{"id":28384,"date":"2019-11-21T12:11:37","date_gmt":"2019-11-21T09:11:37","guid":{"rendered":"http:\/\/ihcoedu.uobaghdad.edu.iq\/?p=28384"},"modified":"2019-11-30T06:51:27","modified_gmt":"2019-11-30T03:51:27","slug":"%d9%82%d8%b3%d9%85-%d8%a7%d9%84%d9%83%d9%8a%d9%85%d9%8a%d8%a7%d8%a1-%d9%8a%d9%86%d8%a7%d9%82%d8%b4-%d8%b1%d8%b3%d8%a7%d9%84%d8%a9-%d9%85%d8%a7%d8%ac%d8%b3%d8%aa%d9%8a%d8%b1-%d8%aa%d8%a8%d8%ad%d8%ab-10","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=28384","title":{"rendered":"\u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u064a\u0646\u0627\u0642\u0634 \u0631\u0633\u0627\u0644\u0629 \u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u062a\u0628\u062d\u062b \u0641\u064a \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0628\u0639\u0636 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0644\u0627\u062f\u0648\u064a\u0629 \u0645\u062e\u062a\u0627\u0631\u0629"},"content":{"rendered":"<h4><span style=\"color: #000080\"><strong>\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0645\u0629 (<\/strong>\u062a\u062d\u0636\u064a\u0631 , \u062a\u0634\u062e\u064a\u0635 \u0648\u062a\u0642\u064a\u064a\u0645 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0628\u0639\u0636 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0645\u0639 \u0627\u062f\u0648\u064a\u0629 \u0645\u062e\u062a\u0627\u0631\u0629 (\u0644\u0644\u0637\u0627\u0644\u0628\u0629 (\u0633\u062c\u0649 \u0627\u062d\u0645\u062f \u0639\u0628\u062f \u0627\u0644\u0644\u0647) \u0627\u0644\u062a\u064a \u0627\u0646\u062c\u0632\u062a\u0647\u0627 \u062a\u062d\u062a \u0627\u0634\u0631\u0627\u0641 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a\u0629 \u0641\u064a \u0627\u0644\u0642\u0633\u0645 (\u0623.\u062f. \u062a\u063a\u0631\u064a\u062f \u0647\u0627\u0634\u0645 \u0627\u0644\u0646\u0648\u0631) .<\/span><\/h4>\n<p><span style=\"text-decoration: underline\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-28513\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/11\/IMG_20191130_064954.jpg\" alt=\"\" width=\"960\" height=\"744\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/11\/IMG_20191130_064954.jpg 960w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/11\/IMG_20191130_064954-300x233.jpg 300w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/11\/IMG_20191130_064954-768x595.jpg 768w\" sizes=\"auto, (max-width: 960px) 100vw, 960px\" \/><\/span><\/p>\n<p>&nbsp;<\/p>\n<h4><span style=\"color: #000080\">\u0648\u0646\u0648\u0642\u0634\u062a \u0627\u0644\u0631\u0633\u0627\u0644\u0629 \u0645\u0646 \u0642\u0628\u0644 \u0627\u0639\u0636\u0627\u0621 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 :<\/span><\/h4>\n<ul>\n<li>\n<h4><span style=\"color: #000080\">\u0627.\u062f \u0627\u062d\u0645\u062f \u062b\u0627\u0628\u062a \u0646\u0639\u0645\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u0631\u0626\u064a\u0633\u0627\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u0627.\u062f \u0639\u0645\u0631 \u062d\u0645\u062f \u0634\u0647\u0627\u0628\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u0639\u0636\u0648\u0627<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u0627.\u0645.\u062f \u0637\u0627\u0631\u0642 \u062d\u0633\u064a\u0646 \u0627\u0644\u0645\u063a\u064a\u0631\u00a0 \u00a0 \u00a0\u0639\u0636\u0648\u0627<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u0627.