1H-NMR experimental and theoretical according to chem office program, FT-IR spectra, U.v-visble and mass spectra. New cluster complexes\u00a0 ligand of (L-AZD) with VO(II) ,Cr(III), Mn(II),Co(II) ,Ni(II),Cu(II),Zn(II),Cd(II), and Hg(II) ions ware prepared by the reaction of metal chlorides except VOSO4.H2O with (L-AZD) with ratio\u00a0 (M:L) (3:1) giving the following molecular formula:-<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">\u00a0[(VO)3 (L-AZD)(H2O)2(SO4)2]SO4.3H2O<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">[Cr3(L-AZD)(H2O)2Cl8]Cl.2H2O.C2H5OH<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">[Mn3(L-AZD)(H2O)5Cl5]Cl.4H2O.2C2H5OH<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">[Co3(L-AZD)(H2O)5Cl5]Cl. H2O.2C2H5OH<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">[Ni3(L-AZD)(H2O)5Cl5]Cl<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">[Cu3(L-AZD)(H2O) Cl5]Cl. 4H2O<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">[Zn3(L-AZD)Cl5]Cl<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">[Cd3(L-AZD)(H2O) Cl5]Cl<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">[Hg3(L-AZD)(H2O)Cl5]Cl.25H2O<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 New clusters complexes were identified by UV and visible spectra, infrared spectra (FT-IR), magnetic susceptibility at room temperature. The molar ratio of the complexes VO(II) ,Cr(III), Mn(II), Cu(II),Zn(II),Cd(II), and Hg(II) , molar conductance measurements and atomic absorption to find the percentage of metal content in the complexes. All the metal complexes of (L-AZD) ligand coordinate to metal ions through terminal azido and carbonyl azide groups with Cr(III), Mn(II), Co(II) and Ni(II) except Vo(II),Cu(II),Zn(II),Cd(II) and Hg(II) were coordinated through azide. The complexes of Cr(III), Mn(II),Co(II) and Ni(II) have an (octahedral) geometry . The VO (II) has an (square pyramidal) geometry , while Zn (II), Cd (II), and Hg (II) showed a (tetrahedral) geometry and Cu(II) have (square planar) geometry, Theoretical electronic structure of (L-AZD) and\u00a0 complexes were carried out by applying the program of \u00a0chem office 2016,3DX to visualize the shapes of the ligand and their complexes and probability of coordinated sites as shown below :-<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">Figure (1) The proposed molecular structure of (L-AZD)<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">Figure (2) The complex VO(II)ion<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">Figure (3) The complex Cr(III) ion<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">Figure (4) The complexes Mn(II),Co(II) and Ni(II) metal ions.<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">(1).M=Mn.<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">(2).M=Co.<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">(3). M=Ni.<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">Figure (5) The complex Cu(II) ion<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">Figure (6) The complexes Zn(II),Cd(II), and Hg(II)metal ions<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">\u00a0(1).M=Zn.<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">(2).M=Cd.<\/span><\/h3>\n<h3 style=\"direction: ltr\"><span style=\"color: #993366\">(3).M=Hg.<\/span><\/h3>\n<h3 style=\"direction: ltr\"><\/h3>\n","protected":false},"excerpt":{"rendered":"<p>\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0645\u0631\u0643\u0628 \u062c\u062f\u064a\u062f \u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0623\u0633\u0643\u0648\u0631\u0628\u064a\u0643 \u0645\u0639&#8230;.<a class=\"cz_readmore\" href=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=25697\"><i class=\"fa fa-angle-left\" aria-hidden=\"true\"><\/i><span>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":25701,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-25697","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/25697","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=25697"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/25697\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/25701"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=25697"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=25697"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=25697"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}