{"id":33438,"date":"2020-10-06T12:00:26","date_gmt":"2020-10-06T09:00:26","guid":{"rendered":"http:\/\/ihcoedu.uobaghdad.edu.iq\/?p=33438"},"modified":"2020-10-11T10:11:37","modified_gmt":"2020-10-11T07:11:37","slug":"33438","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=33438","title":{"rendered":"\u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u064a\u0646\u0627\u0642\u0634 \u0631\u0633\u0627\u0644\u0629 \u0645\u0627\u062c\u0633\u062a\u064a\u0631\u00a0 \u062a\u062d\u0636\u0631 \u0648\u062a\u0634\u062e\u0635 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0645\u0639 \u0644\u064a\u0643\u0646\u062f\u0627\u062a \u062c\u062f\u064a\u062f\u0629 \u0645\u0634\u062a\u0642\u0629 \u0645\u0646 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0623\u0645\u064a\u0646\u064aL- Cysteine \u00a0"},"content":{"rendered":"

\"\"<\/h4>\n

\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 ( \u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0645\u0639 \u0644\u064a\u0643\u0646\u062f\u0627\u062a \u062c\u062f\u064a\u062f\u0629 \u0645\u0634\u062a\u0642\u0629 \u0645\u0646 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0623\u0645\u064a\u0646\u064aL- Cysteine \u00a0\u0648\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0646\u0634\u0627\u0637 \u0627\u0644\u0628\u064a\u0648\u0644\u0648\u062c\u064a ) \u0644\u0644\u0637\u0627\u0644\u0628\u0629 (\u0627\u0628\u0631\u0627\u0631 \u062b\u0627\u0645\u0631 \u0639\u0628\u062f\u0627\u0644\u0644\u0647 \u064a\u0639\u0642\u0648\u0628 ) \u0627\u0644\u062a\u064a \u0627\u0646\u062c\u0632\u062a\u0647\u0627 \u062a\u062d\u062a \u0627\u0634\u0631\u0627\u0641 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a\u0629 \u0641\u064a \u0627\u0644\u0642\u0633\u0645 (\u0627.\u062f \u0628\u0627\u0633\u0645\u0647 \u0645\u062d\u0633\u0646 \u0633\u0631\u062d\u0627\u0646 ) \u0648\u0646\u0648\u0642\u0634\u062a \u0645\u0646 \u0642\u0628\u0644 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u062a\u064a \u062a\u0623\u0644\u0641\u062a \u0645\u0646 \u0627\u0644\u0627\u0639\u0636\u0627\u0621 \u0627\u0644\u0645\u0628\u064a\u0646\u0629 \u0627\u0633\u0645\u0627\u0626\u0647\u0645 \u0641\u064a\u0645\u0627 \u064a\u0623\u062a\u064a :<\/span><\/h4>\n

\u0627.\u062f. \u062a\u063a\u0631\u064a\u062f \u0647\u0627\u0634\u0645 \u062c\u0627\u0633\u0645 \u0627\u0644\u0646\u0648\u0631 (\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n

\u0627.\u0645.\u062f. \u0631\u064a\u0627\u0636 \u0645\u062d\u0645\u0648\u062f \u0627\u062d\u0645\u062f (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n

\u0627.\u0645.\u062f. \u0639\u0627\u062f\u0644 \u0627\u062d\u0645\u062f \u0639\u0648\u0627\u062f (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n

\u0627.\u062f. \u0628\u0627\u0633\u0645\u0647 \u0645\u062d\u0633\u0646 \u0633\u0631\u062d\u0627\u0646 (\u0639\u0636\u0648\u0627 \u0648\u0645\u0634\u0631\u0641\u0627)<\/span><\/h4>\n

\"\"<\/h4>\n

\u0648\u064a\u0647\u062f\u0641 \u0627\u0644\u0628\u062d\u062b \u0627\u0644\u0649 :<\/span><\/h4>\n
    \n
  1. \n

    \u062a\u062d\u0636\u064a\u0631 \u0627\u062b\u0646\u064a\u0646 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0646\u062f\u0627\u062a (ATS) \u0648 (MTP) \u0639\u0646 \u0637\u0631\u064a\u0642 \u062a\u0641\u0627\u0639\u0644 (\u0627\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u064a\u062f) \u0648 (4-\u0645\u064a\u062b\u0648\u0643\u0633\u064a \u0628\u0646\u0632\u0648\u064a\u0644 \u0643\u0644\u0648\u0631\u064a\u062f)<\/span><\/h4>\n<\/li>\n<\/ol>\n

