{"id":29387,"date":"2020-01-15T13:41:28","date_gmt":"2020-01-15T10:41:28","guid":{"rendered":"http:\/\/ihcoedu.uobaghdad.edu.iq\/?p=29387"},"modified":"2020-01-16T09:42:43","modified_gmt":"2020-01-16T06:42:43","slug":"%d9%85%d9%86%d8%a7%d9%82%d8%b4%d8%a9-%d8%b1%d8%b3%d8%a7%d9%84%d8%a9-%d9%85%d8%a7%d8%ac%d8%b3%d8%aa%d9%8a%d8%b1-%d8%aa%d8%af%d8%b1%d8%b3-%d8%a7%d9%84%d9%81%d8%b9%d8%a7%d9%84%d9%8a%d8%a9-%d8%a7%d9%84","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=29387","title":{"rendered":"\u0645\u0646\u0627\u0642\u0634\u0629 \u0631\u0633\u0627\u0644\u0629 \u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u062a\u062f\u0631\u0633 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0644\u0644\u0643\u0631\u0643\u0645\u064a\u0646 \u0645\u0639 \u0627\u064a\u0648\u0646\u0627\u062a \u0628\u0639\u0636 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0627\u0646\u062a\u0642\u0627\u0644\u064a\u0629"},"content":{"rendered":"<h4><span style=\"color: #000080\">\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629\u00a0 ( <strong>\u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0644\u0644\u0643\u0631\u0643\u0645\u064a\u0646 \u0645\u0639 \u0627\u064a\u0648\u0646\u0627\u062a \u0628\u0639\u0636 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0627\u0646\u062a\u0642\u0627\u0644\u064a\u0629 \u0648\u062f\u0631\u0627\u0633\u0629 \u0641\u0639\u0627\u0644\u064a\u062a\u0647\u0627 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 ) \u0644\u0644\u0637\u0627\u0644\u0628\u0629 ( <\/strong>\u0648\u062f\u064a\u0627\u0646 \u0641\u0644\u064a\u062d \u062d\u0633\u0646 ) \u0627\u0644\u062a\u064a \u0627\u0646\u062c\u0632\u062a\u0647\u0627 \u062a\u062d\u062a \u0627\u0634\u0631\u0627\u0641 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a \u0641\u064a \u0627\u0644\u0642\u0633\u0645 (\u0623.\u062f. \u0633\u0627\u062c\u062f \u0645\u062d\u0645\u0648\u062f \u0644\u0637\u064a\u0641) .<\/span><\/h4>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-29390\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2020\/01\/DSC_0568.jpg\" alt=\"\" width=\"800\" height=\"533\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2020\/01\/DSC_0568.jpg 800w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2020\/01\/DSC_0568-300x200.jpg 300w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2020\/01\/DSC_0568-768x512.jpg 768w\" sizes=\"auto, (max-width: 800px) 100vw, 800px\" \/><\/p>\n<h4><span style=\"color: #000080\">\u0648\u0646\u0648\u0642\u0634\u062a \u0627\u0644\u0631\u0633\u0627\u0644\u0629 \u0639\u0644\u0649 \u0642\u0627\u0639\u0629 \u0627\u0644\u0645\u0631\u062d\u0648\u0645 (\u0623.\u062f. \u0641\u0647\u062f \u0639\u0644\u064a \u062d\u0633\u064a\u0646 ) \u0645\u0646 \u0642\u0628\u0644 \u0627\u0639\u0636\u0627\u0621 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 :<\/span><\/h4>\n<ul>\n<li>\n<h4><span style=\"color: #000080\">\u0623.\u062f. \u0639\u0627\u0634\u0648\u0631 \u062d\u0645\u0648\u062f \u062f\u0627\u0648\u062f \u0631\u0626\u064a\u0633\u0627<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u0623.\u062f. \u0635\u0641\u0627\u0621 \u0639\u0628\u062f \u0627\u0644\u0631\u062d\u0645\u0646 \u0627\u062d\u0645\u062f \u0639\u0636\u0648\u0627<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u0623.\u0645. \u062f. \u0631\u062d\u0627\u0628 \u0643\u0627\u0638\u0645 \u0631\u062d\u064a\u0645 \u0639\u0636\u0648\u0627<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u0623. \u062f. \u0633\u0627\u062c\u062f \u0645\u062d\u0645\u0648\u062f \u0644\u0637\u064a\u0641 \u0639\u0636\u0648\u0627 \u0648 \u0645\u0634\u0631\u0641\u0627<\/span><\/h4>\n<\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-29389\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2020\/01\/DSC_0563.jpg\" alt=\"\" width=\"800\" height=\"533\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2020\/01\/DSC_0563.jpg 