{"id":44420,"date":"2022-06-16T11:02:13","date_gmt":"2022-06-16T08:02:13","guid":{"rendered":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=44420"},"modified":"2023-06-28T18:32:59","modified_gmt":"2023-06-28T15:32:59","slug":"%d9%82%d8%b3%d9%85-%d8%a7%d9%84%d9%83%d9%8a%d9%85%d9%8a%d8%a7%d8%a1-%d9%8a%d9%86%d8%a7%d9%82%d8%b4-%d8%b1%d8%b3%d8%a7%d9%84%d8%a9-%d9%85%d8%a7%d8%ac%d8%b3%d8%aa%d9%8a%d8%b1-%d8%aa%d8%ad%d8%b6%d8%b1-7","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=44420","title":{"rendered":"\u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u064a\u0646\u0627\u0642\u0634 \u0631\u0633\u0627\u0644\u0629 \u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u062a\u062d\u0636\u0631 \u0648\u062a\u0634\u062e\u0635 \u0628\u0639\u0636 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062e\u062a\u0644\u0637\u0629 \u0628\u064a\u062a\u0627 \u2013 \u0627\u064a\u0646\u0627\u0645\u064a\u0646\u0648\u0646 \u0645\u0639 \u0628\u0639\u0636 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629"},"content":{"rendered":"<h4 style=\"text-align: justify;\"><\/h4>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-44423\" src=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2022\/06\/\u0645\u0646\u0627\u0642\u0634\u0629-\u0631\u0633\u0627\u0644\u0629-\u0645\u0627\u062c\u0633\u062a\u064a\u0631-\u062d\u0633\u0646-\u062c\u0648\u0627\u062f-\u0643\u0627\u0638\u0645-\u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621-2.jpg\" alt=\"\" width=\"587\" height=\"391\" srcset=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2022\/06\/\u0645\u0646\u0627\u0642\u0634\u0629-\u0631\u0633\u0627\u0644\u0629-\u0645\u0627\u062c\u0633\u062a\u064a\u0631-\u062d\u0633\u0646-\u062c\u0648\u0627\u062f-\u0643\u0627\u0638\u0645-\u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621-2.jpg 587w, https:\/\/ihcoedu.uobaghdad.edu.iq\/wp-content\/uploads\/sites\/27\/2022\/06\/\u0645\u0646\u0627\u0642\u0634\u0629-\u0631\u0633\u0627\u0644\u0629-\u0645\u0627\u062c\u0633\u062a\u064a\u0631-\u062d\u0633\u0646-\u062c\u0648\u0627\u062f-\u0643\u0627\u0638\u0645-\u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621-2-300x200.jpg 300w\" sizes=\"auto, (max-width: 587px) 100vw, 587px\" \/>\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 ( \u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0628\u0639\u0636 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062e\u062a\u0644\u0637\u0629 \u0628\u064a\u062a\u0627 \u2013 \u0627\u064a\u0646\u0627\u0645\u064a\u0646\u0648\u0646 (B-enaminone) \u0645\u0639 \u0628\u0639\u0636 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0648 \u062a\u0642\u062f\u064a\u0631 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0647\u0627 ) \u0644\u0644\u0637\u0627\u0644\u0628 ( \u062d\u0633\u0646 \u062c\u0648\u0627\u062f \u0643\u0627\u0638\u0645 ) \u0627\u0644\u062a\u064a \u0627\u0646\u062c\u0632\u0647\u0627 \u062a\u062d\u062a \u0627\u0634\u0631\u0627\u0641 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a \u0641\u064a \u0627\u0644\u0642\u0633\u0645 ( \u0623.\u062f. \u0627\u062d\u0645\u062f \u062b\u0627\u0628\u062a \u0646\u0639\u0645\u0627\u0646 ) \u0648\u0646\u0648\u0642\u0634\u062a \u0645\u0646 \u0642\u0628\u0644 \u0623\u0639\u0636\u0627\u0621 \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0644\u0645\u062f\u0631\u062c \u0623\u0633\u0645\u0627\u0626\u0647\u0645 \u0641\u064a \u0645\u0627 \u064a\u0623\u062a\u064a :<\/span><\/h4>\n<ul style=\"text-align: justify;\">\n<li>\n<h4><span style=\"color: #000080;\">\u0623.\u062f. \u0639\u0627\u0645\u0631 \u062c\u0628\u0627\u0631 \u062c\u0631\u0627\u062f (\u0631\u0626\u064a\u0633\u0627)<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u0623.\u062f. \u0639\u0644\u0627\u0621 \u0641\u0631\u0627\u0643 \u062d\u0633\u064a\u0646 (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u0623.\u0645.\u062f. \u0627\u064a\u0646\u0627\u0633 \u062c\u0627\u0633\u0645 \u0648\u062d\u064a\u062f (\u0639\u0636\u0648\u0627)<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u0623.