{"id":51956,"date":"2023-07-02T23:07:34","date_gmt":"2023-07-02T20:07:34","guid":{"rendered":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=51956"},"modified":"2023-07-02T23:30:34","modified_gmt":"2023-07-02T20:30:34","slug":"51956","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=51956","title":{"rendered":"\u0631\u0633\u0627\u0644\u0629 \u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u062a\u062d\u0636\u0631 \u0648 \u062a\u0634\u062e\u0635 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u00a0\u0644\u0628\u0639\u0636 \u0627\u0644\u0641\u0644\u0632\u0627\u062a \u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624 \u0648 \u062b\u0644\u0627\u062b\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624 \u0645\u0639 \u0642\u0627\u0639\u062f\u0629 \u0634\u064a\u0641 \u0645\u0634\u062a\u0642\u0629 \u0645\u0646 \u0627\u0644\u0643\u0631\u0643\u0645\u064a\u0646"},"content":{"rendered":"

\"\"<\/p>\n

\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 – \u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645\u00a0 \u060c \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 ” \u062a\u062d\u0636\u064a\u0631 \u0648 \u062a\u0634\u062e\u064a\u0635 \u0645\u0639\u0642\u062f\u0627\u062a \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u00a0 \u0644\u0628\u0639\u0636 \u0627\u0644\u0641\u0644\u0632\u0627\u062a \u062b\u0646\u0627\u0626\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624 \u0648 \u062b\u0644\u0627\u062b\u064a\u0629 \u0627\u0644\u062a\u0643\u0627\u0641\u0624 \u0645\u0639 \u0642\u0627\u0639\u062f\u0629 \u0634\u064a\u0641 \u0645\u0634\u062a\u0642\u0629 \u0645\u0646 \u0627\u0644\u0643\u0631\u0643\u0645\u064a\u0646 ” \u0644\u0644\u0637\u0627\u0644\u0628\u0629 ”\u00a0\u0647\u0627\u0644\u0647 \u0645\u062d\u0645\u062f \u0635\u0627\u0644\u062d ” \u0627\u0644\u062a\u064a \u0627\u0646\u062c\u0632\u062a\u0647\u0627 \u0628\u0627\u0634\u0631\u0627\u0641 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a\u0629 \u0641\u064a \u0627\u0644\u0642\u0633\u0645 ”\u00a0\u0627.\u062f. \u062a\u063a\u0631\u064a\u062f \u0647\u0627\u0634\u0645 \u0627\u0644\u0646\u0648\u0631 ” .<\/p>\n

\u064a\u062a\u0646\u0627\u0648\u0644 \u0627\u0644\u0639\u0645\u0644 \u0627\u0644\u0645\u0642\u062f\u0645 \u0641\u064a \u0647\u0630\u0647 \u0627\u0644\u0631\u0633\u0627\u0644\u0629 \u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 :<\/p>\n

\u0623\u200c)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \u00a0\u0642\u0627\u0639\u062f\u0629 \u0634\u0641\u00a0 \u00a0(L) \u00a0\u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0647\u00a0 : :\u00a0 (1E,5Z,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)-5-((3-hydroxyphenyl)imino)hepta-1,6-dien-3-one\u00a0 \u00a0\u0645\u0646 \u0627\u0644\u0643\u0631\u0643\u0645\u064a\u0646 Curcumin (Curc) \u0645\u0639 3-\u0627\u0645\u064a\u0646\u0648 \u0641\u064a\u0646\u0648\u06443-amino phenol \u0627\u0644\u0645\u062a\u0636\u0645\u0646 (N, O) \u0643\u0630\u0631\u0627\u062a \u0648\u0627\u0647\u0628\u0629 \u0646\u0648\u0639 (NO)<\/p>\n

\u0628\u200c)\u00a0 \u0645\u0639\u0642\u062f\u0627\u062a \u0641\u0644\u0632\u064a\u0629 \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0642\u0627\u0639\u062f\u0629 \u0634\u0641 \u00a0(L) \u00a0\u0643\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0648\u0644\u064a \u0648\u0627\u0644\u0641\u0627- \u062d\u0627\u0645\u0636 \u0627\u0645\u064a\u0646\u064a 3-(3,4-Di-hydroxyphenyl)-L-alanine))\u00a0\u00a0\u00a0\u00a0 L-dopa \u0645\u0639 M (II)<\/p>\n

