{"id":28716,"date":"2019-12-22T12:39:53","date_gmt":"2019-12-22T09:39:53","guid":{"rendered":"http:\/\/ihcoedu.uobaghdad.edu.iq\/?p=28716"},"modified":"2020-02-12T02:55:37","modified_gmt":"2020-02-11T23:55:37","slug":"%d9%82%d8%b3%d9%85-%d8%a7%d9%84%d9%83%d9%8a%d9%85%d9%8a%d8%a7%d8%a1-%d9%8a%d9%86%d8%a7%d9%82%d8%b4-%d8%b1%d8%b3%d8%a7%d9%84%d8%a9-%d9%85%d8%a7%d8%ac%d8%b3%d8%aa%d9%8a%d8%b1-%d8%aa%d8%aa%d9%88%d8%b5","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=28716","title":{"rendered":"\u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u064a\u0646\u0627\u0642\u0634 \u0631\u0633\u0627\u0644\u0629 \u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u062a\u062a\u0648\u0635\u0644 \u0627\u0644\u0649 \u062a\u062d\u0636\u064a\u0631 \u0645\u0648\u0627\u062f \u062c\u062f\u064a\u062f\u0629 \u062a\u0633\u062a\u062e\u062f\u0645 \u0643\u0645\u0635\u062f\u0631 \u0628\u0627\u0639\u062b \u0636\u0648\u0626\u064a \u0644\u062a\u0637\u0628\u064a\u0642\u0627\u062a \u0627\u0634\u0628\u0627\u0647 \u0627\u0644\u0645\u0648\u0635\u0644\u0627\u062a"},"content":{"rendered":"

\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 ( \u0645\u0648\u0627\u062f \u0628\u0648\u0644\u064a \u0627\u0645\u064a\u062f\u0627\u062a N- triaryl \u0627\u0644\u062c\u062f\u064a\u062f\u0629 \u0627\u0644\u0645\u0633\u062a\u0628\u062f\u0644\u0629 \u0643\u0645\u0635\u062f\u0631 \u0628\u0627\u0639\u062b \u0636\u0648\u0626\u064a \u0644\u062a\u0637\u0628\u064a\u0642 \u0627\u0634\u0628\u0627\u0647 \u0627\u0644\u0645\u0648\u0635\u0644\u0627\u062a ) \u00a0\u0644\u0644\u0637\u0627\u0644\u0628\u0629 ( \u0643\u0648\u062b\u0631 \u0627\u064a\u0627\u062f \u0639\u0628\u064a\u062f ) \u0627\u0644\u062a\u064a \u0627\u0646\u062c\u0632\u062a\u0647\u0627 \u062a\u062d\u062a \u0627\u0634\u0631\u0627\u0641 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a \u0641\u064a \u0627\u0644\u0642\u0633\u0645 ( \u0645.\u062f. \u0627\u0632\u0647\u0631 \u0643\u0627\u0645\u0644 \u0631\u0634\u064a\u062f )<\/span><\/h4>\n

\"\"<\/h4>\n

<\/h4>\n

\u0648\u0646\u0648\u0642\u0634\u062a \u0627\u0644\u0631\u0633\u0627\u0644\u0629 \u0645\u0646 \u0642\u0628\u0644 \u0627\u0639\u0636\u0627\u0621 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u0645\u062f\u0631\u062c\u0629 \u0627\u0633\u0645\u0627\u0626\u0647\u0645 \u0641\u064a\u0645\u0627 \u064a\u0623\u062a\u064a :<\/span><\/h4>\n
    \n
  • \n

    \u0623.\u0645.\u062f. \u0645\u0647\u0627 \u0637\u0627\u0647\u0631 \u0633\u0644\u0637\u0627\u0646\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u0631\u0626\u064a\u0633\u0627<\/span><\/h4>\n<\/li>\n
  • \n

    \u0623.\u0645.\u062f. \u0635\u0644\u0627\u062d \u0645\u0647\u062f\u064a \u0645\u062c\u064a\u062f \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \u0639\u0636\u0648\u0627<\/span><\/h4>\n<\/li>\n
  • \n

