{"id":951,"date":"2016-01-04T02:58:54","date_gmt":"2016-01-03T11:58:54","guid":{"rendered":""},"modified":"2016-01-04T02:58:54","modified_gmt":"2016-01-03T11:58:54","slug":"","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=951","title":{"rendered":"\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0644\u0644\u0637\u0627\u0644\u0628\u0629 \u0648\u0631\u0648\u062f \u0639\u0644\u064a \u062c\u0639\u0641\u0631 \u0627\u0644\u0633\u0627\u0639\u062f\u064a \u0645\u0646 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621"},"content":{"rendered":"
 
\"\"  <\/p>\n

\u062c\u0631\u062a \u0628\u0639\u0648\u0646 \u0627\u0644\u0644\u0647 \u062a\u0639\u0627\u0644\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0644\u0644\u0637\u0627\u0644\u0628\u0629 \u0648\u0631\u0648\u062f \u0639\u0644\u064a \u062c\u0639\u0641\u0631 \u0627\u0644\u0633\u0627\u0639\u062f\u064a \u0645\u0646 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0648\u0630\u0644\u0643 \u0641\u064a \u064a\u0648\u0645 \u0627\u0644\u0627\u062b\u0646\u064a\u0646 \u0627\u0644\u0645\u0648\u0627\u0641\u0642  4 \/1 \/ 2016 \u0648\u0639\u0644\u0649 \u0642\u0627\u0639\u0629 \u0627\u0644\u0645\u0631\u062d\u0648\u0645  \u0623.\u062f. \u0641\u0647\u062f \u0639\u0644\u064a \u0627\u0644\u062c\u0628\u0648\u0631\u064a.<\/span><\/strong><\/p>\n

\u0648\u0643\u0627\u0646 \u0639\u0646\u0648\u0627\u0646 \u0627\u0644\u0623\u0637\u0631\u0648\u062d\u0629 :<\/span><\/strong><\/p>\n

\u062a\u062d\u0636\u064a\u0631 \u0648 \u062a\u0634\u062e\u064a\u0635 \u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0642\u0648\u0627\u0639\u062f \u0634\u0641 \u062c\u062f\u064a\u062f\u0629 \u0648\u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 \u0645\u0639 \u0628\u0639\u0636 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a \u0627\u0644\u0641\u0644\u0632\u064a\u0629 \u0648\u062a\u0642\u062f\u064a\u0631 \u0641\u0639\u0627\u0644\u064a\u062a\u0647\u0627 \u0627\u0644\u0628\u0643\u062a\u064a\u0631\u064a\u0629<\/span><\/strong><\/p>\n

\u0648\u062a\u0623\u0644\u0641\u062a \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0645\u0646 \u0627\u0644\u0623\u0633\u0627\u062a\u0630\u0629 :<\/span><\/strong><\/p>\n

\u0623.\u062f. \u0639\u0628\u062f\u0627\u0644\u0644\u0647 \u0645\u062d\u0645\u062f \u0639\u0644\u064a     \u062c\u0627\u0645\u0639\u0647 \u0627\u0644\u0643\u0648\u0641\u0647      \u0631\u0626\u064a\u0633\u0627<\/span><\/strong><\/p>\n

\u0623.\u0645.\u062f \u0639\u0628\u062f \u0627\u0644\u0633\u0644\u0627\u0645 \u0639\u0628\u062f \u0627\u0644\u0643\u0631\u064a\u0645 \u0639\u0628\u062f \u0627\u0644\u0631\u062d\u0645\u0646   \u062c\u0627\u0645\u0639\u0647 \u062f\u064a\u0627\u0644\u0649 \u0639\u0636\u0648\u0627\u064b<\/span><\/strong><\/p>\n

\u0623.\u0645.\u062f \u0639\u0645\u0627\u062f \u0639\u0628\u062f \u0627\u0644\u062d\u0633\u064a\u0646 \u064a\u0648\u0633\u0641                \u062c\u0627\u0645\u0639\u0647 \u0627\u0644\u0646\u0647\u0631\u064a\u0646 \u0639\u0636\u0648\u0627\u064b<\/span><\/strong><\/p>\n

 \u0623.\u0645.\u062f \u0639\u0628\u0627\u0633 \u0639\u0644\u064a \u0635\u0627\u0644\u062d                            \u062c\u0627\u0645\u0639\u0647 \u0628\u063a\u062f\u0627\u062f \u0639\u0636\u0648\u0627\u064b<\/span><\/strong><\/p>\n

\u0623.\u0645.\u062f \u062c\u0627\u0633\u0645 \u0634\u0647\u0627\u0628 \u0633\u0644\u0637\u0627\u0646                      \u062c\u0627\u0645\u0639\u0647 \u0628\u063a\u062f\u0627\u062f \u0639\u0636\u0648\u0627\u064b<\/span><\/strong><\/p>\n

\u0623.\u062f \u0633\u0627\u062c\u062f \u0645\u062d\u0645\u0648\u062f \u0644\u0637\u064a\u0641                    \u062c\u0627\u0645\u0639\u0647 \u0628\u063a\u062f\u0627\u062f  \u0639\u0636\u0648\u0627 \u0648\u0645\u0634\u0631\u0641\u0627\u064b<\/span><\/strong><\/p>\n

