{"id":38838,"date":"2021-09-15T09:40:31","date_gmt":"2021-09-15T06:40:31","guid":{"rendered":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=38838"},"modified":"2021-09-19T12:14:02","modified_gmt":"2021-09-19T09:14:02","slug":"%d9%82%d8%b3%d9%85-%d8%a7%d9%84%d9%83%d9%8a%d9%85%d9%8a%d8%a7%d8%a1-%d9%8a%d9%86%d8%a7%d9%82%d8%b4-%d8%b1%d8%b3%d8%a7%d9%84%d8%a9-%d9%85%d8%a7%d8%ac%d8%b3%d8%aa%d9%8a%d8%b1-%d8%aa%d8%ad%d8%b6%d8%b1-5","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=38838","title":{"rendered":"\u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u064a\u0646\u0627\u0642\u0634 \u0631\u0633\u0627\u0644\u0629 \u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u062a\u062d\u0636\u0631 \u0648 \u062a\u062f\u0631\u0633 \u0645\u0639\u0642\u062f\u0627\u062a \u062c\u062f\u064a\u062f\u0629 \u0645\u0634\u062a\u0642\u0629 \u0645\u0646 \u0644\u064a\u0643\u0627\u0646\u062f \u0642\u0627\u0639\u062f\u0629 \u0634\u0641"},"content":{"rendered":"<h4 style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-38840\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2021\/09\/\u0645\u0631\u0648\u0627\u0646-\u064a\u0648\u0633\u0641-\u0639\u0644\u064a\u0648\u064a-6.jpg\" alt=\"\" width=\"1024\" height=\"683\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2021\/09\/\u0645\u0631\u0648\u0627\u0646-\u064a\u0648\u0633\u0641-\u0639\u0644\u064a\u0648\u064a-6.jpg 1024w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2021\/09\/\u0645\u0631\u0648\u0627\u0646-\u064a\u0648\u0633\u0641-\u0639\u0644\u064a\u0648\u064a-6-300x200.jpg 300w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2021\/09\/\u0645\u0631\u0648\u0627\u0646-\u064a\u0648\u0633\u0641-\u0639\u0644\u064a\u0648\u064a-6-768x512.jpg 768w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2021\/09\/\u0645\u0631\u0648\u0627\u0646-\u064a\u0648\u0633\u0641-\u0639\u0644\u064a\u0648\u064a-6-600x400.jpg 600w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/h4>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\">\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629 \u0637\u064a\u0641\u064a\u0629 \u0648\u0641\u064a\u0632\u064a\u0627\u0626\u064a\u0629 \u0648\u062d\u064a\u0648\u064a\u0629 \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u062c\u062f\u064a\u062f\u0629 \u0645\u0634\u062a\u0642\u0629 \u0645\u0646 \u0644\u064a\u0643\u0627\u0646\u062f \u0642\u0627\u0639\u062f\u0629 \u0634\u0641) \u0644\u0644\u0637\u0627\u0644\u0628 (\u0645\u0631\u0648\u0627\u0646 \u064a\u0648\u0633\u0641 \u0639\u0644\u064a\u0648\u064a) \u0627\u0644\u062a\u064a \u0627\u0646\u062c\u0632\u0647\u0627 \u0628\u0625\u0634\u0631\u0627\u0641 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a\u0629 \u0641\u064a \u0627\u0644\u0642\u0633\u0645 (\u0623.\u062f.\u0644\u0642\u0627\u0621 \u062e\u0627\u0644\u062f \u0639\u0628\u062f\u0627\u0644\u0643\u0631\u064a\u0645) \u0648\u0646\u0648\u0642\u0634\u062a \u0645\u0646 \u0642\u0628\u0644 \u0623\u0639\u0636\u0627\u0621 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u0645\u0628\u064a\u0646\u0629 \u0623\u0633\u0645\u0627\u0626\u0647\u0645 \u0641\u064a\u0645 \u0645\u0627 \u064a\u0623\u062a\u064a :<\/span><\/h4>\n<ul style=\"text-align: justify;\">\n<li>\n<h4><span style=\"color: #000080;\"><strong>\u0623.\u062f. \u0633\u0627\u062c\u062f \u0645\u062d\u0645\u0648\u062f \u0644\u0637\u064a\u0641<\/strong> (\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\"><strong>\u0623\u0645.\u062f. \u0631\u064a\u0627\u0636 \u0645\u062d\u0645\u0648\u062f \u0627\u062d\u0645\u062f<\/strong> (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\"><strong>\u0623.\u0645.