{"id":27219,"date":"2019-07-02T11:38:59","date_gmt":"2019-07-02T08:38:59","guid":{"rendered":"http:\/\/ihcoedu.uobaghdad.edu.iq\/?p=27219"},"modified":"2019-07-03T09:47:56","modified_gmt":"2019-07-03T06:47:56","slug":"%d9%82%d8%b3%d9%85-%d8%a7%d9%84%d9%83%d9%8a%d9%85%d9%8a%d8%a7%d8%a1-%d9%8a%d9%86%d8%a7%d9%82%d8%b4-%d8%a7%d8%b7%d8%b1%d9%88%d8%ad%d8%a9-%d8%af%d9%83%d8%aa%d9%88%d8%b1%d8%a7%d9%87-%d8%aa%d8%af%d8%b1-2","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=27219","title":{"rendered":"\u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u064a\u0646\u0627\u0642\u0634 \u0627\u0637\u0631\u0648\u062d\u0629 \u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u062a\u062f\u0631\u0633 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0635\u0628\u0627\u063a \u0623\u0644\u0622\u0632\u0648 \u0645\u0639 \u0623\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0641\u0644\u0632\u064a\u0629"},"content":{"rendered":"<h4><\/h4>\n<h4><span style=\"color: #000080\"><strong>\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631\u060c \u062a\u0634\u062e\u064a\u0635 \u0648\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0635\u0628\u0627\u063a \u0623\u0644\u0622\u0632\u0648 \u0645\u0639 \u0623\u064a\u0648\u0646\u0627\u062a \u0628\u0639\u0636 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0641\u0644\u0632\u064a\u0629) \u0644\u0644\u0637\u0627\u0644\u0628\u0629 (<\/strong>\u062c\u0646\u0627\u0646 \u0645\u062d\u0645\u062f \u0645\u062d\u0645\u0648\u062f) \u0627\u0644\u062a\u064a \u0627\u0646\u062c\u0632\u062a\u0647\u0627 \u0628\u0627\u0634\u0631\u0627\u0641 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a \u0641\u064a \u0627\u0644\u0642\u0633\u0645 (\u0623.\u062f. \u0639\u0627\u0645\u0631 \u062c\u0628\u0627\u0631 \u062c\u0631\u0627\u062f) .<\/span><\/h4>\n<h4><span style=\"color: #000080\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-27223\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/DSC_0307.jpg\" alt=\"\" width=\"800\" height=\"523\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/DSC_0307.jpg 800w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/DSC_0307-300x196.jpg 300w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/DSC_0307-768x502.jpg 768w\" sizes=\"auto, (max-width: 800px) 100vw, 800px\" \/><\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0648\u0646\u0648\u0642\u0634\u062a \u0639\u0644\u0649 \u0642\u0627\u0639\u0629 \u0627\u0644\u0645\u0631\u062d\u0648\u0645 (\u0623.\u062f. \u0641\u0647\u062f \u0639\u0644\u064a \u062d\u0633\u064a\u0646) \u0645\u0646 \u0642\u0628\u0644 \u0627\u0639\u0636\u0627\u0621 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u0645\u062f\u0631\u062c\u0629 \u0627\u0633\u0645\u0627\u0626\u0647\u0645 \u0641\u064a \u0645\u0627 \u064a\u0644\u064a:<\/span><\/h4>\n<ul>\n<li><span style=\"color: #000080\"><strong>\u00a0<\/strong><\/span><strong style=\"color: #000080\">\u0623.\u062f. \u0633\u0627\u062c\u062f \u0645\u062d\u0645\u0648\u062f \u0644\u0637\u064a\u0641 \u0631\u0626\u064a\u0633\u0627.<\/strong><\/li>\n<li>\n<h4><span style=\"color: #000080\"><strong>\u0623.\u062f. \u0639\u0628\u0627\u0633 \u0639\u0644\u064a \u0635\u0627\u0644\u062d \u0639\u0636\u0648\u0627\u064b.<\/strong><\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\"><strong>\u0623.\u062f. \u062d\u064a\u062f\u0631 \u062d\u0645\u064a\u062f \u0645\u062d\u0633\u0646 \u0639\u0636\u0648\u0627\u064b.<\/strong><\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\"><strong>\u0623.\u0645.\u062f. \u0637\u0627\u0631\u0642 \u062d\u0633\u064a\u0646 \u0645\u063a\u064a\u0631 \u0639\u0636\u0648\u0627\u064b.