\u0623.\u062f \u0628\u0627\u0633\u0645\u0647 \u0645\u062d\u0633\u0646 \u0633\u0631\u062d\u0627\u0646               \u062c\u0627\u0645\u0639\u0647 \u0628\u063a\u062f\u0627\u062f  \u0639\u0636\u0648\u0627 \u0648\u0645\u0634\u0631\u0641\u0627\u064b<\/p>\n

\"\"
<\/span><\/strong><\/p>\n

\u0627\u0644\u062e\u0644\u0627\u0635\u0629<\/span><\/strong><\/p>\n

      \u062a\u0636\u0645\u0646 \u0627\u0644\u0639\u0645\u0644 \u062a\u062d\u0636\u064a\u0631 \u062b\u0644\u0627\u062b \u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a <\/span><\/strong>(H2L1, H2L2 and H2L3)<\/span><\/strong> \u0645\u0646 \u0646\u0648\u0639 (<\/span><\/strong> <\/span><\/strong>(N2O2<\/span><\/strong> \u0648\u0627\u0644\u062a\u064a \u0627\u0633\u062a\u0639\u0645\u0644\u062a \u0641\u064a\u0645\u0627 \u0628\u0639\u062f \u0644\u062a\u062d\u0636\u064a\u0631 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0648\u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0647\u064a :<\/span><\/strong><\/p>\n

2-(4-(carboxymethyleneamino)-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-ylideneamino)propanoic acid(H2L1), 2-((E)-3-(2-hydroxyphenylimino)-1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-4-ylimino)acetic acid(H2L2) and 2-((E)-4-((Z)-2-hydroxy-1,2-diphenylethylideneamino)-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-ylideneamino)propanoic acid(H2L3).<\/span><\/strong><\/p>\n

\u062a\u0645 \u062a\u062d\u0636\u064a\u0631 \u0647\u0630\u0647 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0645\u0646 \u0645\u0641\u0627\u0639\u0644\u0647 \u0645\u0643\u0627\u0641\u0626 \u0648\u0627\u062d\u062f \u0645\u0646 <\/span><\/strong>2-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-ylimino)acetic acid<\/span><\/strong>(\u0627\u0644\u0645\u0634\u062a\u0642 \u0627\u0644\u0627\u0648\u0644) \u0645\u0639 \u0645\u0643\u0627\u0641\u0626 \u0648\u0627\u062d\u062f \u0645\u0646 \u062d\u0627\u0645\u0636 \u0627\u0644\u0628\u0631\u0648\u0628\u064a\u0648\u0646\u0643 \u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0644\u0627\u0648\u0644 (<\/span><\/strong>H2L1<\/span><\/strong>) \u0648\u0645\u0646 \u0645\u0641\u0627\u0639\u0644\u0647 \u0646\u0641\u0633 \u0627\u0644\u0645\u0634\u062a\u0642 \u0627\u0644\u0627\u0648\u0644 \u0645\u0639 2-\u0627\u0645\u064a\u0646\u0648 \u0641\u064a\u0646\u0648\u0644 \u0644\u062a\u062d\u0636\u064a\u0631 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0644\u062b\u0627\u0646\u064a <\/span><\/strong>(H2L2)<\/span><\/strong>  \u0627\u0645\u0627 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0644\u062b\u0627\u0644\u062b <\/span><\/strong>(H2L3)<\/span><\/strong> \u0641\u0642\u062f \u062a\u0645 \u062a\u062d\u0636\u064a\u0631\u0647 \u0645\u0646 \u0645\u0641\u0627\u0639\u0644\u0647 \u0645\u0643\u0627\u0641\u0626 \u0648\u0627\u062d\u062f \u0645\u0646 <\/span><\/strong>(Z)-4-(2-hydroxy-1,2-diphenylethylideneamino)-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one<\/span><\/strong> \u0645\u0639 \u0645\u0643\u0627\u0641\u0626 \u0648\u0627\u062d\u062f \u0645\u0646 \u0627\u0644\u0628\u0646\u0632\u0648\u064a\u0646<\/span><\/strong>.<\/span><\/strong><\/p>\n

(\u062c\u0645\u064a\u0639 \u0627\u0644\u062a\u0641\u0627\u0639\u0644\u0627\u062a \u0627\u062c\u0631\u064a\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0644\u0627\u064a\u062b\u0627\u0646\u0648\u0644 \u0643\u0645\u0630\u064a\u0628 \u0648 \u0627\u0644\u062a\u0635\u0639\u064a\u062f \u0627\u0644\u0639\u0643\u0633\u064a \u0648\u0644\u0645\u062f\u0629 7 \u0633\u0627\u0639\u0627\u062a \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 \u0627\u0644\u0627\u0648\u0644 \u0648\u0627\u0644\u062b\u0627\u0646\u064a \u0648 5 \u0633\u0627\u0639\u0627\u062a \u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0644\u062b\u0627\u0644\u062b ).<\/span><\/strong><\/p>\n

