{"id":47229,"date":"2022-12-10T20:07:00","date_gmt":"2022-12-10T17:07:00","guid":{"rendered":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=47229"},"modified":"2023-06-28T01:06:37","modified_gmt":"2023-06-27T22:06:37","slug":"47229","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=47229","title":{"rendered":"\u0631\u0633\u0627\u0644\u0629 \u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u062a\u062d\u0636\u0631 \u0648\u062a\u0634\u062e\u0635 \u0645\u0639\u0642\u062f\u0627\u062a \u062c\u062f\u064a\u062f\u0629 \u0644\u0628\u0639\u0636 \u0645\u0634\u062a\u0642\u0627\u062a \u0627\u0644\u0643\u0644\u0627\u064a\u0633\u064a\u0646 \u0648\u062a\u062f\u0631\u0633 \u0641\u0639\u0627\u0644\u064a\u062a\u0647\u0627 \u0627\u0644\u062d\u064a\u0627\u062a\u064a\u0629"},"content":{"rendered":"

\"\"<\/strong><\/h4>\n

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    \n
  • \n

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  • \n

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  • \n

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  • \n

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    \"\"<\/h4>\n

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      \n
    1. \n

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    2. \n

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    3. \n

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    4. \n

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    5. \n

      \u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u062a\u0623\u062b\u064a\u0631\u0627\u062a \u0627\u0644\u062d\u064a\u0627\u062a\u064a\u0629 \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0646\u0648\u0627\u0639 \u0645\u062e\u062a\u0627\u0631\u0629 \u0645\u0646 \u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u0648\u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a.<\/h4>\n<\/li>\n<\/ol>\n

      <\/h4>\n

      \u0648\u062a\u0636\u0645\u0646\u062a \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u062d\u0636\u064a\u0631 \u0643\u0644 \u0645\u0646 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u0627\u0644\u062c\u062f\u064a\u062f\u064a\u0646 \u0627\u0644\u0645\u0634\u062a\u0642\u064a\u0646 \u0645\u0646 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0627\u0645\u064a\u0646\u064a \u0627\u0644\u0643\u0644\u0627\u064a\u0633\u064a\u0646 \u062d\u064a\u062b \u062a\u0643\u0648\u0646\u00a0 \u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u0633\u0646 \u0645\u0639 \u0628\u0639\u0636 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0645\u0627 \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0648\u062d\u0636\u0631 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u00a0\u00a0<\/sub>\u00a0\u00a0-4 ))]\u0645\u064a\u062b\u0648\u0643\u0633\u064a \u0628\u0646\u0632\u0648\u064a\u0644 )\u0643\u0627\u0631\u0628\u0627\u0645\u064a\u062b\u0648\u064a\u0644 )\u0643\u0644\u0627\u064a\u0633\u064a\u0646 ]\u00a0 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0645\u0641\u0627\u0639\u0644\u0629 (4-\u0645\u064a\u062b\u0648\u0643\u0633\u064a \u0628\u0646\u0632\u0648\u064a\u0644\u00a0 \u0643\u0644\u0648\u0631\u0627\u064a\u062f\u00a0 \u0648\u062b\u0627\u064a\u0648\u0633\u064a\u0627\u0646\u0627\u062a \u0627\u0644\u0627\u0645\u0648\u0646\u064a\u0648\u0645 \u0645\u0639 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0627\u0645\u064a\u0646\u064a \u0627\u0644\u0643\u0644\u0627\u064a\u0633\u064a\u0646) \u0648\u0630\u0644\u0643 \u0628\u0623\u0633\u062a\u0639\u0645\u0627\u0644 \u0645\u0630\u064a\u0628 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646MCG) \u00a0)\u0648\u0643\u0645\u0627 \u062d\u0636\u0631\u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u00a0<\/sub>[((2-\u0643\u0644\u0648\u0631\u0648 \u0627\u0633\u062a\u0627\u064a\u0644) \u0643\u0627\u0631\u0628\u0627\u0645\u064a\u062b\u0648\u064a\u0644 ) \u0643\u0644\u0627\u064a\u0633\u064a\u0646 ] \u0645\u0646 \u0645\u0641\u0627\u0639\u0644\u0629 (\u0643\u0644\u0648\u0631\u0648 \u0627\u0633\u062a\u0627\u064a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f \u0648\u062b\u0627\u064a\u0648\u0633\u064a\u0627\u0646\u0627\u062a \u0627\u0644\u0627\u0645\u0648\u0646\u064a\u0648\u0645 \u0645\u0639 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0627\u0645\u064a\u0646\u064a \u0627\u0644\u0643\u0644\u0627\u064a\u0633\u064a\u0646\u00a0 )\u00a0 \u0648\u0630\u0644\u0643 \u0628\u0623\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0645\u0630\u064a\u0628 \u0646\u0641\u0633\u0647 (CCG) \u0648\u0642\u062f \u0634\u062e\u0635\u062a \u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a\u00a0 \u0627\u0644\u0645\u062d\u0636\u0631\u0629\u00a0 \u00a0MCG\u0648 CCG\u00a0 \u00a0\u0628\u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0627\u0634\u0639\u0629 \u0627\u0644\u062d\u0645\u0631\u0627\u0621 (FT-IR) \u0648\u0628\u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0627\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 (Uv-Vis) \u0648\u0628\u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0648\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a 1<\/sup>HNMR )\u00a0 <\/sup>, 13<\/sup>C) \u0648\u0628\u0623\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0643\u0645\u064a \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631 (C.H.N.S) \u0648\u0627\u0644\u0646\u062a\u0627\u0626\u062c \u0627\u0638\u0647\u0631\u062a \u0645\u0637\u0627\u0628\u0642\u0629 \u062f\u0642\u064a\u0642\u0629 \u0645\u0639 \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a\u0629 \u0627\u0644\u062c\u0632\u064a\u0626\u064a\u0629\u00a0 \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a\u00a0 \u0627\u0644\u0645\u062d\u0636\u0631\u0629<\/h4>\n