\u062f. \u0627\u0628\u062a\u0647\u0627\u0644 \u0643\u0627\u0638\u0645 \u0643\u0631\u064a\u0645<\/strong> (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\"><strong>\u0623.\u0645.\u062f. \u0644\u0642\u0627\u0621 \u062e\u0627\u0644\u062f \u0639\u0628\u062f \u0627\u0644\u0643\u0631\u064a\u0645<\/strong> (\u0639\u0636\u0648\u0627 \u0648\u0645\u0634\u0631\u0641\u0627)<\/span><\/h4>\n<\/li>\n<\/ul>\n<h4 style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-38842\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2021\/09\/\u0645\u0631\u0648\u0627\u0646-\u064a\u0648\u0633\u0641-\u0639\u0644\u064a\u0648\u064a-1.jpg\" alt=\"\" width=\"1024\" height=\"683\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2021\/09\/\u0645\u0631\u0648\u0627\u0646-\u064a\u0648\u0633\u0641-\u0639\u0644\u064a\u0648\u064a-1.jpg 1024w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2021\/09\/\u0645\u0631\u0648\u0627\u0646-\u064a\u0648\u0633\u0641-\u0639\u0644\u064a\u0648\u064a-1-300x200.jpg 300w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2021\/09\/\u0645\u0631\u0648\u0627\u0646-\u064a\u0648\u0633\u0641-\u0639\u0644\u064a\u0648\u064a-1-768x512.jpg 768w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2021\/09\/\u0645\u0631\u0648\u0627\u0646-\u064a\u0648\u0633\u0641-\u0639\u0644\u064a\u0648\u064a-1-600x400.jpg 600w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/h4>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\"><strong>\u0648\u064a\u0647\u062f\u0641 \u0627\u0644\u0628\u062d\u062b \u0627\u0644\u0649 :<\/strong><\/span><\/h4>\n<ol style=\"text-align: justify;\">\n<li>\n<h4><span style=\"color: #000080;\">\u062a\u062d\u0636\u064a\u0631 \u0644\u064a\u0643\u0627\u0646\u062f \u0642\u0627\u0639\u062f\u0629 \u0634\u0641 LT \u0645\u0646 \u062a\u0641\u0627\u0639\u0640\u0644 \u0627\u0644\u0627\u0644\u062f\u064a\u0647\u0627\u064a\u062f 2-Hydroxy-5-methylbenzaldehyde \u0645\u0639 \u0627\u0644\u0623\u0645\u064a\u0646 \u0627\u0644\u0623\u0648\u0644\u064a <strong>\u00a0<\/strong>4-Bromo-O-toluidine \u00a0\u00a0<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u062a\u0634\u062e\u064a\u0635 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0644\u0645\u062d\u0636\u0631 \u0628\u0639\u062f \u062a\u0646\u0642\u064a\u062a\u0647 \u0628\u0627\u0644\u0637\u0631\u0642 \u0627\u0644\u0637\u064a\u0641\u064a\u0629 \u0645\u062b\u0644 \u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631 \u0648\u0637\u064a\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0627\u0644\u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013\u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648\u0637\u064a\u0641 \u0627\u0644\u0643\u062a\u0644\u0629 \u0648\u0637\u064a\u0641 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0648\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u062a\u062d\u0636\u064a\u0631 \u0645\u062c\u0645\u0648\u0639\u062a\u064a\u0646 \u0645\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a :<\/span><\/h4>\n<\/li>\n<\/ol>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\"><strong>\u0627\u0644\u0645\u062c\u0645\u0648\u0639\u0629 \u0627\u0644\u0627\u0648\u0644\u0649<\/strong><strong>:<\/strong> \u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639 \u0627\u0645\u0644\u0627\u062d \u0627\u0644\u0643\u0644\u0648\u0631\u064a\u062f\u0627\u062a \u0627\u0644\u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624 ( Co\u0648 Cu \u0648 Cd \u0648Hg ) \u0628\u0646\u0633\u0628\u0629 (2:1) \u00a0<\/span><\/h4>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\"><strong>\u0627\u0644\u0645\u062c\u0640\u0645\u0648\u0639\u0629 \u0627\u0644\u062b\u0627\u0646\u064a\u0640\u0629:<\/strong> \u0645\u0640\u0639\u0640\u0640\u0642\u062f\u0627\u062a \u0645\u0640\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0646 \u00a0LT\u0648 \u0627\u0645\u0644\u0627\u062d\u00a0 \u0627\u0644\u0643\u0640\u0640\u0640\u0640\u0640\u0640\u0644\u0648\u0631\u064a\u062f\u0627\u062a \u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624( \u00a0Co\u0648 \u00a0Cu \u0648 Zn\u0648 Mn\u0648 Cd \u0648 Hg \u0648 Ni)\u00a0 \u0648\u00a0 1,10-phenanthroline \u00a0\u00a0\u00a0\u0628\u0646\u0633\u0628\u0629 (1:1:1).