\u062f \u062a\u063a\u0631\u064a\u062f \u0647\u0627\u0634\u0645 \u0627\u0644\u0646\u0648\u0631\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u0639\u0636\u0648\u0627 \u0648\u0645\u0634\u0631\u0641\u0627<\/span><\/h4>\n<\/li>\n<\/ul>\n<h4><span style=\"color: #000080\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-28389\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/11\/DSC_0700.jpg\" alt=\"\" width=\"800\" height=\"512\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/11\/DSC_0700.jpg 800w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/11\/DSC_0700-300x192.jpg 300w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2019\/11\/DSC_0700-768x492.jpg 768w\" sizes=\"auto, (max-width: 800px) 100vw, 800px\" \/><\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0648\u064a\u0647\u062f\u0641 \u0627\u0644\u0628\u062d\u062b \u0627\u0644\u0649 :<\/span><\/h4>\n<ol>\n<li>\n<h4><span style=\"color: #000080\">\u062a\u062d\u0636\u064a\u0631 \u0628\u0639\u0636 \u0627\u0644\u064a\u0643\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062e\u0644\u0648\u0637\u0629 (sulfamethoxazole)\u0648 ( Valine\u00a0 and proline).<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u062a\u062d\u062f\u064a\u062f \u0627\u0634\u0643\u0627\u0644 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0648\u0627\u0633\u0637\u0629 \u062a\u0642\u0646\u064a\u0627\u062a (FTIR , Electronic spectra , Magnetic moment measurement, molar conductance).<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u0642\u064a\u0627\u0633 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0644\u0648\u062c\u064a\u0629 \u0644\u0647\u0630\u0627 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629.<\/span><\/h4>\n<\/li>\n<\/ol>\n<h4><span style=\"color: #000080\"><strong>\u00a0<\/strong><\/span><\/h4>\n<h4><span style=\"color: #000080\">\u062a\u0636\u0645\u0646 \u0627\u0644\u0628\u062d\u062b \u062a\u062d\u0636\u064a\u0631 \u0645\u062c\u0645\u0648\u0639\u0629 \u0645\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0627\u062a\u064a\u0629 :<\/span><\/h4>\n<ol>\n<li>\n<h4><span style=\"color: #000080\">\u0645\u0639\u0642\u062f\u0627\u062a \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u00a0:\u062a\u0645 \u0627\u0633\u062a\u0639\u0645\u0627\u0644 <strong>)<\/strong>\u0627\u0644\u0645\u0636\u0627\u062f \u0627\u0644\u062d\u064a\u0648\u064a\u00a0 \u00a0\u00a0( \u0627\u0644\u0633\u0644\u0641\u0627\u0645\u064a\u062b\u0627\u0643\u0632\u0648\u0644\u00a0 <strong>(SMZ)<\/strong>\u00a0 \u00a0\u0643\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0648\u0644\u064a \u0645\u0639 \/ \u0623\u0648\u00a0 \u0644-\u0627\u0644\u0628\u0631\u0648\u0644\u064a\u0646 <strong>( L-ProH)<\/strong>, \u0648 \u0644-\u0627\u0644\u0641\u0627\u0644\u064a\u0646<strong>( L-ValH)<\/strong> \u0643\u0644\u064a\u0643\u0627\u0646\u062f \u062b\u0627\u0646\u0648\u064a\u00a0 \u0645\u0639 \u00a0\u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a M(II) \u0648 M\u2032 (III) \u0643\u0645\u0627 \u062a\u0645 \u0627\u062f\u0631\u0627\u062c\u0647 \u0641\u064a \u0627\u0644\u062c\u062f\u0648\u0644 \u0627\u0644\u0627\u062a\u064a :<\/span><\/h4>\n<\/li>\n<\/ol>\n<table width=\"100%\">\n<tbody>\n<tr>\n<td width=\"23%\">\n<h4><span style=\"color: #000080\"><strong>Type<\/strong><\/span><\/h4>\n<h4><span style=\"color: #000080\"><strong>Mixed ligand<\/strong><\/span><\/h4>\n<h4><span style=\"color: #000080\"><strong>complexes<\/strong><\/span><\/h4>\n<\/td>\n<td width=\"20%\">\n<h4><span style=\"color: #000080\"><strong>Primary<\/strong><\/span><\/h4>\n<h4><span style=\"color: #000080\"><strong>ligand<\/strong><\/span><\/h4>\n<\/td>\n<td width=\"17%\">\n<h4><span style=\"color: #000080\"><strong>Secondary<\/strong><\/span><\/h4>\n<h4><span style=\"color: #000080\"><strong>Ligand<\/strong><\/span><\/h4>\n<h4><span style=\"color: #000080\"><strong>amino acid<\/strong><\/span><\/h4>\n<\/td>\n<td width=\"38%\">\n<h4><span style=\"color: #000080\"><strong>Compositions<\/strong><\/span><\/h4>\n<\/td>\n<\/tr>\n<tr>\n<td rowspan=\"3\" width=\"23%\">\n<h4><span style=\"color: #000080\">Style\u00a0\u00a0 1<\/span><\/h4>\n<h4><span style=\"color: #000080\">SMZ- L ProH &#8211; M<\/span><\/h4>\n<h4><span style=\"color: #000080\">1.1.2<\/span><\/h4>\n<h4><span style=\"color: #000080\">1.1.1<\/span><\/h4>\n<\/td>\n<td width=\"20%\">\n<h4><span style=\"color: #000080\">Sulfamethoxazole<\/span><\/h4>\n<h4><span style=\"color: #000080\">(SMZ)<\/span><\/h4>\n<\/td>\n<td width=\"17%\">\n<h4><span style=\"color: #000080\">L-Proline<\/span><\/h4>\n<h4><span style=\"color: #000080\">( L-ProH)<\/span><\/h4>\n<\/td>\n<td width=\"38%\">\n<h4><span style=\"color: #000080\">[M (SMZ)( L-Pro)<sub>2<\/sub>]<\/span><\/h4>\n<h4><span style=\"color: #000080\">M= Mn(II), \u00a0Fe (II),Ni(II), Cu(II),Cd(II), Hg(II)and\u00a0\u00a0\u00a0\u00a0 Sn(II)<\/span><\/h4>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"20%\">\n<h4><span style=\"color: #000080\">Sulfamethoxazole<\/span><\/h4>\n<h4><span style=\"color: #000080\">(SMZ)<\/span><\/h4>\n<\/td>\n<td width=\"17%\">\n<h4><span style=\"color: #000080\">L-Proline<\/span><\/h4>\n<h4><span style=\"color: #000080\">( L-ProH)<\/span><\/h4>\n<\/td>\n<td width=\"38%\">\n<h4><span style=\"color: #000080\">[ M\u2032 (SMZ)( L-Pro)<sub>2<\/sub>]Cl<\/span><\/h4>\n<h4><span style=\"color: #000080\">M\u2032 =\u00a0 Al(III)\u00a0 ,Cr(III)\u00a0 and \u00a0Fe(III)<\/span><\/h4>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"20%\">\n<h4><span style=\"color: #000080\">Sulfamethoxazole<\/span><\/h4>\n<h4><span style=\"color: #000080\">(SMZ)<\/span><\/h4>\n<\/td>\n<td width=\"17%\">\n<h4><span style=\"color: #000080\">L-Proline<\/span><\/h4>\n<h4><span style=\"color: #000080\">( L-ProH)<\/span><\/h4>\n<\/td>\n<td width=\"38%\">\n<h4><span style=\"color: #000080\">[ Sn(SMZ)( L-Pro)]Cl<\/span><\/h4>\n<\/td>\n<\/tr>\n<tr>\n<td rowspan=\"2\" width=\"23%\">\n<h4><span style=\"color: #000080\">Style\u00a0 2<\/span><\/h4>\n<h4><span style=\"color: #000080\">SMZ. M. L-Val<\/span><\/h4>\n<h4><span style=\"color: #000080\">1.1.2<\/span><\/h4>\n<h4><\/h4>\n<\/td>\n<td width=\"20%\">\n<h4><span style=\"color: #000080\">Sulfamethoxazole<\/span><\/h4>\n<h4><\/h4>\n<h4><span style=\"color: #000080\">(SMZ)<\/span><\/h4>\n<\/td>\n<td width=\"17%\">\n<h4><span style=\"color: #000080\">L-Valine<\/span><\/h4>\n<h4><span style=\"color: #000080\">( L-ValH)<\/span><\/h4>\n<\/td>\n<td width=\"38%\">\n<h4><span style=\"color: #000080\">[M (SMZ)( L-Val)<sub>2<\/sub>]Cl<\/span><\/h4>\n<h4><span style=\"color: #000080\">M= Mn (II), Fe (II), Co(II),Ni(II), Cu(II), ,Cd(II), Hg(II) and Sn(II)<\/span><\/h4>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"20%\">\n<h4><span style=\"color: #000080\">Sulfamethoxazole<\/span><\/h4>\n<h4><span style=\"color: #000080\">(SMZ)<\/span><\/h4>\n<\/td>\n<td width=\"17%\">\n<h4><span style=\"color: #000080\">L-Valine<\/span><\/h4>\n<h4><span style=\"color: #000080\">( L-ValH)<\/span><\/h4>\n<\/td>\n<td width=\"38%\">\n<h4><span style=\"color: #000080\">[M\u2032 (SMZ)( \u00a0L-Val )<sub>2<\/sub>]Cl<\/span><\/h4>\n<h4><span style=\"color: #000080\">M\u2032 = Fe(III)\u00a0 ,Cr(III)\u00a0 and Al(III)<\/span><\/h4>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4><span style=\"color: #000080\"><strong>\u00a0<\/strong><\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0628 &#8211; \u0645\u0639\u0642\u062f\u0627\u062a \u0623\u062d\u0627\u062f\u064a\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u00a0 \u00a0:\u062a\u0645 \u0627\u0633\u062a\u0639\u0645\u0627\u0644\u00a0 \u0627\u0644\u0633\u0644\u0641\u0627\u0645\u064a\u062b\u0627\u0643\u0632\u0648\u0644\u00a0 <strong>(SMZ)<\/strong>\u00a0 \u0648 \u0644-\u0627\u0644\u0628\u0631\u0648\u0644\u064a\u0646 <strong>(L-ProH)<\/strong><strong>\u00a0\u00a0\u00a0\u00a0 <\/strong>\u00a0\u0648 \u0644-\u0627\u0644\u0641\u0627\u0644\u064a\u0646 <strong>( L-ValH)<\/strong> \u0643\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a\u00a0 \u0645\u0639 \u00a0\u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a M(II) \u0648 M\u2032 (III) \u0643\u0645\u0627 \u062a\u0645 \u0627\u062f\u0631\u0627\u062c\u0647 \u0641\u064a \u0627\u0644\u062c\u062f\u0648\u0644 \u0627\u0644\u0627\u062a\u064a\u00a0 :<\/span><\/h4>\n<table width=\"100%\">\n<tbody>\n<tr>\n<td width=\"18%\">\n<h4><span style=\"color: #000080\"><strong>Type<\/strong><\/span><\/h4>\n<\/td>\n<td width=\"38%\">\n<h4><span style=\"color: #000080\"><strong>ligands<\/strong><\/span><\/h4>\n<\/td>\n<td width=\"43%\">\n<h4><span style=\"color: #000080\"><strong>Compositions<\/strong><\/span><\/h4>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"18%\">\n<h4><span style=\"color: #000080\">Style 1<\/span><\/h4>\n<\/td>\n<td width=\"38%\">\n<h4><span style=\"color: #000080\">Sulfamethoxazole<\/span><\/h4>\n<h4><span style=\"color: #000080\">(SMZ)<\/span><\/h4>\n<\/td>\n<td width=\"43%\">\n<h4><span style=\"color: #000080\">[Sn(SMZ)<sub>2<\/sub>]Cl<sub>2<\/sub><\/span><\/h4>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"18%\">\n<h4><span style=\"color: #000080\">Style\u00a0 2<\/span><\/h4>\n<\/td>\n<td width=\"38%\">\n<h4><span style=\"color: #000080\">amino acid<\/span><\/h4>\n<h4><span style=\"color: #000080\">L-Proline ( L-ProH)<\/span><\/h4>\n<\/td>\n<td width=\"43%\">\n<h4><span style=\"color: #000080\">[Sn(L-Pro)<sub>2<\/sub>]<\/span><\/h4>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"18%\">\n<h4><span style=\"color: #000080\">Style\u00a0\u00a0 3<\/span><\/h4>\n<\/td>\n<td width=\"38%\">\n<h4><span style=\"color: #000080\">amino acid<\/span><\/h4>\n<h4><span style=\"color: #000080\">L-Valine\u00a0 ( L-ValH)<\/span><\/h4>\n<\/td>\n<td width=\"43%\">\n<h4><span style=\"color: #000080\">[Sn(L-Val)<sub>2<\/sub>]<\/span><\/h4>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"18%\">\n<h4><span style=\"color: #000080\">Style\u00a0\u00a0 4<\/span><\/h4>\n<\/td>\n<td width=\"38%\">\n<h4><span style=\"color: #000080\">Sulfamethoxazole (SMZ)<\/span><\/h4>\n<\/td>\n<td width=\"43%\">\n<h4><span style=\"color: #000080\">[ M\u2032(SMZ)<sub>3<\/sub>]Cl<sub>3<\/sub><\/span><\/h4>\n<h4><span style=\"color: #000080\">M\u2032=Fe(III),Cr(III) and Al(III)<\/span><\/h4>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4><\/h4>\n<h4><span style=\"color: #000080\">\u00a0\u00a0 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 (\u0631\u0627\u0633\u0628 \u0628\u0634\u0643\u0644 \u0628\u0627\u0648\u062f\u0631) \u062f\u0631\u0633\u062a \u0645\u0646 \u0627\u0644\u0646\u0648\u0627\u062d\u064a \u0627\u0644\u0622\u062a\u064a\u0629 :-<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u060c \u0627\u0644\u062f\u0631\u0627\u0633\u0627\u062a \u0627\u0644\u0637\u064a\u0641\u064a\u0629 (\u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621\u060c \u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629\u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648 \u0645\u0637\u064a\u0627\u0641\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a)\u00a0 \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0627\u0644\u0646\u062a\u0627\u0626\u062c \u0627\u0644\u062a\u064a \u062a\u0645 \u0627\u0644\u062d\u0635\u0648\u0644 \u0639\u0644\u064a\u0647\u0627 \u0645\u0646 \u0627\u0644\u062a\u0642\u0646\u064a\u0627\u062a \u0627\u0644\u0645\u062e\u062a\u0644\u0641\u0629\u060c<\/span><\/h4>\n<h4><\/h4>\n<h3 style=\"text-align: left\"><span style=\"color: #000080\">\u0643\u0645\u0627 \u062a\u0645 \u062a\u0642\u064a\u064a\u0645 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 (\u0627\u0644\u0645\u0636\u0627\u062f\u0629 \u0644\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u0648\u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a )\u00a0 \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u062d\u0631\u0629 \u0645\u0639 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0628\u0642\u064a\u0627\u0633 \u0645\u0646\u0637\u0642\u0629 \u0627\u0644\u062a\u062b\u0628\u064a\u0637\u00a0 (ZI).<\/span><\/h3>\n<hr \/>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Synthesis , characterization and biological activity studies of some metal ions with selective drug<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">By \u00a0Saja Ahmed Abdulla<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Supervised by . prof.Dr.Tagreed\u00a0 H. Al-Noor<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Aim of the Present Work<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Mixed ligands, and their coordination compounds which have played a great importance in medicine, bioinorganic chemistry and industry\/ Due tothese facts, aim of the present work deals with\u00a0 \u00a0<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">The synthesis of some mixed ligand sulfamethoxazole and L= Valine \u00a0and or L-proline then react with metal chloride of \u00a0[Cr III, FeIII , AlII, MnII, FeIII\u00a0 ,CoII, NiII, CuII, ZnII, CdII, HgIIandSn II]\u00a0 \u00a0complexes.<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">To determine structure of \u00a0\u00a0the products using different spectroscopic<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">techniques such as : FTIR , Electronic spectra , Magnetic moment measurement, and molar conductance for complexes<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">The ligands and their metal complexes have been tested against gram positive and <\/span><span style=\"color: #993366\">gram negative bacteria and pathogenic fungi<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Summary<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">The work in this thesisis described as follows<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">\u00a0A: Mixed-Ligand metal complexes<\/span><\/h3>\n<table class=\" alignleft\" width=\"100%\">\n<tbody>\n<tr>\n<td width=\"27%\">\n<h3><span style=\"color: #993366\">Type<\/span><\/h3>\n<h3><span style=\"color: #993366\">Mixed ligand<\/span><\/h3>\n<h3><span style=\"color: #993366\">complexes<\/span><\/h3>\n<\/td>\n<td width=\"20%\">\n<h3><span style=\"color: #993366\">Primary<\/span><\/h3>\n<h3><span style=\"color: #993366\">Ligand<\/span><\/h3>\n<\/td>\n<td width=\"16%\">\n<h3><span style=\"color: #993366\">Secondary<\/span><\/h3>\n<h3><span style=\"color: #993366\">Ligand<\/span><\/h3>\n<h3><span style=\"color: #993366\">aminoacid<\/span><\/h3>\n<\/td>\n<td width=\"35%\">\n<h3><span style=\"color: #993366\">Compositions<\/span><\/h3>\n<\/td>\n<\/tr>\n<tr>\n<td rowspan=\"3\" width=\"27%\">\n<h3><span style=\"color: #993366\">Style\u00a0\u00a0 1<\/span><\/h3>\n<h3><span style=\"color: #993366\">L-ProH -M\u00a0 &#8211; SMZ<\/span><\/h3>\n<h3><span style=\"color: #993366\">1.1.2<\/span><\/h3>\n<h3><span style=\"color: #993366\">1.1.1<\/span><\/h3>\n<h3><\/h3>\n<h3><\/h3>\n<\/td>\n<td width=\"20%\">\n<h3><span style=\"color: #993366\">Sulfamethoxazole<\/span><\/h3>\n<h3><span style=\"color: #993366\">(SMZ)<\/span><\/h3>\n<\/td>\n<td width=\"16%\">\n<h3><span style=\"color: #993366\">L-Proline<\/span><\/h3>\n<h3><span style=\"color: #993366\">( L-ProH)<\/span><\/h3>\n<\/td>\n<td width=\"35%\">\n<h3><span style=\"color: #993366\">[M (SMZ)( L-Pro)2]<\/span><\/h3>\n<h3><span style=\"color: #993366\">M= Mn(II), Fe (II),Ni(II), Cu(II),Cd(II), Hg(II)\u00a0\u00a0 and\u00a0 Sn(II)<\/span><\/h3>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"20%\">\n<h3><span style=\"color: #993366\">Sulfamethoxazole<\/span><\/h3>\n<h3><span style=\"color: #993366\">(SMZ)<\/span><\/h3>\n<\/td>\n<td width=\"16%\">\n<h3><span style=\"color: #993366\">L-Proline<\/span><\/h3>\n<h3><span style=\"color: #993366\">( L-ProH)<\/span><\/h3>\n<\/td>\n<td width=\"35%\">\n<h3><span style=\"color: #993366\">[ M\u2032 (SMZ)( L-Pro)2]Cl<\/span><\/h3>\n<h3><span style=\"color: #993366\">M\u2032 =\u00a0 Al(III)\u00a0 ,Cr(III)\u00a0 and \u00a0Fe(III)<\/span><\/h3>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"20%\">\n<h3><span style=\"color: #993366\">Sulfamethoxazole<\/span><\/h3>\n<h3><span style=\"color: #993366\">(SMZ)<\/span><\/h3>\n<\/td>\n<td width=\"16%\">\n<h3><span style=\"color: #993366\">L-Proline<\/span><\/h3>\n<h3><span style=\"color: #993366\">( L-ProH)<\/span><\/h3>\n<\/td>\n<td width=\"35%\">\n<h3><span style=\"color: #993366\">[ Sn(SMZ)( L-Pro)]Cl<\/span><\/h3>\n<\/td>\n<\/tr>\n<tr>\n<td rowspan=\"2\" width=\"27%\">\n<h3><span style=\"color: #993366\">Style\u00a0 2<\/span><\/h3>\n<h3><span style=\"color: #993366\">SMZ- M. L-Val<\/span><\/h3>\n<h3><span style=\"color: #993366\">1.1.2<\/span><\/h3>\n<h3><\/h3>\n<\/td>\n<td width=\"20%\">\n<h3><span style=\"color: #993366\">Sulfamethoxazole<\/span><\/h3>\n<h3><\/h3>\n<h3><span style=\"color: #993366\">(SMZ)<\/span><\/h3>\n<\/td>\n<td width=\"16%\">\n<h3><span style=\"color: #993366\">L-Valine<\/span><\/h3>\n<h3><span style=\"color: #993366\">( L-ValH)<\/span><\/h3>\n<\/td>\n<td width=\"35%\">\n<h3><span style=\"color: #993366\">[M (SMZ)( L-Val)2]Cl<\/span><\/h3>\n<h3><span style=\"color: #993366\">M= Mn (II), Fe (II), Co(II),Ni(II), Cu(II), ,Cd(II), Hg(II) and Sn(II)<\/span><\/h3>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"20%\">\n<h3><span style=\"color: #993366\">Sulfamethoxazole<\/span><\/h3>\n<h3><span style=\"color: #993366\">(SMZ)<\/span><\/h3>\n<\/td>\n<td width=\"16%\">\n<h3><span style=\"color: #993366\">L-Valine<\/span><\/h3>\n<h3><span style=\"color: #993366\">( L-ValH)<\/span><\/h3>\n<\/td>\n<td width=\"35%\">\n<h3><span style=\"color: #993366\">[M\u2032 (SMZ)( \u00a0L-Val )2]Cl<\/span><\/h3>\n<h3><span style=\"color: #993366\">M\u2032 = Fe(III)\u00a0 ,Cr(III)\u00a0 and Al(III)<\/span><\/h3>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">A: Sulphamethoxazole(SMZ)\u00a0 (antibiotics) are used as primary ligands and\/or\u00a0 L-Proline( L-ProH), and\u00a0 L-Valine ( L-ValH)\u00a0 as secondary ligands with M(II) and M\u2032 (III) complexes\u00a0 (as listed\u00a0 in the Table below.