      \u00a0 <\/sub>(MCG)\u00a0 L1<\/sub>=\u00a0 C11<\/sub>H12<\/sub>N2<\/sub>O4 <\/sub>S<\/h4>\n

      \u00a0 <\/sub>(CCG)\u00a0 L2<\/sub>=\u00a0 C5<\/sub>H7<\/sub>N2<\/sub>O3<\/sub>S Cl<\/h4>\n

      \u062d\u0636\u0631\u062a \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0644\u0643\u0644 \u0645\u0646 \u0645\u0644\u062d\u064a \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646\u00a0 \u0628\u0648\u0627\u0633\u0637\u0629 \u0645\u0641\u0627\u0639\u0644\u0629 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624\u00a0\u00a0 VO+2<\/sup>\u0648 Mn+2<\/sup>\u0648 Co+2 <\/sup>\u0648Ni+2<\/sup>\u0648Cu+2 <\/sup>\u0648 Zn+2<\/sup>\u0648 Cd+2<\/sup>\u0648 Hg+2<\/sup>\u00a0 \u0645\u0639 \u0643\u0644 \u0645\u0646\u0647\u0645\u0627 \u062d\u064a\u062b \u0634\u062e\u0635\u062a \u0648\u062f\u0631\u0633\u062a \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0639\u0646 \u0637\u0631\u064a\u0642 \u0627\u062e\u062a\u0628\u0627\u0631\u0642\u0627\u0628\u0644\u064a\u0629 \u0627\u0644\u0630\u0648\u0628\u0627\u0646 \u0648\u0642\u064a\u0627\u0633 \u0643\u0644 \u0645\u0646 \u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629 \u0648\u062a\u0639\u064a\u064a\u0646 \u0643\u0644\u0627 \u0645\u0646 \u062f\u0631\u062c\u0627\u062a \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631\u0648\u0627\u0644\u062a\u0641\u0643\u0643 \u0648\u0645\u0646 \u0645\u0639\u0631\u0641\u0629 \u062a\u0642\u0646\u064a\u0627\u062a \u0623\u0644\u0627\u0637\u064a\u0627\u0641 \u0644\u0643\u0644 \u0645\u0646 \u0627\u0644\u0627\u0634\u0639\u0629 \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648\u0627\u0644\u0627\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u2013\u00a0 \u0627\u0644\u0645\u0631\u0626\u064a\u0629\u00a0 \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u0643\u0645\u064a \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0648\u062a\u0642\u0646\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a \u0627\u0644\u0644\u0647\u0628\u064a \u062a\u0645 \u062a\u0639\u064a\u064a\u0646 \u0646\u0633\u0628\u0629\u00a0 \u0627\u0644\u0641\u0644\u0632 \u0648\u0623\u0633\u062a\u0646\u0627\u062f\u0627\u00a0 \u0644\u0644\u0646\u062a\u0627\u0626\u062c \u0627\u0644\u062a\u064a \u062a\u0645 \u0627\u0644\u062d\u0635\u0648\u0644 \u0639\u0644\u064a\u0647\u0627\u00a0 \u0627\u0642\u062a\u0631\u062d \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0647\u0630\u0647<\/h4>\n