    \u00a0\u0648\u062b\u064a\u0648\u0633\u064a\u0627\u0646\u0627\u062a \u0627\u0644\u0623\u0645\u0648\u0646\u064a\u0648\u0645 \u0645\u0639\u00a0 \u0633\u064a\u0633\u062a\u064a\u0646L-<\/span><\/h4>\n
      \n
    1. \n

      \u062a\u062e\u0644\u064a\u0642 \u0627\u0644\u0645\u0631\u0643\u0628\u0627\u062a \u0627\u0644\u0645\u0639\u062f\u0646\u064a\u0629 \u0639\u0646 \u0637\u0631\u064a\u0642 \u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u0631\u0648\u0627\u0628\u0637 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0645\u0639 \u0623\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0645\u0639\u0627\u062f\u0646 (M + 2 = VO\u0648 Mn \u0648 Co \u0648 Ni \u0648 Cu \u0648 Zn \u0648 Cd \u0648 Hg).<\/span><\/h4>\n<\/li>\n
    2. \n

      \u062a\u0634\u062e\u064a\u0635 \u062a\u0631\u0627\u0643\u064a\u0628 \u0627\u0644\u0644\u064a\u0643\u0646\u062f\u064a\u064a\u0646 \u0627\u0644\u0645\u0639\u062f\u0629 \u0628\u0634\u0643\u0644 \u0645\u062e\u062a\u0644\u0641 \u062a\u0642\u0646\u064a\u0627\u062a \u0645\u062b\u0644 (FT-IR \u0648 UV-Vis \u0648 H1 \u0648 CNMR 13 \u0648\u0627\u0644\u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u062c\u0632\u0626\u064a\u0629 \u0648 \u062a\u062d\u0644\u064a\u0644 (C.H.N.S).<\/span><\/h4>\n<\/li>\n
    3. \n

      \u062a\u0634\u062e\u064a\u0635 \u0647\u064a\u0627\u0643\u0644 \u0643\u0627\u0641\u0629 \u0627\u0644\u0645\u062c\u0645\u0639\u0627\u062a \u0627\u0644\u0645\u0639\u062f\u0629 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u060c \u0627\u0644\u0645\u0648\u0635\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u064a\u0629 \u060c \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0644\u0644\u0647\u0628 \u060c \u0627\u0644\u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0627\u0644\u0642\u064a\u0627\u0633\u0627\u062a \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062c\u0632\u0626\u064a \u0644\u0644\u0639\u0646\u0627\u0635\u0631 (C.H.N.S) \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0627\u062f\u0646 \u0627\u0644\u0645\u062c\u0645\u0639\u0627\u062a \u060c \u0648\u0627\u0642\u062a\u0631\u062d\u0648\u0627 \u0627\u0644\u0647\u064a\u0643\u0644 \u0627\u0644\u0647\u0646\u062f\u0633\u064a \u0627\u0644\u0645\u0646\u0627\u0633\u0628 \u0628\u0646\u0627\u0621\u064b \u0639\u0644\u0649 \u062a\u0644\u0643 \u0627\u0644\u0628\u064a\u0627\u0646\u0627\u062a.<\/span><\/h4>\n<\/li>\n
    4. \n

      \u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0646\u0634\u0627\u0637 \u0627\u0644\u0628\u064a\u0648\u0644\u0648\u062c\u064a \u0644\u0644\u064a\u0643\u0646\u062f\u064a\u064a\u0646 \u0648\u0645\u062c\u0645\u0639\u0627\u062a\u0647\u0645\u0627 \u0628\u0627\u062b\u0646\u064a\u0646 \u0623\u0646\u0648\u0627\u0639 \u0628\u0643\u062a\u064a\u0631\u064a\u0627 (Staphylococcus aureu) \u0648 (Escherichia coli) \u0645\u0639 \u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0623\u064a\u0636\u064b\u0627 \u0646\u0648\u0639 \u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a (Candida albicance).<\/span><\/h4>\n<\/li>\n<\/ol>\n