\u062f. \u0627\u062d\u0645\u062f \u062b\u0627\u0628\u062a \u0646\u0639\u0645\u0627\u0646 (\u0639\u0636\u0648\u0627 \u0648\u0645\u0634\u0631\u0641\u0627)<\/span><\/h4>\n<\/li>\n<\/ul>\n<h4 style=\"text-align: justify;\"><span style=\"color: #000080;\">\u0648\u064a\u0647\u062f\u0641 \u0627\u0644\u0628\u062d\u062b \u0627\u0644\u0649 :<\/span><\/h4>\n<ol style=\"text-align: justify;\">\n<li>\n<h4><span style=\"color: #000080;\">\u062a\u062d\u0636\u064a\u0631 \u0642\u0648\u0627\u0639\u062f \u0634\u0641 \u062c\u062f\u064a\u062f\u0629 (H2L2) \u062d\u0627\u0648\u064a\u0629 \u0639\u0644\u0649 \u0645\u062c\u0645\u0648\u0639\u0629 (C=N) \u0627\u0644\u0627\u0632\u0648\u0645\u064a\u062b\u064a\u0646 \u0627\u0644\u0645\u0634\u062a\u0642\u0629 \u0645\u0646 (Trimethoprim) . \u0648\u062a\u062d\u0636\u064a\u0631 \u0645\u0631\u0643\u0628\u0627\u062a \u062c\u062f\u064a\u062f\u0629 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f (H1L1) .<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u062a\u062d\u0636\u064a\u0631 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a (HL1,H2L2)(3ph) \u0644\u0628\u0639\u0636 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0627\u0646\u062a\u0642\u0627\u0644\u064a\u0629 \u0648\u063a\u064a\u0631 \u0627\u0644\u0627\u0646\u062a\u0642\u0627\u0644\u064a\u0629 \u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624 (Cu, Zn and Cd , Ni, Co) \u0645\u0646 \u062e\u0644\u0627\u0644 \u0627\u0644\u062a\u0641\u0627\u0639\u0644 \u0627\u0644\u0645\u0628\u0627\u0634\u0631 \u0644\u0643\u0644\u0648\u0631\u064a\u062f\u0627\u062a \u0627\u0644\u0639\u0646\u0627\u0635\u0631\u0627\u0644\u0627\u0646\u062a\u0642\u0627\u0644\u064a\u0629 \u0648\u063a\u064a\u0631 \u0627\u0644\u0627\u0646\u062a\u0642\u0627\u0644\u064a\u0629 \u0627\u0644\u0645\u0646\u062a\u0642\u0627\u0629 \u0628\u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u0645\u0639 \u0645\u062d\u0644\u0648\u0644 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062a\u0631\u0643\u064a\u0628 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0645\u062e\u062a\u0644\u0641\u0629 \u0643\u0637\u064a\u0641 ( FT-IR, (U.V-Vis \u0648\u0645\u0637\u064a\u0627\u0641 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0648\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a \u0644\u0644\u0628\u0631\u0648\u062a\u0648\u0646 \u0648\u0627\u0644\u0643\u0627\u0631\u0628\u0648\u0646 1H, 13C NMR)) \u0648\u0637\u064a\u0641 \u0627\u0644\u0643\u062a\u0644\u0629 \u0641\u0636\u0644\u0627 \u0639\u0646 \u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062e\u0648\u0627\u0635 \u0627\u0644\u0641\u064a\u0632\u0628\u0627\u0626\u064a\u0629 \u0643\u0627\u0644\u0630\u0648\u0628\u0627\u0646\u064a\u0629 \u0648\u062f\u0631\u062c\u0629 \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062a\u0631\u0643\u064a\u0628 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0628\u062a\u0642\u0646\u064a\u0627\u062a \u0645\u062e\u062a\u0644\u0641\u0629 FT-IR) ) , (UV-Vis) \u0648\u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0648\u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0643\u0644\u0648\u0631 \u0648\u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0648\u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u0627\u0642\u062a\u0631\u0627\u062d \u0627\u0644\u0623\u0634\u0643\u0627\u0644 \u0627\u0644\u0641\u0631\u0627\u063a\u064a\u0629 \u0648\u0627\u0644\u0635\u064a\u063a \u0627\u0644\u062a\u0631\u0643\u064a\u0628\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0627\u0633\u062a\u0646\u0627\u062f\u0627 \u0627\u0644\u0649 \u0627\u0644\u062a\u0634\u062e\u064a\u0635 \u0627\u0644\u0645\u0630\u0643\u0648\u0631 \u0627\u0639\u0644\u0627\u0629.<\/span><\/h4>\n<\/li>\n<li>\n<h4><span style=\"color: #000080;\">\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u062d\u064a\u0648\u064a\u0629 \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u062c\u062f\u064a\u062f\u0629 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0639\u0644\u0649 \u0628\u0639\u0636 \u0627\u0646\u0648\u0627\u0639 \u0645\u0646 \u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u0648\u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a.