      ( Mn+2<\/sup>\u0648 \u00a0<\/sup>Co+2<\/sup>\u0648Ni+2<\/sup>\u0648\u00a0 Zn+2<\/sup>\u0648Cd+2<\/sup>\u0648 Hg+2<\/sup>)\u00a0 \u0634\u0643\u0644 \u0631\u0628\u0627\u0639\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0648\u0627\u0642\u062a\u0631\u062d \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u064a\u0648\u0646 \u0627\u0644\u0646\u062d\u0627\u0633 Cu+2<\/sup> \u0627\u0644\u0634\u0643\u0644 \u0627\u0644\u0645\u0631\u0628\u0639 \u0627\u0644\u0645\u0633\u062a\u0648\u064a \u0648\u0643\u0630\u0644\u0643 \u0627\u0642\u062a\u0631\u062d\u00a0 \u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 VO+2<\/sup>\u00a0 \u0627\u0644\u0634\u0643\u0644 \u0627\u0644\u0647\u0631\u0645 \u0627\u0644\u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 .<\/h4>\n

      \u0648\u062f\u0631\u0633\u062a \u0644\u0644\u0645\u0634\u062a\u0642\u0627\u062a \u0648\u0628\u0639\u0636 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u062d\u064a\u0627\u062a\u064a\u0629\u00a0 \u0636\u062f \u0646\u0648\u0639\u064a\u0646 \u0645\u0646 \u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u0627\u0644\u0645\u062e\u062a\u0627\u0631\u0629\u00a0 \u0646\u0648\u0639 \u0645\u0648\u062c\u0628\u0629 \u0644\u0647\u0627 \u0623\u0633\u062a\u062c\u0627\u0628\u0629 \u0644\u0635\u0628\u063a\u0629 \u0643\u0631\u0627\u0645 \u00a0staphylaccus aureu<\/em><\/strong>\u00a0 \u0648\u0646\u0648\u0639 \u0627\u062e\u0631\u00a0 \u0633\u0627\u0644\u0628\u0629 \u0644\u064a\u0633 \u0644\u0647\u0627 \u0623\u0633\u062a\u062c\u0627\u0628\u0629 \u0644\u0635\u0628\u063a\u0629\u00a0 \u0643\u0631\u0627\u0645 \u00a0Eschcrichira coli<\/em><\/strong>\u00a0\u00a0 \u0648\u0627\u064a\u0636\u0627\u00a0 \u0636\u062f \u0646\u0648\u0639 \u0645\u0646 \u0627\u0644\u0641\u0637\u0631Candida alicans\u00a0 <\/em><\/strong>\u00a0\u00a0<\/em>\u0648\u0642\u062f \u0627\u0638\u0647\u0631\u062a \u0627\u0644\u0646\u062a\u0627\u0626\u062c \u0627\u0644\u062a\u064a \u062a\u0645 \u0627\u0644\u062d\u0635\u0648\u0644 \u0639\u0644\u064a\u0647\u0627\u00a0 \u0647\u064a \u0627\u0645\u062a\u0644\u0627\u0643\u00a0 \u0643\u0644\u0627 \u0645\u0646 \u0627\u0644\u0645\u0634\u062a\u0642\u0627\u062a\u00a0 \u0648\u0628\u0639\u0636 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u0645\u062d\u0636\u0631\u0629\u00a0 \u0641\u0639\u0627\u0644\u064a\u0629 \u0645\u062e\u062a\u0644\u0641\u0629 (\u0645\u062a\u0641\u0627\u0648\u062a\u0629 ) \u0627\u062a\u062c\u0627\u0647 \u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u0648\u0627\u0644\u0641\u0637\u0631.<\/h4>\n