800w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2020\/01\/DSC_0563-300x200.jpg 300w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2020\/01\/DSC_0563-768x512.jpg 768w\" sizes=\"auto, (max-width: 800px) 100vw, 800px\" \/><\/p>\n<h4><span style=\"color: #000080\">\u0648\u064a\u0647\u062f\u0641 \u0627\u0644\u0628\u062d\u0640\u0640\u0640\u062b \u0627\u0644\u0649:<\/span><\/h4>\n<ol>\n<li>\n<h4><span style=\"color: #000080\">\u062a\u062d\u0636\u064a\u0631 \u0642\u0627\u0639\u062f\u0629 \u0634\u0641 \u062c\u062f\u064a\u062f\u0629 (L1) \u0648\u0645\u0639\u0631\u0641\u0629 \u0635\u064a\u063a\u062a\u0647\u0627 \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0648\u0643\u0630\u0644\u0643 \u0645\u0639\u0631\u0641\u0629 \u0646\u0648\u0639\u0647\u0627 \u0627\u0630\u0627 \u0643\u0627\u0646\u062a (\u0623\u062d\u0627\u062f\u064a\u0629 \u0627\u0644\u0633\u0646 \u0623\u0648 \u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u0633\u0646 \u0623\u0648 \u062b\u0644\u0627\u062b\u064a\u0629 \u0627\u0644\u0633\u0646.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u062a\u062d\u0636\u064a\u0631 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u062e\u062a\u0644\u0637\u0629 \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u062c\u062f\u064a\u062f\u0629 \u0644\u0644\u0643\u0631\u0643\u0645\u064a\u0646 (\u0644\u064a\u0643\u0627\u0646\u062f \u0623\u0633\u0627\u0633\u064a (HL) \u0648 \u0642\u0627\u0639\u062f\u0629 \u0634\u0641 (L1) (\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u062b\u0627\u0646\u0648\u064a) \u0645\u0639 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0641\u0644\u0632\u064a\u0629 \u00a0[VO(II),Cr(III),Mn(II),Fe(III),Co (II),Ni(II),Cu(II)]<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u062a\u062d\u0636\u064a\u0631 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u062c\u062f\u064a\u062f\u0629 \u0644\u0644\u0643\u0640\u0640\u0631\u0643\u0640\u0640\u0640\u0645\u064a\u0646 (\u0644\u064a\u0643\u0627\u0646\u062f \u0623\u0633\u0627\u0633\u064a (HL) \u0648\u0633\u0643\u0627\u0631\u064a\u0646\u0627\u062a \u0635\u0648\u062f\u064a\u0648\u0645 (Sac Na)(\u0644\u064a\u0643\u0627\u0646\u062f \u062b\u0627\u0646\u0648\u064a ) \u0645\u0639 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a [VO(II),Cr(III),Mn(II),Fe(III),Co,( II),Ni(II),Cu(II)]<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u062a\u0634\u062e\u064a\u0635 \u0642\u0627\u0639\u062f\u0629 \u0634\u0641 \u0627\u0644\u062c\u062f\u064a\u062f\u0629 (L1) \u0648\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0625\u064a\u062c\u0627\u062f \u0635\u064a\u063a\u062a\u0647\u0627 \u0627\u0644\u062c\u0632\u0626\u064a\u0629 \u0648 \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0628\u0648\u0633\u0627\u0637\u0629 \u0637\u064a\u0641 \u0627\u0644\u0627\u0634\u0639\u0629 \u062a\u062d\u0640\u0640\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 (FT-IR) \u0648\u0627\u0644\u0637\u0640\u0640\u064a\u0641 \u0627\u0644\u0627\u0644\u0643\u062a\u0640\u0640\u0631\u0648\u0646\u064a (UV-VIS)\u0648\u0637\u0640\u0640\u0640\u0640\u0640\u064a\u0641 \u0627\u0644\u0643\u0640\u0640\u062a\u0644\u0640\u0640\u0629\u00a0\u00a0\u00a0 (LC-mass) \u0648 \u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0631\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a 1H-13C-NMR \u0648\u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0641\u0636\u0644\u0627 \u0639\u0646 \u0642\u064a\u0627\u0633\u0627\u062a \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0648\u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631(C.H.N.S) \u0648\u0642\u064a\u0627\u0633 \u0645\u062d\u062a\u0648\u064a \u0627\u0644\u0643\u0644\u0648\u0631 \u0648 \u0642\u064a\u0627\u0633\u0627\u062a \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u0627\u0642\u062a\u0631\u0627\u062d \u0627\u0644\u0627\u0634\u0643\u0627\u0644 \u0627\u0644\u0647\u0646\u062f\u0633\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0627\u0644\u0635\u0644\u0628\u0629.