    \u0623.\u0645.\u062f. \u0631\u0627\u0626\u062f \u0645\u0635\u0637\u0641\u0649 \u0634\u0627\u0643\u0631 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \u0639\u0636\u0648\u0627<\/span><\/h4>\n<\/li>\n
  • \n

    \u0645.\u062f. \u0627\u0632\u0647\u0631 \u0643\u0627\u0645\u0644 \u0631\u0634\u064a\u062f\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u0639\u0636\u0648\u0627 \u0648\u0645\u0634\u0631\u0641\u0627<\/span><\/h4>\n<\/li>\n<\/ul>\n

    \"\"<\/p>\n

    \u0648\u064a\u0647\u062f\u0641 \u0627\u0644\u0628\u062d\u062b \u0627\u0644\u0649 :<\/span><\/h4>\n

    \u062a\u062d\u0636\u064a\u0631 \u0645\u0648\u0646\u064a\u0645\u0631\u0627\u062a \u062d\u0627\u0645\u0636\u064a\u0629 \u062c\u062f\u064a\u062f\u0629 \u0628\u0648\u0627\u0633\u0637\u0629 \u062a\u0641\u0627\u0639\u0644 ( P-cyanobenzofluride ) \u0645\u0639 \u062b\u0644\u0627\u062b \u0627\u0645\u064a\u0646\u0627\u062a \u0627\u0631\u0648\u0645\u0627\u062a\u064a\u0629 \u0645\u062e\u062a\u0644\u0641\u0629 :<\/span><\/h4>\n
      \n
    • \n

      2-chloro,4-nitroaniline<\/span><\/h4>\n<\/li>\n
    • \n

      2,4,6-Trichloro aniline<\/span><\/h4>\n<\/li>\n
    • \n

      2,6-dichloro-4-ethoxyaniline<\/span><\/h4>\n<\/li>\n<\/ul>\n

      \u0639\u0646 \u0637\u0631\u064a\u0642 \u0627\u0644\u062a\u0639\u0648\u064a\u0636 \u0627\u0644\u0646\u064a\u0648\u0643\u0644\u064a\u0648\u0641\u064a\u0644\u064a \u0627\u0644\u0627\u0631\u0648\u0645\u0627\u062a\u064a \u0644\u062a\u0643\u0648\u064a\u0646 \u062b\u0644\u0627\u062b \u0645\u0631\u0643\u0628\u0627\u062a \u0648\u0633\u0637\u064a\u0629 \u0645\u0646 \u0627\u0644\u062f\u0627\u064a \u0633\u064a\u0627\u0646\u064a\u062f \u0648\u0627\u0644\u062a\u064a \u062a\u0643\u0648\u0646 \u0641\u064a \u0627\u0644\u0646\u0647\u0627\u064a\u0629 \u0645\u0648\u0646\u064a\u0645\u0631\u0627\u062a \u0627\u0644\u062f\u0627\u064a \u2013 \u0643\u0627\u0631\u0628\u0648\u0643\u0633\u064a\u0644\u064a\u0643 \u0628\u0648\u0627\u0633\u0637\u0629 \u0627\u0644\u062a\u062d\u0644\u0644 \u0627\u0644\u0642\u0627\u0639\u062f\u064a \u0644\u0645\u0631\u0643\u0628\u0627\u062a \u0627\u0644\u062f\u0627\u064a \u0633\u064a\u0627\u0646\u064a\u062f .\u0627\u062e\u064a\u0631\u0627\u00a0 \u0647\u0630\u0647 \u0627\u0644\u0645\u0648\u0646\u064a\u0645\u0631\u0627\u062a \u062a\u062a\u0641\u0627\u0639\u0644 \u0645\u0639 \u0627\u062b\u0646\u064a\u0646 \u0645\u0646 \u0645\u0631\u0643\u0628\u0627\u062a \u0627\u0644\u062f\u0627\u064a \u2013 \u0627\u0645\u064a\u0646\u0627\u062a \u0627\u0644\u0627\u0631\u0648\u0645\u0627\u062a\u064a\u0629 \u0627\u0644\u0645\u062e\u062a\u0644\u0641\u0629 \u060c \u0648\u0647\u064a phenylene dimins and benzidine \u0639\u0644\u0649 \u0627\u0644\u062a\u0648\u0627\u0644\u064a \u0648\u0630\u0644\u0643 \u0644\u0627\u062c\u0631\u0627\u0621 \u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u0628\u0644\u0645\u0631\u0629 \u0627\u0644\u062a\u0643\u062b\u064a\u0641\u064a\u0629 \u0627\u0644\u0645\u062a\u0639\u062f\u062f\u0629 \u0648\u062a\u0643\u0648\u064a\u0646 \u0627\u0644\u0628\u0648\u0644\u064a \u0627\u0645\u064a\u062f\u0627\u062a (P1-P6) .<\/span><\/h4>\n