      <\/h4>\n

      \u0641\u064a \u0647\u0630\u0627 \u0627\u0644\u0628\u062d\u062b \u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0645\u0634\u062a\u0642\u064a\u0646 \u062c\u062f\u064a\u062f\u064a\u0646 \u0644\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0627\u0645\u064a\u0646\u064a L-cysteine \u0645\u0639 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0645\u0627 \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0648\u0643\u0645\u0627 \u064a\u0644\u064a:-<\/span>
      \n\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0644\u0627\u0648\u0644 -3)-2), (L1)\u0627\u0633\u064a\u062a\u0627\u064a\u0644 \u062b\u0627\u064a\u0648\u064a\u0648\u0631\u064a\u062f\u0648-3-(\u0633\u0648\u0644\u0641\u0648\u0647\u064a\u062f\u0631\u064a\u0644 \u0628\u0631\u0648\u0628\u0627\u0646\u0648\u064a\u0643 ) \u0648\u062a\u0645 \u0627\u0639\u0637\u0627\u0621\u0647 \u0627\u0644\u0631\u0645\u0632 (ATS) ,\u062d\u064a\u062b \u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0647\u0630\u0627 \u0627\u0644\u0645\u0634\u062a\u0642 \u0645\u0646 \u0645\u0641\u0627\u0639\u0644\u0629 acetyl chloride \u0645\u0639 \u0645\u062d\u0644\u0648\u0644\u00a0 ammonium thiocyanate \u0641\u064a \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0648\u0628\u0639\u062f \u0630\u0644\u0643 \u062a\u0645 \u0645\u0641\u0627\u0639\u0644\u0629 \u0646\u0627\u062a\u062c \u0627\u0644\u0645\u062d\u0644\u0648\u0644 \u0627\u0644\u0633\u0627\u0628\u0642 \u0645\u0639 \u0645\u062d\u0644\u0648\u0644 L-cysteine \u0641\u064a \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0643\u0645\u0630\u064a\u0628 \u0645\u0639 \u0627\u0644\u062a\u0635\u0639\u064a\u062f \u0644\u0645\u062f\u0629 \u00a06\u0633\u0627\u0639\u0627\u062a .<\/span><\/h4>\n

      \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0644\u062b\u0627\u0646\u064a) (L2) 3-\u0633\u0648\u0644\u0641\u0648\u0647\u064a\u062f\u0631\u064a\u0644-2-(3-(4-\u0645\u064a\u062b\u0648\u0643\u0633\u064a \u0628\u0646\u0632\u0648\u064a\u0644)\u062b\u0627\u064a\u0648\u064a\u0648\u0631\u064a\u062f\u0648)\u0628\u0631\u0648\u0628\u0627\u0646\u0648\u064a\u0643) \u0648\u0642\u062f \u062a\u0645 \u0627\u0639\u0637\u0627\u0621\u0629 \u0627\u0644\u0645\u062e\u062a\u0635\u0631MTP)) ,\u0648\u062d\u0636\u0631 \u0627\u0644\u0645\u0634\u062a\u0642 \u0627\u0644\u062b\u0627\u0646\u064a \u0645\u0646 \u0645\u0641\u0627\u0639\u0644\u0629 4-methoxy benzoyl chlorid \u00a0\u0645\u0639 \u0645\u062d\u0644\u0648\u0644 ammonium thiocyanate \u00a0\u0641\u064a \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0648\u0645\u0646 \u062b\u0645 \u0645\u0641\u0627\u0639\u0644\u0629 \u0646\u0627\u062a\u062c \u0627\u0644\u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u0633\u0627\u0628\u0642 \u0645\u0639 \u0645\u062d\u0644\u0648\u0644 L-cysteine\u00a0 \u0641\u064a \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0643\u0645\u0630\u064a\u0628 \u0645\u0639 \u0627\u0644\u062a\u0635\u0639\u064a\u062f \u0644\u0645\u062f\u0629 \u00a06\u0633\u0627\u0639\u0627\u062a.<\/span><\/h4>\n

      \u0643\u0644\u0627 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 (ATS) )MTP),) \u062a\u0645 \u062a\u0634\u062e\u064a\u0635\u0647\u0645\u0627 \u0628\u0648\u0627\u0633\u0637\u0629 \u0627\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 (FT-IR) ,\u0627\u0634\u0639\u0629 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0648\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633 13 C-NMR)\u0648 ,( 1H \u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631 (C.H.N.S) \u00a0\u0648\u0627\u0644\u0627\u0637\u064a\u0627\u0641 \u0627\u0644\u0627\u0644\u0643\u062a\u0631\u0648\u0646\u064a\u0629, (UV-Vis) \u0648\u0645\u0646 \u062a\u0644\u0643 \u0627\u0644\u0646\u062a\u0627\u0626\u062c \u062a\u0645 \u0627\u0633\u062a\u0646\u062a\u0627\u062c \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0631\u0643\u0628\u064a\u0646 \u0648\u0643\u0645\u0627 \u064a\u0644\u064a:-<\/span>
      \nC6H10N2O3S2 = ATS<\/span>
      \nC12H14N2O4S2 = MTP<\/span><\/h4>\n