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080\">\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0642\u0627\u0639\u062f\u0629 \u0634\u0641 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 (L1) \u0648\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062e\u062a\u0644\u0637\u0629 \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0639\u0644\u0649 \u0628\u0639\u0636 \u0623\u0646\u0648\u0627\u0639 \u0645\u0646 \u0628\u0643\u062a\u0631\u064a\u0627 \u0648\u0641\u0637\u0631\u064a\u0627\u062a \u0648 \u0627\u0644\u0639\u0641\u0646<\/span><\/h4>\n<\/li>\n<\/ol>\n<h4><span style=\"color: #000080\">\u00a0\u00a0\u00a0\u00a0\u00a0 \u062a\u0636\u0645\u0646\u062a \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629\u00a0 \u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0642\u0627\u0639\u062f\u0629 \u0634\u0641 \u062c\u062f\u064a\u062f\u0629 (L<sup>1<\/sup>) \u0627\u0644\u0646\u0627\u062a\u062c\u0629\u00a0 \u0645\u0646 \u0645\u0641\u0627\u0639\u0644\u0629 \u0627\u0644\u0627\u0632\u0627\u062a\u064a\u0646 \u0648 2<strong>&#8211;<\/strong>\u0627\u0645\u064a\u0646\u0648-6-\u0645\u064a\u062b\u0648\u0643\u0633\u064a \u0628\u0646\u0632\u0648\u062b\u0627\u064a\u0627\u0632\u0648\u0644 \u0648\u062a\u0636\u0645\u0646\u062a \u0623\u064a\u0636\u0627 \u062a\u062d\u0636\u064a\u0631 \u0646\u0648\u0639\u064a\u0646 \u0645\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u00a0\u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0643\u0631\u0643\u0645\u064a\u0646 \u0628\u0635\u0641\u062a\u0647 \u0644\u064a\u0643\u0627\u0646\u062f \u0623\u0633\u0627\u0633\u064a (HL) \u060c \u0642\u0627\u0639\u062f\u0629 \u0634\u0641 \u0644\u064a\u0643\u0627\u0646\u062f \u062b\u0627\u0646\u0648\u064a (L<sup>1<\/sup>) \u00a0\u0648\u0633\u0643\u0627\u0631\u064a\u0646\u0627\u062a \u0627\u0644\u0635\u0648\u062f\u064a\u0648\u0645 (Sac Na) (\u0644\u064a\u0643\u0627\u0646\u062f \u062b\u0627\u0646\u0648\u064a ) \u0645\u0639 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629:<\/span><\/h4>\n<h4><span style=\"color: #000080\">[VO(II),Cr(III),Mn(II),Fe(III),Co(II),Ni(II),Cu(II)] M=<\/span><\/h4>\n<h4><span style=\"color: #000080\">\u0628\u0646\u0633\u0628 \u0645\u0648\u0644\u064a\u0629 (1:1:1) \u00a0\u0644\u0643\u0644 \u0645\u0646\u00a0 (M:HL:L<sup>1<\/sup>) \u0648(1:1:2) \u0628\u0627\u0644\u0646\u0633\u0628\u0629 (M:HL: Sac Na)\u0623\u062c\u0631\u064a\u062a \u0627\u0644\u062a\u0641\u0627\u0639\u0644\u0627\u062a \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0627\u064a\u062b\u0627\u0646\u0648\u0644 \u0643\u0645\u0630\u064a\u0628 \u0648\u0628\u0639\u0645\u0644\u064a\u0629 \u0627\u0644\u062a\u0635\u0639\u064a\u062f \u0627\u0644\u0639\u0643\u0633\u064a \u0644\u0645\u062f\u0629 \u0633\u0627\u0639\u062a\u064a\u0646 \u060c\u0648\u0627\u0642\u062a\u0631\u062d\u062a \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629\u00a0 \u0648\u0643\u0627\u0644\u0627\u062a\u064a :<\/span><\/h4>\n<h4 style=\"text-align: left\"><span style=\"color: #000080\">Na[VO(L)(L<sup>1<\/sup>)SO<sub>4<\/sub>]\u00a0 , [Cr(L)(L<sup>1<\/sup>)Cl]Cl , [Fe(L)(L<sup>1<\/sup>)H<sub>2<\/sub>O](NO<sub>3<\/sub>)<sub>2<\/sub><\/span><\/h4>\n<h4 style=\"text-align: left\"><span style=\"color: #000080\">[M(L)(L<sup>1<\/sup>)Cl]<\/span><\/h4>\n<h4 style=\"text-align: left\"><span style=\"color: #000080\">Na[VO(L)(Sac)<sub>2<\/sub>H<sub>2<\/sub>O] , [Cr(L) (Sac)<sub>2<\/sub>(H<sub>2<\/sub>O)<sub>2<\/sub>] , [Fe(L) (Sac)<sub>2<\/sub>(H<sub>2<\/sub>O)<sub>2<\/sub>]<\/span><\/h4>\n<h4 style=\"text-align: left\"><span style=\"color: #000080\">Na[M(L) (Sac)<sub>2<\/sub>(H<sub>2<\/sub>O)<sub>2<\/sub>]<\/span><\/h4>\n<h4 style=\"text-align: left\"><span style=\"color: #000080\">M= Mn(II),Co(II),Ni(II),Cu(II)<\/span><\/h4>\n<h4 