      <\/h4>\n

      \u0648\u062a\u0645 \u0641\u064a \u0647\u0630\u0627 \u0627\u0644\u0628\u062d\u062b \u062a\u0634\u062e\u064a\u0635 \u0627\u0644\u062a\u0631\u0643\u064a\u0628 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a \u0644\u0647\u0630\u0647 \u0627\u0644\u0628\u0648\u0644\u064a\u0645\u0631\u0627\u062a \u0628\u0648\u0627\u0633\u0637\u0629 \u062a\u0642\u0646\u064a\u0627\u062a (FTIR and NMR).<\/span>
      \n\u062c\u0645\u064a\u0639 \u0646\u062a\u0627\u0626\u062c \u0627\u0644\u0628\u0648\u0644\u064a \u0627\u0645\u064a\u062f\u0627\u062a \u062c\u064a\u062f\u0629 \u0627\u0644\u0630\u0648\u0628\u0627\u0646 \u0641\u064a \u0627\u063a\u0644\u0628 \u0627\u0644\u0645\u0630\u064a\u0628\u0627\u062a \u0627\u0644\u0642\u0637\u0628\u064a\u0629 \u0644\u062a\u0634\u0643\u064a\u0644 \u0627\u0641\u0644\u0627\u0645 \u0631\u0642\u064a\u0642\u0629 \u0642\u0648\u064a\u0629 .<\/span><\/h4>\n

      \u0644\u0644\u0628\u0648\u0644\u064a \u0627\u0645\u064a\u062f\u0627\u062a \u0627\u0633\u062a\u0642\u0631\u0627\u0631\u064a\u0629 \u062d\u0631\u0627\u0631\u064a\u0629 \u062c\u064a\u062f\u0629 \u0645\u0639 \u0627\u0631\u062a\u0641\u0627\u0639 \u062f\u0631\u062c\u0629 \u062d\u0631\u0627\u0631\u0629 \u0627\u0644\u0627\u0646\u062a\u0642\u0627\u0644 \u0627\u0644\u0632\u062c\u0627\u062c\u064a (Tg) .\u0645\u062d\u0627\u0644\u064a\u0644 \u0627\u0644\u0628\u0648\u0644\u064a \u0627\u0645\u064a\u062f\u0627\u062a \u0627\u0644\u0646\u0627\u062a\u062c\u0629 \u0641\u064a \u0645\u0630\u064a\u0628 \u0627\u0644\u0640 DMSO \u062a\u0639\u0637\u064a \u0642\u0648\u0629 \u062a\u0623\u0644\u0642 \u0636\u0648\u0626\u064a (PL) .\u062a\u0645 \u0635\u0646\u0639 \u0642\u0637\u0628 \u0627\u0644\u0643\u062a\u0631\u0648\u062f (\u0627\u0646\u0648\u062f) \u0644\u0639\u0645\u0644 \u062e\u0644\u064a\u0629 \u0641\u0648\u0644\u062a\u0627\u0645\u062a\u0631\u064a\u0629 (Cyclic Voltammetry)( (C.V \u0648\u0630\u0644\u0643 \u0628\u0637\u0644\u0627\u0621 \u0642\u0637\u0628 \u0632\u062c\u0627\u062c\u064a \u062e\u0627\u0635 \u0645\u0635\u0646\u0648\u0639 \u0645\u0646 \u0627\u0648\u0643\u0633\u064a\u062f \u0627\u0644\u0642\u0635\u062f\u064a\u0631- \u062a\u064a\u062a\u0627\u0646\u064a\u0648\u0645(iridium\u2013tinoxide) \u0645\u0646 \u0645\u062d\u0627\u0644\u064a\u0644 \u0627\u0644\u0628\u0648\u0644\u064a \u0627\u0645\u064a\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0641\u064a \u0645\u062d\u0644\u0648\u0644 \u0627\u0644\u0643\u062a\u0631\u0648\u0644\u064a\u062a\u064a \u0645\u0646 CH3<\/sub>CN \u0627\u0644\u062c\u0627\u0641 \u0648\u0645\u062d\u0644\u0648\u0644 \u0645\u0643\u0648\u0646 \u0645\u0646 (0.1M) tetrabutylantimoneperchlorate (TBAP) \u0648\u0631\u0628\u0637\u0647 \u0645\u0639 \u0642\u0637\u0628 \u0642\u064a\u0627\u0633\u064a \u0645\u0642\u0627\u0628\u0644 \u0644\u062d\u0633\u0627\u0628 \u0642\u064a\u0645\u00a0\u00a0 HOMO,LUMO, \u0648\u0627\u0644\u0641\u0631\u0642 \u0628\u064a\u0646\u0647\u0645\u0627.\u00a0\u00a0<\/span><\/h4>\n
      \n

