{"id":51990,"date":"2023-07-03T14:33:04","date_gmt":"2023-07-03T11:33:04","guid":{"rendered":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=51990"},"modified":"2023-07-04T08:11:23","modified_gmt":"2023-07-04T05:11:23","slug":"51990","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=51990","title":{"rendered":"\u0627\u0637\u0631\u0648\u062d\u0629 \u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u062a\u062d\u0636\u0631 \u0648\u062a\u0634\u062e\u0635 \u0628\u0639\u0636 \u0627\u0644\u0645\u0631\u0643\u0628\u0627\u062a \u00a0\u0627\u0644\u0627\u0645\u064a\u0646\u064a\u0629 \u0627\u0644\u0639\u0636\u0648\u064a\u0629 \u0627\u0644\u062c\u062f\u064a\u062f\u0629 \u0627\u0644\u0645\u062d\u062a\u0648\u064a\u0629 \u0639\u0644\u0649 \u0630\u0631\u0627\u062a \u0645\u0627\u0646\u062d\u0629 \u0645\u0639 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0648\u062a\u062f\u0631\u0633\u0647\u0627 \u0648\u062f\u0631\u0627\u0633\u0629 \u0628\u064a\u0648\u0644\u0648\u062c\u064a\u0627"},"content":{"rendered":"

\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 ( \u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0648\u062f\u0631\u0627\u0633\u0629 \u0628\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0631\u0643\u0628\u0627\u062a \u00a0\u0627\u0644\u0627\u0645\u064a\u0646\u064a\u0629 \u0627\u0644\u0639\u0636\u0648\u064a\u0629 \u0627\u0644\u062c\u062f\u064a\u062f\u0629 \u0627\u0644\u0645\u062d\u062a\u0648\u064a\u0629 \u0639\u0644\u0649 \u0630\u0631\u0627\u062a \u0645\u0627\u0646\u062d\u0629 \u0645\u0639 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u0641\u0644\u0632\u064a\u0629 ) \u0644\u0644\u0637\u0627\u0644\u0628\u0629 (\u00a0\u062b\u0631\u064a\u0647 \u0639\u0628\u062f \u0627\u0644\u0642\u0627\u062f\u0631 \u0637\u0627\u0647\u0631 ) \u0627\u0644\u062a\u064a \u0627\u0646\u062c\u0632\u062a\u0647\u0627 \u0628\u0627\u0634\u0631\u0627\u0641 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a\u0629 \u0641\u064a \u0627\u0644\u0642\u0633\u0645 (\u00a0\u0627.\u062f. \u0628\u0627\u0633\u0645\u0647 \u0645\u062d\u0633\u0646 \u0633\u0631\u062d\u0627\u0646 ).<\/p>\n

 <\/p>\n

\u0648\u062a\u0645 \u0641\u064a \u0647\u0630\u0647 \u0627\u0644\u062f\u0631\u0627\u0633\u0629 \u062a\u062d\u0636\u064a\u0631 \u0627\u0631\u0628\u0639\u0629 \u0644\u064a\u0643\u0646\u062f\u0627\u062a \u062c\u062f\u064a\u062f\u0647 \u00a0\u0645\u0634\u062a\u0642\u0629 \u0645\u0646 \u0627\u0644\u0633\u0627\u064a\u062a\u0648\u0633\u064a\u0646 \u0648\u0627\u0644\u0628\u064a\u062a\u0627 \u0627\u0644\u0627\u0646\u064a\u0646 \u0645\u0639 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0627\u0644\u0644\u064a\u0643\u0646\u062f \u0627\u0644\u0627\u0648\u0644 \u00a0\u0648\u0627\u0644\u0630\u064a \u062a\u0645 \u00a0\u062a\u062d\u0636\u064a\u0631\u0647 \u0645\u0646 \u062a\u0641\u0627\u0639\u0644 \u0627\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f \u0645\u0639 \u062b\u0627\u064a\u0648 \u0633\u064a\u0627\u0646\u0627\u062a \u0627\u0644\u0627\u0645\u0648\u0646\u064a\u0648\u0645 \u0648\u0627\u0644\u0633\u0627\u064a\u062a\u0648\u0633\u064a\u0646 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0643\u0645\u0630\u064a\u0628 \u0645\u0639 \u0627\u0644\u062a\u0635\u0639\u064a\u062f \u0627\u0644\u0639\u0643\u0633\u064a \u0644\u0645\u062f\u0629 \u0633\u062a \u0633\u0627\u0639\u0627\u062a \u0627\u0644\u0649 \u062b\u0645\u0627\u0646\u064a \u0633\u0627\u0639\u0627\u062a:<\/p>\n

\u0627\u0644\u0644\u064a\u0643\u0646\u062f \u0627\u0644\u0627\u0648\u0644 : L1<\/sub>: (DPA) = (N-(2-oxo-1,2-dihydropyrimidin-4-ylcarbamothioyl)acetamide) .<\/p>\n