style=\"text-align: right\"><span style=\"color: #000080\">\u00a0\u0634\u062e\u0635\u062a \u0642\u0627\u0639\u062f\u0629 \u0634\u0641 \u0648 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0631\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a \u0648\u0637\u064a\u0641 \u0627\u0644\u0643\u062a\u0644\u0629 (LC-mass) \u0648\u0637\u064a\u0641 \u0627\u0644\u0627\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0637\u064a\u0641 \u0627\u0644\u0627\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629-\u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0627\u0644\u0644\u0647\u0628\u064a \u0644\u062a\u0639\u064a\u0646 \u0646\u0633\u0628\u0629 \u0627\u0644\u0641\u0644\u0632 \u0641\u0636\u0644\u0627 \u0639\u0646 \u0642\u064a\u0627\u0633\u0627\u062a \u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631 (C.H.N.S) \u0648 \u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0648 \u0642\u064a\u0627\u0633 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631 \u0648\u0642\u064a\u0627\u0633 \u0645\u062d\u062a\u0648\u064a \u0627\u0644\u0643\u0644\u0648\u0631 ). \u00a0\u0648\u0628\u0627\u0639\u062a\u0645\u0627\u062f \u0646\u062a\u0627\u0626\u062c \u0647\u0630\u0647 \u0627\u0644\u062a\u0642\u0646\u064a\u0627\u062a \u062a\u0645 \u0627\u0642\u062a\u0631\u0627\u062d \u0627\u0644\u0627\u0634\u0643\u0627\u0644 \u0627\u0644\u0647\u0646\u062f\u0633\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648 \u0647\u0648 \u0627\u0644\u0634\u0643\u0644 \u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0643\u0645\u0627\u00a0 \u062a\u0645 \u062a\u0642\u062f\u064a\u0631 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u062d\u064a\u0648\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629\u00a0 \u0636\u062f \u0646\u0648\u0639\u064a\u0646 \u0645\u0646 \u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627\u00a0 \u0648\u0647\u064a :<\/span><\/h4>\n<h4><span style=\"color: #000080\">Staphylococcus aureus\u00a0\u00a0 and\u00a0\u00a0 Escherichia coli )\u00a0\u00a0\u00a0 ) \u0648\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a\u00a0Trichophyton rubrum \u0648\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0639\u0641\u0646 \u00a0Candida albicans\u0642\u062f \u0623\u0638\u0647\u0631\u062a \u0627\u0644\u0646\u062a\u0627\u0626\u062c\u00a0 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u062d\u064a\u0648\u064a\u0629 \u0623\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0644\u0647\u0627 \u0641\u0639\u0627\u0644\u064a\u0629 \u062d\u064a\u0648\u064a\u0629 \u0645\u0636\u0627\u062f\u0629 \u0644\u0644\u0628\u0643\u062a\u0631\u064a\u0627\u0621 \u0648\u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a\u00a0 \u0648\u0627\u0644\u0639\u0641\u0646 \u0623\u0639\u0644\u0627\u0647 \u0628\u0627\u0644\u0645\u0642\u0627\u0631\u0646\u0629 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a .<\/span><\/h4>\n<h4><\/h4>\n<h4><span style=\"color: #000080\">\u0648\u062a\u0648\u0635\u0644\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0627\u0644\u0649 \u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u0627\u062a\u064a\u0629 :\u00a0<\/span><\/h4>\n<h4><span style=\"color: #000080\">1-\u0625\u0645\u0643\u0627\u0646\u064a\u0629 \u062f\u0631\u0627\u0633\u0629 \u0648 \u062a\u062d\u0636\u064a\u0631 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0646 \u0627\u0644\u0643\u0631\u0643\u0645\u064a\u0646 \u0645\u0639 \u0628\u0639\u0636 \u0627\u0644\u0645\u0631\u0643\u0628\u0627\u062a \u0627\u0644\u062f\u0648\u0627\u0626\u064a\u0629 \u0648\u062f\u0631\u0627\u0633\u0629 \u0641\u0639\u0627\u0644\u064a\u062a\u0647\u0627 \u0627\u0644\u0639\u0644\u0627\u062c\u064a\u0629 .<\/span><\/h4>\n<h4><span style=\"color: #000080\">2-\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0633\u0644\u0648\u0643 \u0627\u0644\u0628\u0648\u0644\u0627\u0631\u0648\u0643\u0631\u0627\u0641\u064a \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 .