      New N-triaryl \u2013substituted Polyamides materials as light Emitters\u00a0 for Semiconductors\u00a0 Application<\/span><\/h3>\n

      By Kawthar Ayad Obaid \u00a0<\/span><\/h3>\n

      Supervised by Dr.Azhar Kamal Rasheed<\/span><\/h3>\n

      Aim of this study<\/span><\/h3>\n

      \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 The aim of this work is to synthesis of new aromatic polyamides containing TPA moieties and to study their optical, thermal and electrochemistry properties. These polyamides are used as a hole transporting materials in light emitting devices. The work steps include synthesis of monomers which react with two types of aromatic diamines by phosphorylation polycondensation reaction. All compounds (intermediates, monomers and final polymers) were confirmed by FTIR, 1H and 13C NMR spectroscopic technique.Thermal and optical properties were studied for these new polyamides.<\/span><\/h3>\n

      Finally, the redox properties of the synthesizedpolyamides were investigated and calculate the HOMO and LOMO energy levels by cyclic voltammetry to confirm that these new materials have light emitting behavior<\/span><\/h3>\n

      Abstract<\/span><\/h3>\n

      In this work, new three di-cyano compounds as intermediates (Di-CN1-Di-CN3) were synthesized by reaction of p-cyanobenzofluride with three different aromatic amines (2-chloro,4-nitroaniline, 2,4,6-Trichloro aniline and 2,6-dichloro-4-ethoxyaniline) via aromatic nucleophilic substitution method. After alkaline hydrolysis of these intermediates, three di-carboxylic monomers (Di-COOH1- Di-COOH3) were formed. Finally, these monomers react with two different aromatic di amines, (phenylenediamins and benzidine) respectively via polycondensation reaction to form final polyamides (P1-P6). The chemical structure of these polymers was characterized by FTIR and NMR techniques. All the results of polyamides have excellent solubility in most polar solvents to form strong thin films. The polyamides have a good thermal stability with high glass transition temperatures Tg<\/span><\/h3>\n

      Polyamides in DMSO solvent gave strongUv-Vis absorbance. Thin casting films of these polyamides in cyclic voltammetry (C.V) on glass base of iridium-tin oxide (ITO) as working electrode in dry CH3CN solvent contains 0.1 M of tetra butyl antimone perchlorate (TBAP) as an electrolyte gave one redox wav<\/span><\/h3>\n","protected":false},"excerpt":{"rendered":"

      \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 ( \u0645\u0648\u0627\u062f….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":28717,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"no","_lmt_disable":"","footnotes":""},"categories":[44,7,16],"tags":[23],"class_list":["post-28716","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-44","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/28716","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=28716"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/28716\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/28717"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=28716"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=28716"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=28716"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}