\u0648 \u0627\u0644\u0644\u0643\u0646\u062f \u0627\u0644\u062b\u0627\u0646\u064a : L2<\/sub>\u00a0 :(MPB) = 4-methoxy -N-(2-oxo-1,2-dihydropyrimidin-4- ylcarbamothioyl ) benzamide<\/p>\n

\u0648\u0627\u0644\u0630\u064a \u062d\u0636\u0631 \u0645\u0646 \u062a\u0641\u0627\u0639\u0644 4- \u0645\u064a\u062b\u0648\u0643\u0633\u064a \u0628\u0646\u0632\u0648\u064a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f \u0645\u0639 \u062b\u0627\u064a\u0648 \u0633\u064a\u0627\u0646\u0627\u062a \u0627\u0644\u0627\u0645\u0648\u0646\u064a\u0648\u0645 \u0648\u0627\u0644\u0633\u0627\u064a\u062a\u0648\u0633\u064a\u0646\u00a0 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0643\u0645\u0630\u064a\u0628\u060c<\/p>\n

\u0627\u0645\u0627 \u0627\u0644\u0644\u0643\u0646\u062f \u0627\u0644\u062b\u0627\u0644\u062b : L3<\/sub>:(ATA)3-(acetylthioureido)propanoicacid\u00a0 \u0648\u0627\u0644\u0630\u064a \u062d\u0636\u0631 \u0645\u0646 \u062a\u0641\u0627\u0639\u0644 \u0627\u0633\u064a\u062a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f \u0645\u0639 \u062b\u0627\u064a\u0648 \u0633\u064a\u0627\u0646\u0627\u062a \u0627\u0644\u0627\u0645\u0648\u0646\u064a\u0648\u0645 \u0648\u0628\u064a\u062a\u0627 \u0627\u0644\u0627\u0646\u064a\u0646 \u00a0\u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645\u00a0 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0643\u0645\u0630\u064a\u0628 .<\/p>\n

\u0648 \u0642\u062f \u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0627\u0644\u0644\u0643\u0646\u062f \u0627\u0644\u0631\u0627\u0628\u0639 :\u00a0L4<\/sub>: (MTA)3-(3-(4- methoxy thioureido)propanoic acid\u00a0\u0648\u0627\u0644\u0630\u064a \u062d\u0636\u0631 \u0645\u0646 \u062a\u0641\u0627\u0639\u0644 4- \u0645\u064a\u062b\u0648\u0643\u0633\u064a \u0628\u0646\u0632\u0648\u064a\u0644 \u0643\u0644\u0648\u0631\u0627\u064a\u062f \u0645\u0639 \u062b\u0627\u064a\u0648 \u0633\u064a\u0627\u0646\u0627\u062a \u0627\u0644\u0627\u0645\u0648\u0646\u064a\u0648\u0645 \u0648\u0627\u0644\u0628\u064a\u062a\u0627 \u0627\u0644\u0627\u0646\u064a\u0646 \u00a0\u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0644\u0627\u0633\u064a\u062a\u0648\u0646 \u0643\u0645\u0630\u064a\u0628 \u0648\u0634\u062e\u0635\u062a \u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0646\u062f\u0627\u062a \u00a0, (DPA) (MPB)), (ATA) , (MTA) , \u0628\u0648\u0627\u0633\u0637\u0647 FT-IR1<\/sup>H,13<\/sup>C-NMR, ,UV-Vis ,Mass spectra\u00a0 \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631 (C.H.N.S).<\/p>\n

(DPA) L1<\/sub> = C7<\/sub>H8<\/sub> N4<\/sub>O2<\/sub>S<\/p>\n

(MPB) L2<\/sub> = C13<\/sub>H12<\/sub>N4<\/sub> O3 <\/sub>S<\/p>\n

(ATA) L3\u00a0 <\/sub>= C6<\/sub>H10<\/sub>N2 <\/sub>O3 <\/sub>S<\/p>\n

(MTA) L4<\/sub>= C12<\/sub>H14<\/sub>N2<\/sub> O4<\/sub>S<\/p>\n

\u062a\u0645 \u0645\u0641\u0627\u0639\u0644\u0647 \u0627\u0644\u0644\u064a\u0643\u0646\u062f\u0627\u062a \u0627\u0644\u0627\u0631\u0628\u0639\u0647 \u0645\u0639\u00a0 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629\u00a0 \u0648\u00a0(VO+2<\/sup>, Mn+2<\/sup>, Co+2<\/sup>, Ni+2<\/sup> , Cu+2<\/sup>, Zn+2<\/sup>, Cd+2<\/sup> and Hg+2<\/sup>)<\/p>\n