<\/strong><\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\"><strong>\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062e\u0627\u0644\u062f \u0639\u0628\u062f \u0627\u0644\u0643\u0631\u064a\u0645 \u0639\u0636\u0648\u0627\u064b.<\/strong><\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\"><strong>\u0623.\u062f. \u0639\u0627\u0645\u0631 \u062c\u0628\u0627\u0631 \u062c\u0648\u0627\u062f \u0639\u0636\u0648\u0627\u064b.<\/strong><\/span><\/h4>\n<\/li>\n<\/ul>\n<h4><span style=\"color: #000080\"><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-27222\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/DSC_0309.jpg\" alt=\"\" width=\"800\" height=\"533\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/DSC_0309.jpg 800w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/DSC_0309-300x200.jpg 300w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/DSC_0309-768x512.jpg 768w\" sizes=\"auto, (max-width: 800px) 100vw, 800px\" \/>\u00a0<\/strong><\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0628\u0627\u0644\u0646\u0638\u0631 \u0644\u0644\u0627\u0633\u062a\u0639\u0645\u0627\u0644\u0627\u062a \u0627\u0644\u0648\u0627\u0633\u0639\u0629 \u0644\u0645\u0631\u0643\u0628\u0627\u062a \u0627\u0644\u0627\u0632\u0648 \u0627\u0644\u0639\u0636\u0648\u064a\u0629 \u0648\u0627\u0645\u062a\u062f\u0627\u062f \u0644\u0628\u062d\u0648\u062b \u0633\u0627\u0628\u0642\u0629 \u0627\u0644\u062a\u064a \u062c\u0631\u062a \u0641\u064a \u0645\u062e\u062a\u0628\u0631\u0646\u0627 \u0641\u0642\u062f \u0634\u0645\u0644 \u0627\u0644\u0647\u062f\u0641 \u0645\u0646 \u0627\u0644\u0628\u062d\u062b \u0645\u0627\u064a\u0644\u064a:-<\/span><\/h4>\n<ol>\n<li>\n<h4><span style=\"color: #000080\">\u062a\u062d\u0636\u064a\u0631 \u0639\u062f\u062f \u0645\u0646 \u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0627\u0632\u0648 \u0627\u0644\u0639\u0636\u0648\u064a\u0629 \u0648\u062a\u0634\u062e\u064a\u0635\u0647\u0627 \u0628\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0645\u062a\u0627\u062d\u0629.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0645\u0632\u062c \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 [Co<sup>\u0406\u0406<\/sup>, Ni<sup>\u0406\u0406<\/sup>, Cu<sup>II<\/sup> and Zn<sup>\u0406\u0406<\/sup>] \u0645\u0639 \u0645\u062d\u0627\u0644\u064a\u0644 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0645\u0646\u0647\u0627 \u062a\u062b\u0628\u064a\u062a \u0627\u0644\u0638\u0631\u0648\u0641 \u0627\u0644\u0645\u062b\u0644\u0649 \u0645\u0646 \u062a\u0631\u0643\u064a\u0632 \u0648\u062f\u0627\u0644\u0629 \u062d\u0627\u0645\u0636\u064a\u0629 \u0648\u0646\u0633\u0628\u0629 \u0627\u0644\u0641\u0644\u0632 \u0627\u0644\u0649 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0644\u063a\u0631\u0636 \u062a\u062d\u0636\u064a\u0631 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0635\u0644\u0628\u0629 \u0644\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0639\u0644\u0627\u0647.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u062a\u0634\u062e\u064a\u0635 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0628\u0627\u0644\u0637\u0631\u0627\u0626\u0642 \u0627\u0644\u0637\u064a\u0641\u064a\u0629 \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644\u064a\u0629 \u0648\u062f\u0631\u0627\u0633\u0629 \u062b\u0648\u0627\u0628\u062a \u0627\u0633\u062a\u0642\u0631\u0627\u0631\u064a\u062a\u0647\u0627.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u0641\u0644\u0632\u064a\u0629.