<\/span><\/h4>\n<ol style=\"text-align: justify;\" start=\"4\">\n<li>\n<h4><span style=\"color: #000080;\">\u062a\u0634\u062e\u064a\u0635 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062c\u0645\u0648\u0639\u062a\u064a\u0646 \u0627\u0644\u0623\u0648\u0644\u0649 \u0648\u0627\u0644\u062b\u0627\u0646\u064a\u0629 \u0628\u0627\u0644\u0637\u0631\u0642 \u0627\u0644\u0637\u064a\u0641\u064a\u0629 \u0645\u062b\u0644 \u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631 (H.N) \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629-\u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648 \u0627\u0644\u0627\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0642\u064a\u0627\u0633\u0627\u062a \u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0643\u0644\u0648\u0631 \u0648\u0646\u0633\u0628\u0629 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0641\u064a \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0627\u0644\u0644\u0647\u0628\u064a \u0641\u0636\u0644\u0627 \u0639\u0646 \u0627\u062c\u0631\u0627\u0621 \u0642\u064a\u0627\u0633 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631 \u0648 \u0627\u062e\u062a\u0628\u0627\u0631 \u0627\u0644\u0630\u0648\u0628\u0627\u0646\u064a\u0629 \u0644\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629. .<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0646\u0634\u0627\u0637 \u0627\u0644\u0645\u0636\u0627\u062f \u0644\u0644\u0628\u0643\u062a\u064a\u0631\u064a\u0627 \u0627\u0644\u0630\u064a \u064a\u062a\u0645 \u0627\u062e\u062a\u0628\u0627\u0631\u0647 \u0636\u062f \u0646\u0648\u0639\u064a\u0646 \u0645\u0646 \u0627\u0644\u0628\u0643\u062a\u064a\u0631\u064a\u0627 Staphylococcus<em> Aureu<\/em> \u0648 <em>Escherichia coli<\/em> \u0648\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a <em>Rhizopodium<\/em>.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062f\u0648\u0627\u0644 \u0627\u0644\u062b\u0631\u0645\u0648\u062f\u064a\u0646\u0627\u0645\u064a\u0643\u064a\u0629 \u0648 \u0394S \u0648 \u0394G \u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0645\u0639\u0642\u062f\u0627\u062a\u0647.<\/span><\/h4>\n<\/li>\n<\/ol>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\">\u00a0 \u062a\u0636\u0645\u0646\u062a \u0647\u0640\u0640\u0640\u0630\u0647 \u0627\u0644\u0631\u0633\u0640\u0640\u0640\u0640\u0627\u0644\u0629 \u062a\u062d\u0636\u064a\u0631 \u0644\u064a\u0643\u0627\u0646\u062f \u0642\u0627\u0639\u0640\u0640\u0640\u062f\u0629 \u0634\u0641 \u062c\u062f\u064a\u062f\u0629 ( \u00a0LT) \u0648\u0630\u0644\u0643 \u0645\u0640\u0640\u0640\u0646 \u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u0623\u0645\u064a\u0646 \u00a0\u00a04-Bromo-O-toluidine\u00a0 \u0645\u0639 \u00a02-hydroxy-5-methyl benzalaldehyde \u0641\u064a \u0645\u062d\u064a\u0637 \u062d\u0627\u0645\u0636\u064a \u0645\u0639 \u0627\u0644\u062a\u0643\u062b\u064a\u0641 \u0648\u0628\u0639\u062f\u0647\u0627 \u062a\u0645 \u0639\u0632\u0644 \u0627\u0644\u0645\u0631\u0643\u0628 \u0628\u0634\u0643\u0644\u0647 \u0627\u0644\u0635\u0644\u0628 \u0648\u062a\u0634\u062e\u064a\u0635\u0647 \u0644\u0644\u062a\u0623\u0643\u064a\u062f \u0645\u0646 \u062a\u0631\u0643\u064a\u0628\u0647 \u0627\u0644\u0628\u0646\u0627\u0626\u064a \u0628\u0648\u0627\u0633\u0637\u0629 \u0637\u064a\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 FT-IR \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 &#8211; \u0627\u0644\u0645\u0631\u0626\u064a\u0629 (UV-Visible) \u0648\u0637\u064a\u0641 \u0627\u0644\u0643\u062a\u0644\u0629 mass spectrum \u0648\u0637\u064a\u0641 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0648\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a <strong><sup>1<\/sup><\/strong>H-NMR \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631 (C.H.N) \u0648\u0642\u064a\u0627\u0633 \u062f\u0631\u062c\u0629 \u0627\u0646\u0635\u0647\u0627\u0631 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0644\u0645\u062d\u0636\u0631 \u0643\u0645\u0627 \u0645\u0628\u064a\u0646 \u0641\u064a \u0627\u0644\u0635\u064a\u063a\u0629 \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 :\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 2-(((4-bromo-2-methylphenyl)imino)methyl)-4-methylphenol<\/span><\/h4>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\">\u062a\u0645 \u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0644\u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0645\u062e\u0644\u0628 \u0641\u064a \u062a\u062d\u0636\u064a\u0631 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a 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\u0628\u0646\u0633\u0628\u0629 (2:1) (M:L) , \u0648\u0627\u0644\u0635\u064a\u063a\u0629 \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0644\u0640\u0640\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u062a\u0646\u0627\u0633\u0642\u064a\u0629 \u0647\u064a [M (LT)<sub>2<\/sub>(H<sub>2<\/sub>O)<sub>2<\/sub>].<\/span><\/h4>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\">\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \u0627\u0644\u0645\u062c\u0645\u0648\u0639\u0629 \u0627\u0644\u062b\u0627\u0646\u064a\u0629 : \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0640\u062e\u0640\u062a\u0640\u0644\u0637\u0640\u0629 \u0627\u0644\u0644\u064a\u0640\u0643\u0640\u0640\u0640\u0640\u0627\u0646\u0640\u062f \u0645\u0646 \u0627\u0644\u0644\u064a\u0640\u0640\u0640\u0643\u0640\u0627\u0646\u0640\u062f \u0627\u0644\u0627\u0648\u0644\u064a ( LT ) \u0648\u0627\u0644\u0644\u064a\u0640\u0640\u0643\u0640\u0640\u0627\u0646\u0640\u0640\u062f \u0627\u0644\u062b\u0640\u0640\u0627\u0646\u0648\u064a\u00a0 \u00a01,10-Phenanathroline \u00a0\u0645\u0639 \u0627\u0645\u0644\u0627\u062d \u0643\u0644\u0648\u0631\u064a\u062f\u0627\u062a \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624 \u0645\u062b\u0644 \u00a0( Zn\u0648 Mn \u0648 Cd\u0648 Ni \u0648 \u00a0Hg\u0648 Cu \u0648 Co ) \u0628\u0646\u0633\u0628\u0629 (1:1:1) \u0648\u0627\u0644\u0635\u064a\u063a\u0629 \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0647\u064a [M(LT)(Phen)(H<sub>2<\/sub>O)<sub>2<\/sub>] \u00a0\u0648 [M(LT)(Phen)Cl (H<sub>2<\/sub>O)].<\/span><\/h4>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\">\u00a0\u00a0\u00a0 \u00a0\u00a0\u0634\u064f\u062e\u0635\u062a \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0628\u0639\u062f\u0629 \u062a\u0642\u0646\u064a\u0627\u062a \u0645\u0646\u0647\u0627 \u0637\u064a\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 FT-IR \u0648\u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 (UV-Visible) \u0644\u0645\u062d\u0627\u0644\u064a\u0644 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0641\u064a \u0645\u0630\u064a\u0628 DMSO \u00a0\u0648\u0642\u064a\u0627\u0633\u0627\u062a \u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0641\u0642\u062f \u0627\u0639\u0637\u062a \u0646\u062a\u0627\u0626\u062c \u062a\u062a\u0648\u0627\u0641\u0642 \u0645\u0639 \u062a\u0644\u0643 \u0627\u0644\u0642\u064a\u0645 \u0627\u0644\u062e\u0627\u0635\u0629 \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u062b\u0645\u0627\u0646\u064a\u0629 \u0627\u0644\u0633\u0637\u0648\u062d. \u0643\u0645\u0627 \u0627\u0638\u0647\u0631\u062a \u0646\u062a\u0627\u0626\u062c \u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631 (C.H.N.O) \u0648\u062d\u0633\u0627\u0628 \u0646\u0633\u0628\u0629 \u0627\u0644\u0641\u0644\u0632 \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0627\u0644\u0644\u0647\u0628\u064a \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u062a\u0648\u0627\u0641\u0642\u0627\u064b \u0643\u0628\u064a\u0631\u0627 \u0645\u0639 \u0627\u0644\u0642\u064a\u0645 \u0627\u0644\u0645\u062d\u0633\u0648\u0628\u0629 \u0646\u0638\u0631\u064a\u0627\u064b \u0644\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0645\u0630\u0643\u0648\u0631\u0629 \u0648\u0646\u062a\u0627\u0626\u062c \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0643\u0647\u0631\u0628\u0627\u0626\u064a\u0629 \u0648\u0642\u064a\u0627\u0633 \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0643\u0644\u0648\u0631 \u0648\u0642\u064a\u0627\u0633 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629.<\/span><\/h4>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\">\u00a0\u00a0\u00a0\u00a0 \u0648\u0627\u064a\u0636\u0627 \u062a\u0645\u062a \u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u062a\u062c\u0627\u0647 \u0646\u0648\u0639\u064a\u0646 \u0645\u0646 \u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u0627\u0644\u0645\u0631\u0636\u064a\u0629 \u0627\u062d\u062f\u0647\u0645\u0627 \u0645\u0648\u062c\u0628\u0629 \u0627\u0644\u0635\u0628\u063a\u0629 \u0627\u0644\u0643\u0631\u0627\u0645 (G+) <em>Staphylococcus<\/em> \u00a0\u0648\u0627\u0644\u0627\u062e\u0631\u0649 \u0628\u0643\u062a\u0631\u064a\u0627 \u0633\u0627\u0644\u0628\u0629 \u0627\u0644\u0635\u0628\u063a\u0629 (G-) \u0627\u0644\u0645\u062a\u0645\u062b\u0644\u0629 \u0628\u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 <em>\u00a0<\/em><em>\u00a0\u00a0Escherichia coli<\/em>\u0648\u0646\u0648\u0639 \u0645\u0646 \u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a <em>Rhizosporium<\/em> \u0628\u062a\u0642\u0646\u064a\u0629 \u0642\u064a\u0627\u0633 \u0645\u0646\u0637\u0642\u0629 \u0627\u0644\u062a\u062b\u0628\u064a\u0637 (ZI) \u0627\u0630 \u0627\u0638\u0647\u0631\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0641\u0639\u0627\u0644\u064a\u0629 \u0645\u062e\u062a\u0644\u0641\u0629 \u062a\u062c\u0627\u0647 \u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u0648\u0627\u0644\u0641\u0637\u0631.<\/span><\/h4>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\">\u00a0\u00a0\u00a0\u00a0 \u062a\u0636\u0645\u0646 \u0627\u0644\u062c\u0632\u0621 \u0627\u0644\u0627\u062e\u064a\u0631 \u062f\u0631\u0627\u0633\u0629 \u0642\u064a\u0645 \u0627\u0644\u062f\u0648\u0627\u0644 \u0627\u0644\u062b\u0631\u0645\u0648\u062f\u064a\u0646\u0627\u0645\u064a\u0643\u064a\u0629 \u2206H , \u2206S \u0648 \u2206G \u0644\u0644\u0644\u064a\u0643\u0627\u0646\u062f ((LT \u0648\u0627\u0644\u0645\u0639\u0642\u062f [Co(LT)<sub>2<\/sub>H<sub>2<\/sub>O] \u062d\u064a\u062b \u062a\u0628\u064a\u0646 \u0645\u0646 \u0642\u064a\u0645 \u2206H \u0627\u0646 \u0639\u0645\u0644\u064a\u0629 \u062a\u062d\u0644\u0644 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0627\u0644\u0645\u0639\u0642\u062f \u0647\u064a \u0639\u0645\u0644\u064a\u0629 \u0645\u0627\u0635\u0629 \u0644\u0644\u062d\u0631\u0627\u0631\u0629 \u0648\u0627\u0646 \u0642\u064a\u0645 \u0627\u0644\u0627\u0646\u062a\u0631\u0648\u0628\u064a \u2206S \u062a\u0643\u0648\u0646 \u0633\u0627\u0644\u0628\u0629 \u0644\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0648\u0645\u0648\u062c\u0628\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0648\u0647\u0630\u0627 \u064a\u062f\u0644 \u0639\u0644\u0649 \u0627\u0646 \u0627\u0644\u0645\u0639\u0642\u062f \u0627\u0643\u062b\u0631 \u0627\u0633\u062a\u0642\u0631\u0627\u0631\u064a\u0629 \u0648\u0627\u0646 \u0642\u064a\u0645 \u2206G \u062a\u0644\u0642\u0627\u0626\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f \u0648\u063a\u064a\u0631 \u062a\u0644\u0642\u0627\u0626\u064a\u0629 \u0644\u0644\u0644\u064a\u0643\u0627\u0646\u062f .<\/span><\/h4>\n<h4 style=\"text-align: justify;\"><\/h4>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\">\u0648\u062e\u0644\u0635 \u0627\u0644\u0637\u0627\u0644\u0628 \u0627\u0644\u0649 \u0627\u0644\u062a\u0648\u0635\u064a\u0627\u062a \u0627\u0644\u0627\u062a\u064a\u0629 :<\/span><\/h4>\n<ol style=\"text-align: justify;\">\n<li>\n<h4><span style=\"color: #000080;\">\u062a\u0640\u0640\u0640\u0640\u0640\u0640\u0640\u0640\u0640\u062d\u0636\u064a\u0631 \u0642\u0640\u0640\u0648\u0627\u0639\u0640\u0640\u062f \u0634\u0640\u0640\u0641 \u0627\u062e\u0631\u0649 \u0645\u0640\u0640\u0646 2-Hydroxy-5-methyl benzaldehyde \u0648 4-Bromo-O-toluidine\u00a0 \u0648 1,10-Phenanthroline \u0648\u0645\u0632\u062c\u0647\u0645\u0627 \u0645\u0639 \u0627\u0644\u0627\u062d\u0645\u0627\u0636 \u0627\u0644\u0627\u0645\u064a\u0646\u064a\u0629 \u0627\u0648 \u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u062e\u0631\u0649 .<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0644\u062f\u064a\u0647\u0627\u064a\u062f\u0627\u062a \u0627\u062e\u0631\u0649 \u062a\u062d\u062a\u0648\u064a \u0639\u0644\u0649 \u0645\u062c\u0645\u0648\u0639\u0629 \u0645\u0627\u0646\u062d\u0629 \u0627\u062e\u0631\u0649 .<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u062a\u062d\u0636\u064a\u0631 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u0646 \u0627\u064a\u0648\u0646\u0627\u062a \u0641\u0644\u0632\u064a\u0629 \u0627\u062e\u0631\u0649 \u0645\u062b\u0644 Fe (II) , Pd (II) , Pt (II) \u0648\u063a\u064a\u0631\u0647\u0627.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u062f\u0631\u0627\u0633\u0629 \u0645\u0648\u0633\u0639\u0629 \u0644\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0644\u0648\u062c\u064a\u0629 \u0644\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0646\u0648\u0627\u0639 \u0627\u062e\u0631\u0649 \u0645\u0646 \u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u0648\u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a .<\/span><\/h4>\n<hr \/>\n<\/li>\n<\/ol>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">Synthesis, spectroscopic, physical and biological study<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">\u00a0of new complexes derived from Ligand Schiff base<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">By Marwan Yousif Oleiwi Lawas<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">Supervised by Prof. Dr.Lekaa Khalid Abdul Karem<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">Abstract<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">This study included , a new Schiff base ligand (LT), was prepared from the reaction of the 4-bromo-2-methylaniline with 2-hydroxy-5-methylbenzalaldehyde in an acidic medium with condensation and after isolation The compound is in its solid form and diagnosed to confirm its structural composition by means of mass spectrum, NMR, FT-IR and UV-Visible. The ratio of elements (CHN), melting point to the prepared ligand is calculated as shown in the structural formula below.