      <\/h4>\n

      \u0648\u062e\u0644\u0635\u062a \u0627\u0644\u0637\u0627\u0644\u0628\u0629 \u0641\u064a \u0646\u0647\u0627\u064a\u0629 \u0631\u0633\u0627\u0644\u062a\u0647\u0627 \u0627\u0644\u0649 \u0627\u0644\u062a\u0648\u0635\u064a\u0629 \u0628\u0627\u0644\u062f\u0631\u0627\u0633\u0627\u062a \u0627\u0644\u0645\u0633\u062a\u0642\u0628\u0644\u064a\u0629 \u0627\u0644\u0627\u062a\u064a\u0629:<\/strong><\/h4>\n

      1- \u062f\u0631\u0627\u0633\u0629 \u0648\u062a\u062d\u0636\u064a\u0631 \u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0623\u062e\u0631\u0649 \u0645\u0639 \u0628\u0639\u0636 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0645\u0646 \u0627\u0644\u062d\u0627\u0645\u0636 \u0627\u0644\u0627\u0645\u064a\u0646\u064a \u0627\u0644\u0643\u0644\u0627\u064a\u0633\u064a\u0646.<\/h4>\n

      2- \u062a\u062d\u0636\u064a\u0631\u0648 \u062f\u0631\u0627\u0633\u0629 \u0645\u0634\u062a\u0642\u0627\u062a \u062c\u062f\u064a\u062f\u0629 \u0644\u0644\u062d\u0648\u0627\u0645\u0636 \u0627\u0644\u0627\u0645\u064a\u0646\u064a\u0629 \u0627\u0644\u0627\u062e\u0631\u0649 \u0645\u0639 \u0628\u0639\u0636 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u062f\u0648\u0631\u0629 \u0627\u0644\u062b\u0627\u0646\u064a\u0629 \u0648\u0627\u0644\u062b\u0627\u0644\u062b\u0629 \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629.<\/h4>\n

      3- \u062f\u0631\u0627\u0633\u0629 \u0648\u062a\u0639\u064a\u064a\u0646 \u062b\u0648\u0627\u0628\u062a \u0627\u0644\u0627\u0633\u062a\u0642\u0631\u0627\u0631\u064a\u0629 \u0644\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0639\u0646\u062f \u062f\u0631\u062c\u0627\u062a \u062d\u0631\u0627\u0631\u064a\u0629 \u0645\u062e\u062a\u0644\u0641\u0629 \u0648\u062d\u0633\u0627\u0628 \u0627\u0644\u062b\u0648\u0627\u0628\u062a \u0627\u0644\u062b\u0631\u0645\u0648\u062f\u064a\u0646\u0627\u0645\u064a\u0643\u064a\u0629 \u0645\u062b\u0644 (\u0644\u0627\u0646\u062a\u0631\u0648\u0628\u064a\u2206S\u060c \u0637\u0627\u0642\u0629 \u0643\u0628\u0633 \u0627\u0644\u062d\u0631\u0629 G\u2206,\u0627\u0644\u0627\u0646\u062b\u0627\u0644\u0628\u064a \u0627\u0644\u062a\u0641\u0627\u0639\u0644 H \u2206).<\/h4>\n

      \u00a0-4\u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062e\u062a\u0644\u0637\u0629 \u0645\u0639 \u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0623\u062e\u0631\u0649.<\/h4>\n

      \u00a0-5\u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u0646\u0648\u0649 \u0645\u0639 \u0627\u0644\u0645\u0634\u062a\u0642\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 (MCG) \u0648 ((CCG<\/h3>\n
      \n

      – Preparation, identification and study of the biological activity of new complexes of some glycine derivatives with some metal ion salts<\/span><\/h3>\n

      \u00a0Raghad Abdul Sattar Fadhil Mahdi<\/span><\/h3>\n

      Prof. Dr. Basma Mohsen Sarhan \/Chemistry Department<\/span><\/h3>\n

      – The aim of the research<\/span><\/h3>\n

      – Preparation of two new derivatives, the first ligand and the second ligand containing N,O electron-donating atoms that are binary, through the reaction of the primary materials, which are (4-methoxybenzoyl chloride)<\/span><\/h3>\n

      – 2-Preparation of a series of metal complexes by reacting 2mol of the prepared ligands with 1mol of divalent metal ions M++ = Mn, Co, Ni, Cu, Zn, Cd and Hg and tetravalent V+4 O-2.<\/span><\/h3>\n