<\/span><\/h4>\n<hr \/>\n<\/li>\n<\/ol>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">Synthesis and characterizationof some ligands and mixed ligands complexes of \u03b2-enaminone with some metal ions and evaluation of their bacterial activity<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">By Hassan J.Khadum<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">Supervised by prof.Dr.Ahmed T.Numan<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">Summary\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">This research included the preparation and characterization of new ligands of type (HL1), (H2L2) and their mixed ligand complexes with a group of transition element ions of formula, K[M(L2)(3ph)] [M(L1)(3ph)].<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">M=[Co(II), Ni(II), Cu(II), Zn(II)andCd(II)] .<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">Where<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">\u00a0HL1=3-((2-amino-5-(3,4,5-trimethoxybenzyl)pyrimidin-4-yl)amino)-5,5-dimethylcyclohex-3-en-1-one(<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">H2L2= (E)-3-((3-((2-amino-5-(3,4,5-trimethoxybenzyl)pyrimidin-4-yl)amino)-5,5-dimethylcyclohex-3-en-1-ylidene)amino)phenolmethyl)naphthalen-2-ol<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">The prepared ligands were characterized by infrared (FT-IR), UV-Vis spectra, 1H, 13C-NMR, mass spectra, melting point, thin film chThe complexes were prepared from the reaction of the prepared ligands (HL1 and H2L2) with binary metal ions by in a retrograde escalation method using absolute ethanol as a solvent.<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">All the prepared complexes were characterized by spectroscopic methods, such as: infrared spectra, ultraviolet-visible radiation, chlorine content, the presence of chlorine ion or not by adding silver nitrate solution (AgNO3), melting point with molar conductivity measurements, microanalysis of the elements, absorption Atomic, magnetic susceptibility. The above measurements showed that the expected stereoscopic shape of the above complexes around the metallic and non-metallic ions [Co(II), Ni(II), Cu(II), Zn(II) andCd(II)]] is octahedral. The results of the magnetic susceptibility measurements also showed that some of the prepared complexes possess the characteristic of magnetic daya and others possess the characteristic of magnetic bar, which in turn reinforces the proposed shape.<\/span><\/h3>\n<h3 style=\"text-align: left;\"><span style=\"color: #993366;\">The biological activity of the prepared ligands and complexes was studied using the activation method. The result was that the prepared ligands and complexes showed antibacterial and antifungal activities. And the possible structures of the complexes prepared from ligands (tetradentateromatography. (TLC), the possible structures of ligands: (HL1 and H2L2)<\/span><\/h3>\n<h3 style=\"text-align: left;\"><\/h3>\n","protected":false},"excerpt":{"rendered":"<p>\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 ( \u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0628\u0639\u0636 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648 \u0645\u0639\u0642\u062f\u0627\u062a&#8230;.<a class=\"cz_readmore\" href=\"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=44420\"><i class=\"fa fa-angle-left\" aria-hidden=\"true\"><\/i><span>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":44422,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"no","_lmt_disable":"","footnotes":""},"categories":[7,59,68,98,16],"tags":[],"class_list":["post-44420","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-59","category-68","category-98","category-16"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/44420","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=44420"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/44420\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/44422"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=44420"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=44420"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=44420"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}