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u0648\u0627\u062e\u064a\u0631\u0627 \u062f\u0631\u0627\u0633\u0629 \u0642\u062f\u0631\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0639\u0644\u0649 \u0635\u0628\u0627\u063a\u0629 \u0627\u0644\u0627\u0646\u0633\u062c\u0629 \u0648\u0645\u0642\u062f\u0627\u0631 \u062b\u0628\u0627\u062a \u0647\u0630\u0629 \u0627\u0644\u0635\u0628\u063a\u0627\u062a \u062a\u062c\u0627\u0647 \u0627\u0644\u0636\u0648\u0621 \u0648\u0627\u0644\u063a\u0633\u064a\u0644 \u0648\u0627\u0644\u0645\u0646\u0638\u0641\u0627\u062a.<\/span><\/h4>\n<\/li>\n<\/ol>\n<h4><span style=\"color: #000080\"><strong>\u00a0<\/strong><\/span><\/h4>\n<h4><span style=\"color: #000080\">\u062a\u062a\u0636\u0645\u0646 \u0647\u0630\u0629 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u062d\u0636\u064a\u0631 \u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0622\u0632\u0648 \u062c\u062f\u064a\u062f\u0629 (L<sub>1<\/sub>-L<sub>4<\/sub>) \u0625\u0631\u062a\u0643\u0632\u062a \u062c\u0645\u064a\u0639\u0647\u0627 \u0639\u0644\u0649 <\/span><br \/>\n<span style=\"color: #000080\">4-\u0627\u0645\u064a\u0646\u0648 \u0627\u0646\u062a\u064a\u0628\u064a\u0631\u064a\u0646 \u06482-\u0627\u0645\u064a\u0646\u0648 \u0628\u0646\u0632\u0648\u062b\u064a\u0644\u0632\u0648\u0644\u060c \u062a\u0645\u062a\u0644\u0643 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0627\u0644\u0622\u062a\u064a\u0629:<\/span><\/h4>\n<h4><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-27220\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/12345.jpg\" alt=\"\" width=\"500\" height=\"538\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/12345.jpg 358w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/12345-279x300.jpg 279w\" sizes=\"auto, (max-width: 500px) 100vw, 500px\" \/><\/h4>\n<h4><span style=\"color: #000080\">\u00a0 \u0634\u062e\u0635\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0628\u0623\u0633\u062a\u062e\u062f\u0627\u0645 (IR, UV-Vis, <sup>1<\/sup>H and <sup>13<\/sup>CNMR) \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0643\u0645\u064a \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631C.H.N))\u060c \u0641\u0636\u0644\u0627\u064b \u0639\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u0623\u0646\u0635\u0647\u0627\u0631. \u062d\u0636\u0640\u0631\u062a \u0645\u062c\u0645\u0640\u0648\u0639\u0640\u0640\u0629 \u0645\u0640\u0640\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0644\u0623\u064a\u0640\u0648\u0646\u0640\u0640\u0627\u062a \u0627\u0644\u0641\u0640\u0644\u0632\u064a\u0640\u0640\u0640\u0629 (Cu<sup>II<\/sup>, Ni<sup>II<\/sup>, Co<sup>II<\/sup> \u0648Zn<sup>II<\/sup>) \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a (L<sub>1<\/sub>-L<sub>4<\/sub>). \u0628\u0639\u062f \u062a\u062b\u0628\u064a\u062a \u0627\u0644\u0638\u0631\u0648\u0641 \u0627\u0644\u0645\u062b\u0644\u0649 \u0645\u0646 \u062f\u0627\u0644\u0629 \u062d\u0627\u0645\u0636\u064a\u0629 \u0648\u062a\u0631\u0643\u064a\u0632 \u0645\u0648\u0644\u0627\u0631\u064a \u0645\u0646 \u062e\u0644\u0627\u0644 \u062f\u0631\u0627\u0633\u0629 \u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0640\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629- \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0645\u0632\u062c \u0627\u0644\u0623\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0645\u0639 \u0645\u062d\u0627\u0644\u064a\u0644 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0623\u0639\u0644\u0627\u0647 \u0648\u0644\u0645\u062f\u0649 \u0648\u0627\u0633\u0639 \u0645\u0646 \u0627\u0644\u062f\u0627\u0644\u0629 \u0627\u0644\u062d\u0627\u0645\u0636\u064a\u0629 \u0648\u0627\u0644\u062a\u0631\u0627\u0643\u064a\u0632 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0627\u0644\u062e\u0627\u0636\u0639\u0629 \u0644\u0642\u0627\u0646\u0648\u0646 \u0644\u0627\u0645\u0628\u0631\u062a- \u0628\u064a\u0631\u060c \u0648\u0642\u062f \u0625\u062e\u062a\u0644\u0641\u062a \u0638\u0631\u0648\u0641 \u0627\u0644\u062a\u062d\u0636\u064a\u0631 \u0628\u0625\u062e\u062a\u0644\u0627\u0641 \u0627\u0644\u0623\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0644\u0645\u0633\u062a\u062e\u062f\u0645\u0629.