      \u0643\u0645\u0627 \u062a\u0645 \u0645\u0641\u0627\u0639\u0644\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u0645\u0639 \u0639\u062f\u062f \u0645\u0646 \u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0627\u0645\u0644\u0627\u062d \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0645\u062b\u0644\u00a0 VO+2,Mn+2,Co+2,Ni+2\u00a0 ) (Cu+2,Zn+2,Cd+2,Hg+2 \u0644\u062a\u062d\u0636\u064a\u0631 \u0639\u062f\u062f \u0645\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0648\u0627\u0644\u062a\u064a \u0634\u062e\u0635\u062a \u0628\u0648\u0627\u0633\u0637\u0629 \u0642\u064a\u0627\u0633 \u0627\u0644\u0630\u0648\u0628\u0627\u0646\u064a\u0629, \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631 \u0648\u0627\u0644\u062a\u0641\u0643\u0643 , \u0627\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621, \u0627\u0644\u0627\u0637\u064a\u0627\u0641 \u0627\u0644\u0627\u0644\u0643\u062a\u0631\u0648\u0646\u064a\u0629, \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629, \u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629, \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631(C.H.N.S) \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0648\u062a\u0639\u064a\u064a\u0646 \u0646\u0633\u0628\u0629 \u0627\u0644\u0641\u0644\u0632 \u00a0\u0641\u064a \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u00a0 \u0628\u0648\u0627\u0633\u0637\u0647 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a.<\/span><\/h4>\n

      \u0648\u0645\u0646 \u062e\u0644\u0627\u0644 \u0646\u062a\u0627\u0626\u062c \u062a\u0644\u0643 \u0627\u0644\u0642\u064a\u0627\u0633\u0627\u062a \u062a\u0645 \u0627\u0633\u062a\u0646\u062a\u0627\u062c \u0627\u0644\u0634\u0643\u0644 \u0631\u0628\u0627\u0639\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0644\u0643\u0644 \u0645\u0646 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a\u00a0 (Mn+2 , Co+2, Ni+2, Zn+2, Cd+2, Hg+2) \u0628\u064a\u0646\u0645\u0627 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u064a\u0648\u0646 \u0627\u0644\u0646\u062d\u0627\u0633 (Cu+2) \u0641\u0623\u062e\u0630\u062a \u0634\u0643\u0644 \u0627\u0644\u0645\u0631\u0628\u0639 \u0627\u0644\u0645\u0633\u062a\u0648\u064a, \u0648\u0634\u0643\u0644 \u0627\u0644\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u064a\u0648\u0646 \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644(VO+2 ) \u0643\u0645\u0627 \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0643\u0644\u0627 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u0645\u0639 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0645\u0627 \u0645\u0639 \u0646\u0648\u0639\u064a\u0646 \u0645\u0646 \u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u00a0(Escherichia coli) \u0648 (Staphylococcus aurea) \u0648\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a\u00a0 ( Candida\u00a0 albicance) \u0648\u0642\u062f \u0627\u0639\u0637\u062a \u0627\u0644\u0645\u0631\u0643\u0628\u0627\u062a \u0646\u062a\u0627\u0626\u062c \u0645\u062e\u062a\u0644\u0641\u0629 \u0641\u064a \u062a\u062b\u0628\u064a\u0637 \u0646\u0645\u0648\u0647\u0627.<\/span><\/h4>\n

      \"\"<\/span><\/h4>\n

      \u0648\u062e\u0644\u0635\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0627\u0644\u0649 \u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a<\/span><\/h4>\n