<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">B : Mono Ligand Complexes<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Sulphamethoxazole (antibiotics) ,L-Proline and\u00a0\u00a0 L-Valine<\/span><\/h3>\n<table class=\" alignleft\" width=\"553\">\n<tbody>\n<tr>\n<td width=\"84\">\n<h3><span style=\"color: #993366\">Type<\/span><\/h3>\n<\/td>\n<td width=\"227\">\n<h3><span style=\"color: #993366\">ligands<\/span><\/h3>\n<\/td>\n<td width=\"242\">\n<h3><span style=\"color: #993366\">Compositions<\/span><\/h3>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"84\">\n<h3><span style=\"color: #993366\">Style 1<\/span><\/h3>\n<\/td>\n<td width=\"227\">\n<h3><span style=\"color: #993366\">Sulfamethoxazole<\/span><\/h3>\n<h3><span style=\"color: #993366\">(SMZ)<\/span><\/h3>\n<\/td>\n<td width=\"242\">\n<h3><span style=\"color: #993366\">[Sn(SMZ)2]Cl2<\/span><\/h3>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"84\">\n<h3><span style=\"color: #993366\">Style\u00a0 2<\/span><\/h3>\n<\/td>\n<td width=\"227\">\n<h3><span style=\"color: #993366\">aminoacid<\/span><\/h3>\n<h3><span style=\"color: #993366\">L-Proline ( L-ProH)<\/span><\/h3>\n<\/td>\n<td width=\"242\">\n<h3><span style=\"color: #993366\">[Sn(L-Pro)2]<\/span><\/h3>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"84\">\n<h3><span style=\"color: #993366\">Style\u00a0\u00a0 3<\/span><\/h3>\n<\/td>\n<td width=\"227\">\n<h3><span style=\"color: #993366\">aminoacid<\/span><\/h3>\n<h3><span style=\"color: #993366\">L-Valine\u00a0 ( L-ValH)<\/span><\/h3>\n<\/td>\n<td width=\"242\">\n<h3><span style=\"color: #993366\">[Sn(L-Val)2]<\/span><\/h3>\n<\/td>\n<\/tr>\n<tr>\n<td width=\"84\">\n<h3><span style=\"color: #993366\">Style\u00a0\u00a0 4<\/span><\/h3>\n<\/td>\n<td width=\"227\">\n<h3><span style=\"color: #993366\">Sulfamethoxazole<\/span><\/h3>\n<h3><span style=\"color: #993366\">(SMZ)<\/span><\/h3>\n<\/td>\n<td width=\"242\">\n<h3><span style=\"color: #993366\">[ M\u2032(SMZ)3]Cl3<\/span><\/h3>\n<h3><span style=\"color: #993366\">M\u2032=Fe(III),Cr(III)and Al(III)<\/span><\/h3>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Wereusedas mono ligand complexes (as listed in the Table<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">below:<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Products, were found to besolid complexes, which were characterized through the following techniques: Molar conductance, Melting point measurements and spectroscopic m\u00e9thodes i.e., [FT-IR, UV-Vis and AA]. According to the results obtained from the different techniques<\/span><\/h3>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 , \u062a\u0634\u062e\u064a\u0635 \u0648\u062a\u0642\u064a\u064a\u0645 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0628\u0639\u0636&#8230;.<a class=\"cz_readmore\" href=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=28384\"><i class=\"fa fa-angle-left\" aria-hidden=\"true\"><\/i><span>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":28387,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"no","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-28384","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/28384","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=28384"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/28384\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/28387"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=28384"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=28384"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=28384"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}