      3- Studying and determining the stability constants of the prepared complexes at different temperatures and calculating the thermodynamic constants such as (entropy \u2206S, free compressive energy G\u2206, enthalpy of interaction H \u2206).<\/span><\/h3>\n

      \u00a0– Preparation and characterization of some mixed complexes with other ligands.<\/span><\/h3>\n

      \u00a0– Preparation and characterization of some binuclear complexes with prepared derivatives (MCG) and (CCG)<\/span><\/h3>\n

      Abstract<\/span><\/h3>\n

      This study included the preparation of each of the two new ligandins derived from the amino acid glycine, which is dimericwith some of their metal complexes. Acetone (MCG)) or operation of the ligand [((2-chloroethyl)carbamethoyl)glycine] from the reaction of (chloroacetyl chloride and ammonium thiocyanate with histidine glycine)This was done by using the same solvent (CCG). These prepared ligands, MCG and CCG, were identified by FT-IR, UV-Vis, 1HNMR, 13C) and by accurate quantitative analysis of the elements (C.H.N.S) and the results. It showed an exact match with the molecular chemical formulas of the prepared ligands<\/span><\/h3>\n

      \u00a0 (MCG)\u00a0 L1= \u00a0C11H12N2O4 S<\/span><\/h3>\n

      \u00a0 (CCG)\u00a0 L2=\u00a0 C5H7N2O3S Cl<\/span><\/h3>\n

      Some metal complexes of each of the two salts of licandene were prepared by reacting divalent metal ions VO+2, Mn+2, Co+2, Ni+2, Cu+2, Zn+2, Cd+2, and Hg+2 with each of them. These prepared complexes were diagnosed and studied by susceptibility test. Solubility, magnetic susceptibility, molar conductivity, determination of melting and dissociation degrees, and knowledge of spectra techniques for both infrared and ultraviolet visible rays, and accurate quantitative elemental analysis of some of the prepared complexes, and the atomic absorption technique of the flame, the metal ratio was determined. Based on the obtained results, it was proposed for these complexes<\/span><\/h3>\n

      (Mn+2, Co+2, Ni+2, Zn+2, Cd+2, and Hg+2) has a tetrahedral shape, and it is suggested for the Cu+2 ion complexes the flat square shape, as well as for the VO+2 vanadyl ion complexes, the square base pyramid was suggested<\/span><\/h3>\n

      The bioactivity of the prepared derivatives and some of their complexes was studied against two types of selected bacteria, one positive in response to staphylaccusaureu and another negative type that does not respond to the cream dye Eschcrichira coli, as well as against a type of fungus Candida alicans. The results obtained showed the possession of both derivatives and some of their complexes. The preparation has different (variable) activity against bacteria and fungi<\/span><\/h3>\n

      Prospective Studies<\/span><\/h3>\n

      – Study and preparation of other ligands with some of their metal complexes from the amino acid glycine<\/span><\/h3>\n

      \u00a0Preparation and study of new derivatives of other amino acids with some of their complexes for the ions of the second and third cycles with the prepared ligands<\/span><\/h3>\n

      -Study and determination of the stability constants of the complexes prepared at different temperatures and the calculation of the thermodynamic constants such as (entropy, free pressure energy G\u2206, enthalpy reaction H\u2206)<\/span><\/h3>\n

      \u00a0 Preparation and characterization of some complexes mixed with ligands<\/span><\/h3>\n

      Preparation and characterization of some binuclear complexes with prepared derivatives (MCG) and (CCG .).<\/span><\/h3>\n

       <\/p>\n","protected":false},"excerpt":{"rendered":"

      \u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 ” \u00a0\u062a\u062d\u0636\u064a\u0631, \u062a\u0634\u062e\u064a\u0635 \u0648\u062f\u0631\u0627\u0633\u0629 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u062d\u064a\u0627\u062a\u064a\u0629 \u0644\u0645\u0639\u0642\u062f\u0627\u062a….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":47234,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"no","_lmt_disable":"","footnotes":""},"categories":[7,59,68,98,79,16],"tags":[23,61,47],"class_list":["post-47229","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-59","category-68","category-98","category-chem-dept","category-16","tag-ihcoedu","tag-61","tag-chem"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/47229","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=47229"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/47229\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/47234"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=47229"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=47229"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=47229"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}