\u062a\u0645\u064a\u0632\u062a \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u00a0\u0628\u0642\u0627\u0628\u0644\u064a\u0629 \u0630\u0648\u0628\u0627\u0646\u0647\u0627 \u0642\u064a \u00a0\u0628\u0639\u0636 \u0627\u0644\u0645\u0630\u064a\u0628\u0627\u062a \u060c\u0648\u062a\u0645 \u0642\u064a\u0627\u0633 \u00a0\u0646\u0642\u0637\u0629 \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631 \u0648\u0642\u064a\u0627\u0633 \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0647 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0647 \u0644\u0647\u0627\u060c \u0642\u064a\u0627\u0633\u0627\u062a \u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u060c \u0627\u0644\u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0625\u0644\u0643\u062a\u0631\u0648\u0646\u064a\u0629 \u0648\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0639\u0646\u0627\u0635\u0631 ((C.H.N.S \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a.\u0648\u0627\u0642\u062a\u0631\u062d \u0647\u064a\u0643\u0644 \u0647\u0646\u062f\u0633\u064a \u062b\u0645\u0627\u0646\u064a \u0633\u0637\u0648\u062d \u0644\u0644\u0643\u0646\u062f\u0627\u062a (DPA) \u0648(MPB) \u0645\u0639 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u00a0Mn+ 2<\/sup> \u060c Co + 2<\/sup>\u060c Ni + 2,<\/sup>Cu+ 2<\/sup>\u060c Zn + 2<\/sup>\u060c Cd + 2<\/sup> \u00a0\u0648 Hg + 2<\/sup> \u060c \u0648 \u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0629 \u0645\u0639 \u0627\u064a\u0648\u0646\u00a0(VO) +2<\/sup> \u0627\u0642\u062a\u0631\u0627\u062d \u0647\u064a\u0643\u0644 \u0647\u0646\u062f\u0633\u064a \u0631\u0628\u0627\u0639\u064a \u0627\u0644\u0633\u0637\u0648\u062d \u0645\u0639 \u0627\u0644\u0644\u064a\u0643\u0646\u062f\u0627\u062a (ATA) \u0648 (MTA) \u0645\u0639 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629<\/p>\n

Mn + 2<\/sup> Co + 2<\/sup>\u060c Ni + 2<\/sup>\u060c Zn + 2<\/sup>\u060c Cd + 2<\/sup> \u00a0\u0648 Hg + 2<\/sup>\u0648 \u0628\u064a\u0646\u0645\u0627 \u0645\u0639\u0642\u062f\u0627\u062a \u0627\u064a\u0648\u0646 \u0627\u0644\u0646\u062d\u0627\u0633 \u0641\u0627\u062e\u0630\u062a \u0634\u0643\u0644 \u0627\u0644\u0645\u0631\u0628\u0639 \u0627\u0644\u0645\u0633\u062a\u0648\u064a.\u0648\u0647\u0631\u0645 \u0645\u0631\u0628\u0639 \u0627\u0644\u0642\u0627\u0639\u062f\u0647 \u0645\u0639 \u0627\u064a\u0648\u0646 (VO) +2<\/sup> \u00a0\u0623\u0638\u0647\u0631\u062a \u0627\u0644\u0644\u0643\u0646\u062f\u0627\u062a \u0627\u0644\u0623\u0631\u0628\u0639\u0629 \u0648\u0628\u0639\u0636 \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0646\u0634\u0627\u0637\u0627\u0628\u064a\u0648\u0644\u0648\u062c\u064a\u064b\u0627 \u0645\u062e\u062a\u0644\u0641\u0629 \u0641\u064a \u062a\u062b\u0628\u064a\u0637 \u0646\u0645\u0648\u0647\u0627 \u0636\u062f \u0646\u0648\u0639\u064a\u0646 \u0645\u0646 \u00a0\u0627\u0644\u0628\u0643\u062a\u064a\u0631\u064a\u0627 \u0645\u062e\u062a\u0644\u0641\u0629 \u0644\u0645\u0646\u0639 \u0646\u0645\u0648\u0647 ( Escherichia Coli<\/em> and<\/em> Staphylococcus aureus<\/em>) \u00a0\u0648\u0646\u0648\u0639 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0641\u0637\u0631\u064a\u0627\u062a \u0627\u0644\u0645\u0628\u064a\u0636\u0627\u062a \u0627\u0644\u0628\u064a\u0636\u0627\u0621( Candida albica<\/em>)\u00a0.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u0646\u0627\u0642\u0634 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0641\u064a \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629 (\u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645) \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0627\u0644\u0645\u0648\u0633\u0648\u0645\u0629 ( \u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635 \u0648\u062f\u0631\u0627\u0633\u0629 \u0628\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0631\u0643\u0628\u0627\u062a….<\/i>\u0627\u0644\u0645\u0632\u064a\u062f<\/span><\/a><\/p>\n","protected":false},"author":25,"featured_media":51996,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"no","_lmt_disable":"","footnotes":""},"categories":[7,59,98,79,16],"tags":[23,61,47],"class_list":["post-51990","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-7","category-59","category-98","category-chem-dept","category-16","tag-ihcoedu","tag-61","tag-chem"],"modified_by":"ihcoedu","_links":{"self":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/51990","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=51990"}],"version-history":[{"count":0,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/posts\/51990\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=\/wp\/v2\/media\/51996"}],"wp:attachment":[{"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=51990"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=51990"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ihcoedu.uobaghdad.edu.iq\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=51990"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}