<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u00a0 \u0627\u0633\u062a\u062e\u062f\u0645\u062a \u0637\u0631\u064a\u0642\u062a\u064a \u0627\u0644\u0646\u0633\u0628 \u0627\u0644\u0645\u0648\u0644\u064a\u0629 \u0648\u0637\u0631\u064a\u0642\u0629 \u062c\u0648\u0628 \u0644\u0644\u062a\u0639\u0631\u0641 \u0639\u0644\u0649 \u062a\u0631\u0627\u0643\u064a\u0628 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629\u00a0 \u0648\u0648\u062c\u062f \u0623\u0646 \u0646\u0633\u0628\u0629 \u0627\u0644\u0641\u0644\u0632: \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0647\u064a (2:1). \u0623\u0645\u0627 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0632\u064a\u062c \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0641\u0642\u062f \u0643\u0627\u0646\u062a \u0627\u0644\u0646\u0633\u0628\u0629 (1:1:1) (\u0641\u0644\u0632:L:L).<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u00a0 \u0634\u062e\u0635\u062a \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0628\u0648\u0633\u0627\u0637\u0629 \u0623\u0637\u064a\u0627\u0641UV-Vis \u0648IR \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0643\u0645\u064a \u0627\u0644\u062f\u0642\u064a\u0642\u0644\u0644\u0639\u0646\u0627\u0635\u0631C.H.N))\u060c \u0648\u0642\u064a\u0633\u062a \u0627\u0644\u0646\u0633\u0628\u0629 \u0627\u0644\u0645\u0626\u0648\u064a\u0629 \u0644\u0644\u0641\u0644\u0632 \u0628\u0625\u0633\u062a\u062e\u062f\u0627\u0645 \u0637\u064a\u0641 \u0627\u0644\u0625\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0627\u0644\u0644\u0647\u0628\u064a \u0648\u0627\u0644\u062a\u062d\u0627\u0644\u064a\u0644 \u0627\u0644\u0641\u064a\u0632\u064a\u0627\u0648\u064a\u0629 \u0648\u0639\u064a\u0646\u062a \u062f\u0631\u062c\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0645\u0648\u0635\u0644\u064a\u062a\u0647\u0627 \u0627\u0644\u0643\u0647\u0631\u0628\u0627\u0626\u064a\u0629\u060c \u0641\u0636\u0644\u0627\u064b \u0639\u0646 \u0642\u064a\u0627\u0633 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u0625\u0646\u0635\u0647\u0627\u0631. \u0623\u0645\u0627 \u062f\u0631\u0627\u0633\u0629 \u062b\u0627\u0628\u062a \u0627\u0644\u062a\u0643\u0648\u064a\u0646 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0641\u0642\u062f \u0623\u0638\u0647\u0631\u062a \u0623\u0646 \u0645\u0639\u0638\u0645 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u062a\u062a\u0645\u062a\u0639 \u0628\u0625\u0633\u062a\u0642\u0631\u0627\u0631\u064a\u0629 \u0639\u0627\u0644\u064a\u0629. \u0627\u0633\u062a\u0646\u0627\u062f\u0627 \u0627\u0644\u0649 \u0627\u0644\u0646\u062a\u0627\u0626\u062c \u0627\u0644\u0645\u0633\u062a\u062d\u0635\u0644\u0629 \u0644\u0644\u062f\u0631\u0627\u0633\u0627\u062a \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0641\u0642\u062f \u062a\u0645 \u0623\u0642\u062a\u0631\u0627\u062d \u0627\u0644\u0634\u0643\u0644 \u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d\u00a0 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629.