\u062a\u200c)\u00a0 \u00a0\u0645\u0639\u0642\u062f\u0627\u062a \u0641\u0644\u0632\u064a\u0629 \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644\u00a0 L-dopa \u0648 Curcumin \u0645\u0639 M (II)\u0648 M’ (III) \u00a0\u0643\u0645\u0627 \u0645\u062f\u0631\u062c \u0641\u064a \u0627\u0644\u062c\u062f\u0648\u0644 \u0627\u0644\u0627\u062a\u064a :<\/p>\n\n\n\n\n\n\n
\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0648\u0644\u064a<\/p>\n

1\u00a0 \u0645\u0644\u064a \u0645\u0648\u0644<\/td>\n

\u0644\u064a\u0643\u0627\u0646\u062f \u062b\u0627\u0646\u0648\u064a<\/td>\n\u0627\u0644\u062a\u0631\u0627\u0643\u064a\u0628<\/td>\n<\/tr>\n
L<\/p>\n

Schiff base<\/p>\n

1\u00a0 \u0645\u0644\u064a \u0645\u0648\u0644<\/td>\n

L-dopa<\/p>\n

2\u00a0 \u0645\u0644\u064a \u0645\u0648\u0644<\/p>\n

 <\/td>\n

[M (L) (L-dopa)2]<\/p>\n

M=\u00a0 Mn(II), Ni(II), Cu(II), Zn(II), Cd(II)<\/td>\n<\/tr>\n

\u0627\u0644\u0643\u0631\u0643\u0645\u064a\u0646 Curcumin<\/p>\n

(Curc)<\/p>\n

1\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \u00a0\u00a0\u0645\u0644\u064a \u0645\u0648\u0644<\/td>\n

L-dopa<\/p>\n

2\u00a0 \u0645\u0644\u064a \u0645\u0648\u0644<\/td>\n

[M (Curc) (L-dopa)2]<\/p>\n

[M (Cur) (L-dopa)2]<\/p>\n

M=\u00a0 Mn(II), Fe(II),Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II). mg(II),Ca(II),Sn(II),and pb(II).<\/td>\n<\/tr>\n

[M’ (Curc)(L-dopa)2]Cl<\/p>\n

M’= Al(III) , Cr(III). La(III).<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

 <\/p>\n

\u062a\u0645 \u062a\u0634\u062e\u064a\u0635 \u0642\u0627\u0639\u062f\u0629 \u0634\u0641\u00a0\u00a0 \u0628\u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621(FT-IR) \u0648\u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629(UV\u2013Vis) \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631 (C.H.N) \u0648\u00a0 \u0645\u0637\u064a\u0627\u0641\u064a\u0629\u00a0 \u0627\u0644\u0631\u0646\u064a\u0646\u00a0 \u0627\u0644\u0646\u0648\u0648\u064a\u00a0 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u00a0 1H,13C-NMR \u0648\u0645\u0637\u064a\u0627\u0641\u064a\u0629\u00a0 \u0627\u0644\u0643\u062a\u0644\u0629\u00a0 \u0648\u00a0 \u062f\u0631\u062c\u0627\u062a\u00a0 \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631 \u0648 \u0627\u0644\u0627\u0634\u0643\u0627\u0644\u00a0 \u0627\u0644\u0641\u0631\u0627\u063a\u064a\u0629\u00a0 \u0627\u0644\u0645\u0642\u062a\u0631\u062d\u0629\u00a0 \u0644\u0644\u0645\u0631\u0643\u0628\u0627\u062a\u00a0 \u0627\u0644\u0645\u062d\u0636\u0631\u0629\u00a0 \u0631\u0633\u0645\u062a\u00a0 \u0628\u0648\u0633\u0627\u0637\u0629\u00a0 \u0628\u0631\u0646\u0627\u0627\u0645\u062c<\/p>\n