    \u062a\u0645 \u062a\u0634\u062e\u064a\u0635 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a  \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631 \u0648 \u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 \u0648 \u0637\u064a\u0641 \u0627\u0644\u0631\u0646\u064a\u0646 \u0627\u0644\u0646\u0648\u0648\u064a \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a \u0645\u0639 \u062f\u0631\u062c\u0629 \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631. \u0643\u0645\u0627 \u062a\u0636\u0645\u0646 \u0627\u0644\u0628\u062d\u062b \u062a\u062d\u0636\u064a\u0631 \u0633\u0644\u0633\u0644\u0629 \u0645\u0646 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0648 \u0630\u0644\u0643 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0645\u0641\u0627\u0639\u0644\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0645\u0639 \u0623\u0645\u0644\u0627\u062d \u0627\u0644\u0639\u0646\u0627\u0635\u0631 \u0627\u0644\u062a\u0627\u0644\u064a\u0629 :<\/span><\/strong><\/p>\n

\u0627\u0644\u0641\u0646\u0627\u062f\u064a\u0644 <\/span><\/strong>II<\/span><\/strong> \u0648 \u0627\u0644\u0645\u0646\u063a\u0646\u064a\u0632 <\/span><\/strong>II<\/span><\/strong> \u0648 \u0627\u0644\u0643\u0648\u0628\u0644\u062a <\/span><\/strong>II<\/span><\/strong> \u0648 \u0627\u0644\u0646\u064a\u0643\u0644 <\/span><\/strong>II<\/span><\/strong> \u0648 \u0627\u0644\u0646\u062d\u0627\u0633 <\/span><\/strong>II<\/span><\/strong> \u0648 \u0627\u0644\u0632\u0646\u0643 <\/span><\/strong>II<\/span><\/strong> \u0648 \u0627\u0644\u0643\u0627\u062f\u0645\u064a\u0648\u0645 <\/span><\/strong>II<\/span><\/strong> \u0645\u0639 \u0627\u0644\u0632\u0626\u0628\u0642 <\/span><\/strong>II<\/span><\/strong>. \u0648 \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0644\u0627\u064a\u062b\u0627\u0646\u0648\u0644 \u0643\u0648\u0633\u0637 \u062a\u0641\u0627\u0639\u0644 \u0648 \u0627\u0644\u062a\u0635\u0639\u064a\u062f \u0627\u0644\u0639\u0643\u0633\u064a.  \u0634\u062e\u0635\u062a \u0647\u0630\u0647 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645 \u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631 \u0648 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a (<\/span><\/strong>A.A<\/span><\/strong>) \u0648 \u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621 \u0648 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629 – \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648 \u0642\u064a\u0627\u0633\u0627\u062a \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u0629 \u0627\u0644\u0643\u0647\u0631\u0628\u0627\u0626\u064a\u0629 \u0648 \u0645\u062d\u062a\u0648\u0649 \u0627\u0644\u0643\u0644\u0648\u0631 \u0645\u0639 \u062f\u0631\u062c\u0629 \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631 .<\/span><\/strong><\/p>\n

\u062d\u064a\u062b \u0627\u0642\u062a\u0631\u062d\u062a \u0627\u0644\u0635\u064a\u063a \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a\u0629 \u0627\u0644\u0639\u0627\u0645\u0629 \u0627\u0644\u062a\u0627\u0644\u064a\u0629 : <\/span><\/strong>[M(L)2(X)(Y)]n<\/span><\/strong> \u062d\u064a\u062b:<\/span><\/strong><\/p>\n

L=H2L1<\/span><\/strong><\/p>\n

M=VO<\/span><\/strong>)<\/span><\/strong>II), X=0, Y=OSO3-2, n=0<\/span><\/strong><\/p>\n

M=Mn(II), X=H2O, Y=H2O, n=+2<\/span><\/strong><\/p>\n

M= Co(II),Ni(II),Cu(II),Zn(II),Hg(II), X=H2O, Y=Cl, n=+1<\/span><\/strong><\/p>\n

M=Cd(II), X=Cl, Y=Cl, n=0<\/span><\/strong><\/p>\n

 <\/span><\/strong><\/p>\n

L=H2L2<\/span><\/strong><\/p>\n

M= VO(II), X=0, Y=OSO3-2, n=0<\/span><\/strong><\/p>\n

M=Ni(II),Cu(II), X= H2O, Y=Cl, n=+1<\/span><\/strong><\/p>\n

M= Mn(II),Co(II),Zn(II),Cd(II),Hg(II), X=Cl, Y=Cl, n=0<\/span><\/strong><\/p>\n

L=H2L3<\/span><\/strong><\/p>\n

M=VO(II), X=0, Y=OSO3-2, n=0<\/span><\/strong><\/p>\n

M=Co(II),Cd(II), X=H2O, Y=Cl, n=+1<\/span><\/strong><\/p>\n

M=Mn(II),Ni(II),Cu(II),Zn(II), X=H2O, Y=H2O, n=+2<\/span><\/strong><\/p>\n

M=Hg(II), X=Cl, Y= Cl  , n= 0<\/span><\/strong><\/p>\n

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