<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u00a0 \u0644\u0642\u062f \u062a\u0645 \u0627\u0644\u0625\u0641\u0627\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0642\u064a\u062f \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0641\u064a \u0625\u0645\u0643\u0627\u0646\u064a\u0629 \u0625\u0633\u062a\u062e\u062f\u0627\u0645\u0647\u0627 \u0643\u0623\u0635\u0628\u0627\u063a \u0644\u0635\u0628\u0627\u063a\u0629 \u0627\u0644\u0623\u0646\u0633\u062c\u0629 \u0627\u0644\u0642\u0637\u0646\u064a\u0629 \u0646\u0638\u0631\u0627\u064b \u0644\u0645\u0627 \u064a\u062a\u0645\u064a\u0632 \u0628\u0647 \u0645\u0646 \u0623\u0644\u0648\u0627\u0646 \u0632\u0627\u0647\u064a\u0629\u060c \u0648\u0642\u062f \u062a\u0628\u064a\u0646 \u0623\u0646 \u0623\u0644\u0648\u0627\u0646\u0647\u0627 \u062b\u0627\u0628\u062a\u0629 \u0648\u0630\u0627\u062a \u0645\u0642\u0627\u0648\u0645\u0629 \u0639\u0627\u0644\u064a\u0629 \u0644\u0644\u063a\u0633\u0644 \u0648\u0627\u0644\u0645\u0646\u0638\u0641\u0627\u062a \u0648\u0644\u0636\u0648\u0621 \u0627\u0644\u0634\u0645\u0633. \u0643\u0630\u0644\u0643 \u062a\u0645\u062a \u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0641\u0627\u0639\u0644\u064a\u0629 \u0627\u0644\u062d\u064a\u0648\u064a\u0629 \u0639\u0644\u0649 \u0627\u0646\u0648\u0627\u0639 \u0645\u062e\u062a\u0644\u0641\u0629 \u0645\u0646 \u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u0648\u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a.\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/span><\/h4>\n<h4><span style=\"color: #000080\"><strong>\u00a0<\/strong><\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a:-<\/span><\/h4>\n<ul>\n<li>\n<h4><span style=\"color: #000080\">\u062a\u062d\u0636\u064a\u0631 \u0645\u0639\u0642\u062f\u0627\u062a \u0641\u0644\u0632\u064a\u0629 \u062c\u062f\u064a\u062f\u0629 \u0648\u0630\u0644\u0644\u0643 \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u064a\u0648\u0646\u0627\u062a \u0641\u0644\u0632\u064a\u0629 \u0627\u062e\u0631\u0649.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0641\u064a \u0645\u062c\u0627\u0644 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0627\u0644\u062a\u062d\u0644\u064a\u0644\u064a\u0629 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0627\u0644\u062a\u0642\u062f\u064a\u0631 \u0627\u0644\u0637\u064a\u0641\u064a \u0644\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0634\u0639\u0629 \u0627\u0644\u0633\u064a\u0646\u064a\u0629 \u0641\u064a \u062a\u0634\u062e\u064a\u0635 \u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0627\u0632\u0648 \u0648\u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u0641\u0644\u0632\u064a\u0629.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u0627\u0645\u0643\u0627\u0646\u064a\u0629 \u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0627\u0632\u0648 \u0641\u064a \u0641\u0635\u0644 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a \u0628\u0648\u0633\u0627\u0637\u0629 \u0643\u0631\u0648\u0645\u0648\u062a\u0648\u063a\u0631\u0627\u0641\u064a\u0627 \u0627\u0644\u0639\u0645\u0648\u062f.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0627\u0646\u0632\u064a\u0645\u064a\u0629 \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0627\u0632\u0648 \u0648\u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u0641\u0644\u0632\u064a\u0629.