Ultra \u2013 chem.\u00a0 office\u00a0 program,\u00a0 3DX\u00a0 (2019)\u00a0 \u0648\u0643\u0645\u0627\u00a0 \u0645\u0628\u064a\u0646\u00a0 \u0641\u064a\u00a0 \u0627\u0627\u0644\u0634\u0643\u0644\u00a0\u00a0 \u0627\u0644\u0627\u062a\u064a\u00a0 \u0644\u0644\u064a\u0643\u0627\u0646\u062f:<\/p>\n

\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u062f\u0631\u0633\u062a \u0645\u0646 \u0627\u0644\u0646\u0648\u0627\u062d\u064a \u0627\u0644\u0622\u062a\u064a\u0629: \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629\u060c \u0627\u0644\u062f\u0631\u0627\u0633\u0627\u062a \u0627\u0644\u0637\u064a\u0641\u064a\u0629 (\u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621\u060c \u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629\u2013 \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648 \u0645\u0637\u064a\u0627\u0641\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a) \u0641\u0636\u0644\u0627 \u0639\u0646 \u0642\u064a\u0627\u0633\u0627\u062a \u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0643\u0644\u0648\u0631 \u0642\u064a\u0645 \u0627\u0644\u0639\u0632\u0648\u0645 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u00a0\u0648\u0627\u0644\u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0627\u0644\u0643\u062a\u0631\u0648\u0646\u064a\u0629 \u0644\u062c\u0645\u064a\u0639 \u00a0\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u062f\u0644\u062a \u0639\u0644\u0649 \u0623\u0646 \u062c\u0645\u064a\u0639 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0647\u0627 \u0628\u0646\u064a\u0629 \u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d .<\/p>\n

[M(II)-(L)-(L-dopa)2]<\/p>\n

[M(III) -(Curc)-(L-dopa)2]Cl<\/p>\n

\u0648\u064a\u062a\u0636\u0645\u0646 \u0627\u0644\u0628\u062d\u062b \u0627\u0633\u062a\u0639\u0645\u0627\u0644\u00a0\u00a0 \u0627\u0644\u0623\u0635\u0628\u0627\u063a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0639\u0644\u0649 \u062e\u064a\u0648\u0637 \u0623\u0644\u064a\u0627\u0641 \u0627\u0644\u0642\u0637\u0646 \u0648\u0627\u0644\u0635\u0648\u0641 \u0643\u0645\u0627 \u062a\u0645 \u0627\u062e\u062a\u0628\u0627\u0631 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0627\u0644\u0645\u0636\u0627\u062f\u0629 \u0644\u0644\u0628\u0643\u062a\u0631\u064a\u0627\u00a0 \u0644\u0642\u0627\u0639\u062f\u0629 \u0634\u0641\u00a0 \u0645\u0639\u00a0 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u062a\u062c\u0627\u0647 \u0627\u062b\u0646\u064a\u0646 \u0645\u0646 \u00a0\u0627\u0644\u0628\u0643\u062a\u0631\u064a\u0627 \u0647\u064a\u00a0 :\u00a0 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0staphylococcus aureus\u00a0 \u0648\u00a0\u00a0\u00a0 ,klebsiella pneumonia<\/p>\n

\u0648\u0627\u0644\u0641\u0637\u0631 \u0645\u0646 \u0646\u0648\u0639: Candida albicans .<\/p>\n","protected":false},"excerpt":{"rendered":"

\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 – \u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645\u00a0 \u060c \u0631\u0633\u0627\u0644\u0629 \u0627\u0644\u0645\u0627\u062c\u0633\u062a\u064a\u0631 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 ” \u062a\u062d\u0636\u064a\u0631 \u0648 \u062a\u0634\u062e\u064a\u0635 \u0645\u0639\u0642\u062f\u0627\u062a….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":51961,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"no","_lmt_disable":"","footnotes":""},"categories":[44,7,59,98,79,16],"tags":[23,61,47],"class_list":["post-51956","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-44","category-7","category-59","category-98","category-chem-dept","category-16","tag-ihcoedu","tag-61","tag-chem"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/51956","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=51956"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/51956\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/51961"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=51956"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=51956"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=51956"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}