      1- \u062a\u062d\u0636\u064a\u0631 \u0645\u0639\u0642\u062f\u0627\u062a \u062a\u062d\u062a\u0648\u064a \u0639\u0644\u0649 \u0645\u0634\u062a\u0642\u0627\u062a \u0644\u064a\u062c\u0627\u0646\u062f \u062c\u062f\u064a\u062f\u0629 \u0645\u062e\u062a\u0644\u0641\u0629 \u0645\u0646 \u0627\u0644\u0633\u064a\u0633\u062a\u064a\u0646 \u0648\u0627\u0644\u0623\u062d\u0645\u0627\u0636 \u0627\u0644\u0623\u0645\u064a\u0646\u064a\u0629 \u0627\u0644\u0623\u062e\u0631\u0649<\/span><\/h4>\n

      2- \u0627\u0633\u062a\u062e\u062f\u0645 \u0627\u0644\u0623\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0645\u0639\u062f\u0646\u064a\u0629 \u0645\u0646 \u0627\u0644\u0633\u0644\u0633\u0644\u0629 \u0627\u0644\u062b\u0627\u0646\u064a\u0629 \u0648\u0627\u0644\u062b\u0627\u0644\u062b\u0629 \u0623\u0648 \u0627\u0644\u0644\u0627\u0646\u062b\u0627\u0646\u064a\u062f\u0627\u062a \u0648\u0627\u0644\u0623\u0643\u062a\u064a\u0646\u064a\u062f\u0627\u062a \u0645\u0639 \u0647\u0630\u0647 \u0627\u0644\u0631\u0648\u0627\u0628\u0637 \u0644\u062a\u062d\u0636\u064a\u0631 \u0645\u0639\u0642\u062f\u0627\u062a \u062c\u062f\u064a\u062f\u0629.<\/span><\/h4>\n

      3- \u062f\u0631\u0627\u0633\u0629 \u062b\u0628\u0627\u062a \u0627\u0644\u0627\u0633\u062a\u0642\u0631\u0627\u0631 \u0644\u0644\u0631\u0627\u0628\u0637\u062a\u064a\u0646 \u0648\u0645\u062c\u0645\u0639\u0627\u062a\u0647\u0645\u0627 \u0648\u062d\u0633\u0627\u0628 \u0627\u0644\u0639\u0648\u0627\u0645\u0644 \u0627\u0644\u062f\u064a\u0646\u0627\u0645\u064a\u0643\u064a\u0629 \u0627\u0644\u062d\u0631\u0627\u0631\u064a\u0629 \u2206H \u0648 S\u2206.<\/span><\/h4>\n

      4- \u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062a\u0637\u0628\u064a\u0642 \u0627\u0644\u0635\u0646\u0627\u0639\u064a \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0631\u0643\u0628\u0627\u062a.<\/span><\/h4>\n

      5- \u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0645\u062c\u0645\u0648\u0639\u0627\u062a \u0623\u0646\u0648\u0627\u0639 \u0645\u062e\u062a\u0644\u0641\u0629 \u0645\u0646 \u0627\u0644\u0628\u0643\u062a\u064a\u0631\u064a\u0627 \u0648\u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a \u0644\u0627\u062e\u062a\u0628\u0627\u0631 \u0627\u0644\u0646\u0634\u0627\u0637 \u0627\u0644\u0628\u064a\u0648\u0644\u0648\u062c\u064a \u0644\u0647\u0630\u0647 \u0627\u0644\u0645\u0631\u0643\u0628\u0627\u062a.<\/span><\/h4>\n
      \n

      Synthesis and characterization of some metal complexes with new ligands derived L-cysteine amino acid and study biological activity<\/span><\/h3>\n

      \u00a0\u00a0Abrar Thamer Abduallah<\/span><\/h3>\n

      \u00a0\u00a0 Prof. Dr. Basima M. Sarhan<\/span><\/h3>\n

      Aim of the work<\/span><\/h3>\n
        \n
      1. \n

        Synthesis of two ligands (ATS) and (MTP) by the reaction of the (Acetyl chloride) and (4-Mithoxybenzoyl chloride) and ammonium thiocyanat with L-Cysteine<\/span><\/h3>\n<\/li>\n
      2. \n

        Synthesis of the metal complexes by the reaction of the prepared ligands with metal ions (M+2 =VO, Mn, Co, Ni, Cu, Zn, Cd and Hg)<\/span><\/h3>\n<\/li>\n
      3. \n

        Characterization the structures of the two prepared ligands by different techniques like (FT-IR, UV-Vis, 1H,13C NMR spectra, and micro elemental analysis (C.H.N.S)<\/span><\/h3>\n<\/li>\n
      4. \n