<\/span><\/h4>\n<h4><span style=\"color: #000080\">3-\u062a\u062d\u0636\u064a\u0631 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u00a0 \u062c\u062f\u064a\u062f\u0629 \u0648\u062f\u0631\u0627\u0633\u0629 \u0641\u0639\u0627\u0644\u064a\u062a\u0647\u0627 \u0627\u0644\u062d\u064a\u0648\u064a\u0629 .<\/span><\/h4>\n<h4><span style=\"color: #000080\">4-\u0627\u062c\u0631\u0627\u0621 \u0627\u062e\u062a\u0628\u0627\u0631\u0627\u062a \u0639\u0644\u0649 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0628\u0648\u0633\u0627\u0637\u0629 \u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0648\u0632\u0646\u064a \u0627\u0644\u062d\u0631\u0627\u0631\u064a (TGA)\u00a0<\/span><\/h4>\n<h4><span style=\"color: #000080\">5-\u062a\u062d\u0636\u064a\u0631 \u0645\u0639\u0642\u062f\u0627\u062a \u0641\u0644\u0632\u064a\u0629 \u062c\u062f\u064a\u062f\u0629 \u0644\u0642\u0627\u0639\u062f\u0629 \u0634\u0641 (L<sup>1<\/sup>) \u0641\u0642\u0637\u00a0\u00a0<\/span><\/h4>\n<h4><span style=\"color: #000080\">(oxidanylidyne)methyl)-2-methylphenyl(2-oxoindolin-3-ylidene)carbamimidothioate \u0648\u062f\u0631\u0627\u0633\u0629 \u0641\u0639\u0627\u0644\u064a\u062a\u0647\u0627 \u0627\u0644\u062d\u064a\u0648\u064a\u0629 \u0645\u0639 \u0623\u0646\u0648\u0627\u0639 \u0623\u062e\u0631\u0649 \u0645\u0646 \u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u0648 \u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a\u00a0<\/span><\/h4>\n<hr \/>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\"><span style=\"color: #993366\">Synthesis and Characterization Mixed Ligand Complexes for Cur cumin\u00a0with some Transition Elements Ions and Study Biologically Activity<\/span><\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">By Widean Flayah Hassan<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Supervised by prof.Sajid Mahmood Latif<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">\u00a0Cur cumin and its complexes are of great importance in many areas including<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">. Biological efficacy of many bacteria and fungi<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Use in the preparation of some pharmaceutical materials as anti-cancer<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Therefore, the purpose of the research can be summarized as follows<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Preparation of a new base of lips (L1) and knowledge of its syntactic form as well as to know its type if they are (single-tooth or two-tooth or three-tooth.<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">-Preparation of mixed complexes for new lecand at curcumin (primary lecand (HL) and shelf base (L1) (secondary lecand) with metal ions<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">\u00a0[VO (II), Cr (III), Mn (II), Fe (III), Co (II), Ni (II), Cu (II)]<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\"><strong>Abstract<\/strong><\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">This study included synthesis and characterization of new Schiff base (L<sup>1<\/sup>)derived from reactor isatin and 2-amino-6-methoxybanothiazole , also included synthesis two types for mixed-ligand complexes by using curcumin (HL)(essential ligand), Schiff base (L<sup>1<\/sup>)(secondary ligand) and sodium saccharinate (Sac Na)(secondary ligand)with the metallic ions:<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">VO(II),Cr(III),Mn(II),Fe(III),Co(II),Ni(II) and Cu(II).