<\/span><\/h4>\n<\/li>\n<\/ul>\n<h4><span style=\"color: #000080\"><strong>\u00a0<\/strong><\/span><\/h4>\n<hr \/>\n<hr \/>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\"><strong>\u00a0<\/strong><\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\"><strong>Synthesis, characterization and biological activity of azo dyes complexes with some metal ions<\/strong><\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\">Supervised : Prof. Dr. Amer J. Jarad\u00a0 \/ College of Education for pure science Ibn Al-Haitham \/ Department of Chemistry<\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\"><strong>\u00a0<\/strong><\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\"><strong>Aim of the work<\/strong><\/span><\/h4>\n<h4 style=\"direction: ltr;text-align: left\"><span style=\"color: #000080\">Given the widespread use of organic azo compounds and the extension of previous research conducted in our laboratory, our objectives have also expanded to include.<\/span><\/h4>\n<ul style=\"text-align: left\">\n<li style=\"direction: ltr\">\n<h4><span style=\"color: #000080\">Preparation and characterization of a number of organic ligands in the available methods.<\/span><\/h4>\n<\/li>\n<li style=\"direction: ltr\">\n<h4><span style=\"color: #000080\">Spectroscopic study of [Co<sup>\u0406\u0406<\/sup>, Ni<sup>\u0406\u0406<\/sup>, Cu<sup>II<\/sup> and Zn<sup>\u0406\u0406<\/sup>] mixtures with the prepared ligand solution. The optimum conditions of concentration, pH and metal content are determined: Ligand:Metal for the preparation of the solid complexes metal ions of the above.<\/span><\/h4>\n<\/li>\n<li style=\"direction: ltr\">\n<h4><span style=\"color: #000080\">Characterization of complexes in spectral and analytical techniques and study the constants of their stability.<\/span><\/h4>\n<\/li>\n<li style=\"direction: ltr\">\n<h4><span style=\"color: #000080\">Studying the biological activity for the prepared ligands and their metal complexes.<\/span><\/h4>\n<\/li>\n<li style=\"direction: ltr\">\n<h4><span style=\"color: #000080\">Finally, studying the ability of the prepared ligands and their complexes to dye the tissue and the amount of stability of these pigments towards light, washing and detergents.<\/span><\/h4>\n<\/li>\n<\/ul>\n<h4 style=\"direction: ltr;text-align: left\"><\/h4>\n<h4 style=\"direction: ltr;text-align: left\"><span style=\"color: #000080\"><strong>Recommendations<\/strong><\/span><\/h4>\n<ul style=\"text-align: left\">\n<li style=\"direction: ltr\">\n<h4><span style=\"color: #000080\">Produced new metal complexes by using other metal ions.<\/span><\/h4>\n<\/li>\n<li style=\"direction: ltr\">\n<h4><span style=\"color: #000080\">Azo dyes are used in analytical chemistry for determination of metal ions.<\/span><\/h4>\n<\/li>\n<li style=\"direction: ltr\">\n<h4><span style=\"color: #000080\">Using X-ray technique to complete the characterized of the azo ligands and their metal complexes.<\/span><\/h4>\n<\/li>\n<li style=\"direction: ltr\">\n<h4><span style=\"color: #000080\">Investigated the possibility for using the azo ligands in separation of metal ions by column chromatography.<\/span><\/h4>\n<\/li>\n<li style=\"direction: ltr\">\n<h4><span style=\"color: #000080\">Studies the enzymes activity for the produced azo ligands and their metal chelates.<\/span><\/h4>\n<\/li>\n<\/ul>\n<h4 style=\"direction: ltr;text-align: left\"><span style=\"color: #000080\"><strong>Summary<\/strong><\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\">\u00a0\u00a0 New azo ligands (L<sub>1<\/sub>-L<sub>4<\/sub>) have been produced all rest on the 4-amino-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one and benzo[d] thiazol-2-amine as a back-bone of the prepared ligands\u00a0 having the following structures.