<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">2-(((4-bromo-2-methylphenyl)imino)methyl)-4-methylphenol<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">This ligand was used in preparing coordination complexes from the ligand interaction with the transition elements ions on two groups:<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">The first group, ligand interacted with metal ions (II) chlorides (Co, Cu, Cd, and Hg) in a ratio of (1:2).The molecular formula for complexes is\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 [M (LT)2(H2O)2].<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">The second group, mixed ligand complexes from ligand with metal ions (II) chlorides. nH2O of (Mn, Co, Ni, Cu, Zn, Cd, and Hg) and 1,10-phenanthroline with a ratio (1: 1: 1), The molecular formula for complexes is [M(LT)(phen)Cl (H2O)].<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">The prepared complexes were diagnosed with several techniques, including FT-IR and UV-visible of the solution in the DMSO solvent, and Measurements of the Magnetic\u00a0 Susceptibility it has given results that correspond to those values for octahedral complexes. The results of accurate analysis of the elements (C.H.N) and the calculation of the metal ratio using the atomic absorption technique of the complexes also showed great compatibility with theoretically calculated values of the mentioned elements and the results of electrical conductivity and chlorine content and melting point of the prepared complexes.<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">The biological activity of the prepared complexes towards two types of pathogenic bacteria was also studied, one of which is positive for Staphylococcus (G +) and the other G-negative bacteria, Escherichia coli, and type of fungal where the complexes showed different efficacy towards the bacteria and fungal.<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">The last part of this study (applications) included studying the values of thermodynamic functions \u2206H\u00b0, \u2206S\u00b0 and \u2206G\u00b0 for two systems ligand (LT) and [Co (LT)2(H2O)2] complex. where it was found from the values of \u2206H\u00b0 that the decomposition process of the ligand and the complex is an absorbent process and that the entropy values of \u2206S\u00b0 are negative for the ligand and positive for the complex, and this indicates that the complex is more stable and that<\/span> <span style=\"color: #993366;\">the values of \u2206G\u00b0 are automatic for the complex and non-spontaneous for the ligand.<\/span><\/h3>\n<p>&nbsp;<\/p>\n<h4 style=\"text-align: justify;\"><\/h4>\n","protected":false},"excerpt":{"rendered":"<p>\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 (\u062a\u062d\u0636\u064a\u0631 \u0648\u062f\u0631\u0627\u0633\u0629&#8230;.<a class=\"cz_readmore\" href=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=38838\"><i class=\"fa fa-angle-left\" aria-hidden=\"true\"><\/i><span>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":38841,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"no","_lmt_disable":"","footnotes":""},"categories":[7,16],"tags":[23,47],"class_list":["post-38838","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-16","tag-ihcoedu","tag-chem"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/38838","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=38838"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/38838\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/38841"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=38838"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=38838"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=38838"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}