<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">In mole ratio (1:1:1) for (M:HL:L<sup>1<\/sup>) and (1:1:2)for (M :HL :Sac Na), in ethanol as a solvent and by reflux for (2) hrs , the suggested molecular formulas for complexes are as follows:<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Na[VO(L)(L<sup>1<\/sup>)SO<sub>4<\/sub>],[Cr(L)(L<sup>1<\/sup>)Cl]Cl,[Fe(L)(L<sup>1<\/sup>)H<sub>2<\/sub>O](NO<sub>3<\/sub>)<sub>2<\/sub><\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">[M(L)(L<sup>1<\/sup>)Cl]<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">\u00a0[VO(II),Cr(III),Mn(II),Fe(III),Co(II),Ni(II),Cu(II)]<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Na[Vo(L)(Sac)<sub>2<\/sub>H<sub>2<\/sub>O] , [Cr(L) (Sac)<sub>2<\/sub>(H<sub>2<\/sub>O)<sub>2<\/sub>], [Fe(L) (Sac)<sub>2<\/sub>(H<sub>2<\/sub>O)<sub>2<\/sub>]<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Na[M(L) (Sac)<sub>2<\/sub>(H<sub>2<\/sub>O)<sub>2<\/sub>]<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">M= Mn(II),Co(II),Ni(II),Cu(II)<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">The Schiff base(L<sup>1<\/sup>) and all complexes were characterized by physical and spectroscopic measurements (IR spectrum\u00a0 ,UV-VIS spectrum ,atomic absorption ,LC-mass ,<sup>1<\/sup>H,<sup>13<\/sup>C-NMR)along with elemental microanalysis ,magnetic susceptibility ,Chloride content ,molar conductivity and meting point.<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">According to obtained results an octahedral geometrical formula was suggested for all prepared complexes<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">An evaluation of biological activity of all ligands and prepared complexes was estimated for two types of bacteria<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Staphylococcus aureus \u00a0and Escherichia coli and only one type for each of the mildew (Candida albicans) and fungus (Trichophyton rubrum). The results shown that the biological activity of the complexes against the bacteria \u00a0,mildew and fungus is mold the ligands\u00a0<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">-The possibility of studying and preparation of mixed complexes of lycand of cur cumin with some pharmaceutical compounds and study its therapeutic effectiveness<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">&#8211; Studying the polarographic behavior of the prepared complexes<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">Prepare new mixed lycand complexes and study their biological effectiveness<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">-Conducting tests on some complexes prepared by thermal weight analysis (TGA)<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">&#8211; Preparation of new metal complexes for the base of Sh (L1) only<\/span><\/h3>\n<h3 style=\"text-align: left\"><span style=\"color: #993366\">(oxidanylidyne) methyl) -2-methylphenyl (2-oxoindolin-3-ylidene) carbamimidothioate and study its biological effectiveness with other bacteria and fungi<\/span><\/h3>\n<h3 style=\"text-align: left\"><\/h3>\n","protected":false},"excerpt":{"rendered":"<p>\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629\u00a0 ( \u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0644\u0644\u0643\u0631\u0643\u0645\u064a\u0646&#8230;.<a class=\"cz_readmore\" href=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=29387\"><i class=\"fa fa-angle-left\" aria-hidden=\"true\"><\/i><span>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":29388,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"no","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23],"class_list":["post-29387","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/29387","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=29387"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/29387\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/29388"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=29387"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=29387"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=29387"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}