<\/span><\/h4>\n<h4><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-27220\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/12345.jpg\" alt=\"\" width=\"500\" height=\"538\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/12345.jpg 358w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/07\/12345-279x300.jpg 279w\" sizes=\"auto, (max-width: 500px) 100vw, 500px\" \/><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\">\u00a0Produced azo ligands have been characterized by melting points measurements, (IR, <sup>1<\/sup>H, <sup>13<\/sup>CNMR, and UV-Vis) spectra and (C.H.N) analysis.<\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\">\u00a0The other part of this project refer to the synthesis of metal chelates Co<sup>II<\/sup>, Ni<sup>II<\/sup>, Cu<sup>II<\/sup> and Zn<sup>II<\/sup> with all prepared azo ligands.<\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\">\u00a0 All production was performed after fixing the ideal pH and molar concentration that obeyed Lambert- Beer\u2019s law in the studies pH rates.<\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\">\u00a0 According to the molar ratio and Job methods, the structure of these metal chelates was deduced depending on the spectroscopic studies of the complex solution of the above ions. However, ration of 1:2 M:L for all ions were obtained. The mole ratio of mixed ligand complexes was 1:1:1(M:L:L).\u00a0<\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\">\u00a0IR, UV-Vis spectra, conductivity, magnetic susceptibility and melting points measurements using to characterize of prepared complexes.<\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\">Flameless atomic absorption technique has been measured to calculate the percentage of the metals in the complexes. (C.H.N.) analysis were also found, the results are in agreement with the calculated values. All the complexes are quite stable and could be stored for months without any appreciable change.<\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\">\u00a0Depending to the results obtained by elemental and spectral analysis, an octahedral structure suggested for all produced complexes.<\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\">\u00a0 In addition the dyeing performance of the produced compound have been assessed on cotton fabric, the dyes were tested for light and detergent fastness.\u00a0<\/span><\/h4>\n<h4 style=\"direction: ltr\"><span style=\"color: #000080\">\u00a0 Finally azo ligand and newly metal chelats were screened in vitro for their antibacterial and antifungal activity against: <em>Staphylococcus aureus, Esherichia Coli<\/em>,<em> Candida albicans<\/em>and<em> Candida tropicalis<\/em><\/span><\/h4>\n<h4 style=\"direction: ltr\"><\/h4>\n","protected":false},"excerpt":{"rendered":"<p>\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631\u060c \u062a\u0634\u062e\u064a\u0635 \u0648\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0635\u0628\u0627\u063a&#8230;.<a class=\"cz_readmore\" href=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=27219\"><i class=\"fa fa-angle-left\" aria-hidden=\"true\"><\/i><span>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":27221,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-27219","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/27219","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=27219"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/27219\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/27221"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=27219"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=27219"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=27219"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}