        Characterizing the structures of all the prepared complexes using (FT-IR and U.V-Vis, molar conductance, flame atomic absorption, magnetic susceptibility measurements and micro-elemental analysis (C.H.N.S) for some metal complexes, and proposed the suitable geometrical structure depending on that data.<\/span><\/h3>\n<\/li>\n
      5. \n

        Studying biological activity of the two ligands and their complexes with two types of bacteria (Staphylococcus aureu) and (Escherichia coli), also with one type of fungi Candida albicance<\/span><\/h3>\n<\/li>\n<\/ol>\n

        Abstract<\/span><\/h3>\n

        \u00a0In this research, two new ligands were prepared from L-cysteine<\/span><\/h3>\n

        derivatives with their metal complexes, the first ligand (L1), (2-(3-<\/span><\/h3>\n

        acetylthioureido)-3-sulfu hydryl propanoic acid) (ATS) was performed by reaction of acetyl chloride with ammonium thiocyanate with L-cysteine<\/span><\/h3>\n

        in the acetone as a solvent, while the ligand (L2) [3-sulfu hydryl-2-(3-(4-<\/span><\/h3>\n

        methoxy benzoyl)thiouriedo) propanoic acid] (MTP), was prepared by<\/span><\/h3>\n

        reaction of 4-Methoxy benzoyl chloride and ammonium thiocyanat with<\/span><\/h3>\n

        L-cysteine in acetone as a solvent and stirred for 6 hours<\/span><\/h3>\n

        \u00a0The ligands (ATS) and (MTP) were characterized by FTIR , 1H \u2013NMR<\/span><\/h3>\n

        13C-NMR , micro elemental analysis (C.H.N.S) and UV-Vis<\/span><\/h3>\n

        spectra, the molecular formula of the two ligands were concluded\u00a0<\/span><\/h3>\n

        (ATS) L1 = C6H10N2O3S2<\/span><\/h3>\n

        (MTP) L2 = C12H14N2O4S2<\/span><\/h3>\n

        \u00a0The two ligands L1(ATS) and L2 (MTP) were react with some of<\/span><\/h3>\n

        metal ions like (VO+2, Mn+2, Co+2, Ni+2, Cu+2, Zn+2, Cd+2 and Hg+2) to<\/span><\/h3>\n

        prepared the complexes that characterized by the solubility in some<\/span><\/h3>\n

        solvents, melting point , FT-IR, electronic spectra (UV-Vis), molar<\/span><\/h3>\n

        conductivity, magnetic susceptibility measurement, elemental micro<\/span><\/h3>\n

        analysis(C.H.N.S) and atomic absorption for some complexes<\/span><\/h3>\n

        \u00a0A cording to the measurements, in the both ligands the structures of<\/span><\/h3>\n

        complexes of (Mn+2, Co+2, Ni+2, Zn+2, Cd+2 and Hg+2) was tetrahedral<\/span><\/h3>\n

        geometry, while square planer geometry with complex of (Cu+2<\/span><\/h3>\n

        and the square pyramid for complexes with (VO+2\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \u00a0<\/span><\/h3>\n

        \u00a0The two ligands and their metal complexes against the two types of<\/span><\/h3>\n

        bacteria (Staphylococcus aurea and Escherichia coli ) and one type of<\/span><\/h3>\n

        fungi (Candida albicance) were showed different biological activity that<\/span><\/h3>\n

        inhibit the growth of microorganisms<\/span><\/h3>\n

        The future Studies<\/span><\/h3>\n

        Prepare complexes contain a new different ligands derivatives from cysteine\u00a0 and other amino acid<\/span><\/h3>\n

        Use metal ions of second and third series, or lanthanides and actinides with these ligands to preparation new complexes<\/span><\/h3>\n

        Studying\u00a0 the stability constant of the two ligands and their complexes and calculate the thermodynamic factors \u2206H and \u2206S<\/span><\/h3>\n

        Studying of the industrial application of these compounds<\/span><\/h3>\n

        Use different group group types of bacteria and fungi to testing the biological activity for these compounds<\/span><\/h3>\n","protected":false},"excerpt":{"rendered":"

        \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 ( \u062a\u062d\u0636\u064a\u0631….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":33444,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"no","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23,47],"class_list":["post-33438","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu","tag-chem"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/33438","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=33438"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/33438\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/33444"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=33438"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=33438"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=33438"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}