{"id":963,"date":"2016-01-09T12:09:31","date_gmt":"2016-01-09T09:09:31","guid":{"rendered":""},"modified":"2016-01-09T12:09:31","modified_gmt":"2016-01-09T09:09:31","slug":"","status":"publish","type":"post","link":"https:\/\/ihcoedu.uobaghdad.edu.iq\/?p=963","title":{"rendered":"\u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0644\u0644\u0637\u0627\u0644\u0628\u0629 \u0644\u0642\u0627\u0621 \u062e\u0627\u0644\u062f \u0639\u0628\u062f\u0627\u0644\u0643\u0631\u064a\u0645 \u0645\u0646 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621"},"content":{"rendered":"
 
 \"\" <\/p>\n

\u062c\u0631\u062a \u0628\u0639\u0648\u0646 \u0627\u0644\u0644\u0647 \u062a\u0639\u0627\u0644\u0649 \u0645\u0646\u0627\u0642\u0634\u0629 \u0627\u0637\u0631\u0648\u062d\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0627\u0647 \u0644\u0644\u0637\u0627\u0644\u0628\u0629 \u0644\u0642\u0627\u0621 \u062e\u0627\u0644\u062f \u0639\u0628\u062f\u0627\u0644\u0643\u0631\u064a\u0645 \u0645\u0646 \u0642\u0633\u0645 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0621 \u0648\u0630\u0644\u0643 \u0641\u064a \u064a\u0648\u0645 \u0627\u0644\u062e\u0645\u064a\u0633 \u0627\u0644\u0645\u0648\u0627\u0641\u0642  7 \/1 \/ 2016 \u0648\u0639\u0644\u0649 \u0642\u0627\u0639\u0629 \u0627\u0644\u0645\u0631\u062d\u0648\u0645  \u0623.\u062f. \u0641\u0647\u062f \u0639\u0644\u064a \u0627\u0644\u062c\u0628\u0648\u0631\u064a.<\/span><\/strong><\/p>\n

\u0648\u0643\u0627\u0646 \u0639\u0646\u0648\u0627\u0646 \u0627\u0644\u0623\u0637\u0631\u0648\u062d\u0629 :<\/span><\/strong><\/p>\n

\u062a\u062d\u0636\u064a\u0631\u060c\u062a\u0634\u062e\u064a\u0635 \u0648 \u062a\u0642\u062f\u064a\u0631 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629  \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0644\u0642\u0648\u0627\u0639\u062f \u0634\u0641 \u0648\u0645\u0639\u0642\u062f\u0627\u062a \u0641\u0644\u0632\u064a\u0629 \u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f \u0644\u0628\u0639\u0636 \u0627\u0644\u0645\u0648\u0627\u062f \u0627\u0644\u062f\u0648\u0627\u0626\u064a\u0629<\/p>\n

\"\"
<\/span><\/strong><\/p>\n

\u0648\u0642\u062f \u062a\u0627\u0644\u0641\u062a \u0644\u062c\u0646\u0629 \u0627\u0644\u0645\u0646\u0627\u0642\u0634\u0629 \u0645\u0646 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a\u064a\u0646 \u0627\u0644\u0627\u0641\u0627\u0636\u0644:<\/span><\/strong><\/p>\n

\u0623. \u062f. \u0633\u0627\u062c\u062f \u0645\u062d\u0645\u0648\u062f \u0644\u0637\u064a\u0641    \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629- \u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645    \u0631\u0626\u064a\u0633\u0627\u064b<\/span><\/strong><\/p>\n

\u0627.\u0645. \u062f. \u062d\u064a\u062f\u0631 \u062d\u0645\u064a\u062f \u0645\u062d\u0633\u0646    \u062c\u0627\u0645\u0639\u0629 \u0643\u0631\u0628\u0644\u0627\u0621\/ \u0643\u0644\u064a\u0629 \u0627\u0644\u0639\u0644\u0648\u0645     \u0639\u0636\u0648\u0627\u064b<\/span><\/strong><\/p>\n

\u0623. \u062f. \u0641\u0627\u0636\u0644 \u0645\u062d\u0633\u0646 \u0639\u0628\u062f   \u0648\u0632\u0627\u0631\u0629 \u0627\u0644\u0639\u0644\u0648\u0645 \u0648\u0627\u0644\u062a\u0643\u0646\u0644\u0648\u062c\u064a\u0627    \u0639\u0636\u0648\u0627\u064b<\/span><\/strong><\/p>\n

\u0623.\u0645 .\u062f .\u0639\u0627\u0645\u0631 \u062c\u0628\u0627\u0631 \u062c\u0631\u0627\u062f   \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629- \u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645    \u0639\u0636\u0648\u0627\u064b<\/span><\/strong><\/p>\n

\u0627.\u0645. \u062f.  \u0641\u064a\u062d\u0627\u0621 \u0645\u0642\u062f\u0627\u062f \u062e\u0644\u064a\u0644  \u062c\u0627\u0645\u0639\u0629 \u0628\u063a\u062f\u0627\u062f \/\u0643\u0644\u064a\u0629 \u0627\u0644\u0639\u0644\u0648\u0645 \u0644\u0644\u0628\u0646\u0627\u062a     \u0639\u0636\u0648\u0627\u064b<\/span><\/strong><\/p>\n

\u0627. \u062f. \u062a\u063a\u0631\u064a\u062f \u0647\u0627\u0634\u0645 \u0627\u0644\u0646\u0648\u0631  \u0643\u0644\u064a\u0629 \u0627\u0644\u062a\u0631\u0628\u064a\u0629 \u0644\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0635\u0631\u0641\u0629- \u0627\u0628\u0646 \u0627\u0644\u0647\u064a\u062b\u0645     \u0639\u0636\u0648\u0627\u064b \u0645\u0634\u0631\u0641\u0627\u064b<\/span><\/strong><\/p>\n

 \"\"<\/span><\/strong><\/p>\n


      \u062a\u0646\u0627\u0648\u0644<\/span><\/strong> <\/span><\/strong>\u0627\u0644\u0639\u0645\u0644 \u0627\u0644\u0645\u0642\u062f\u0645 \u0628\u0647\u0630\u0647 \u0627\u0644\u0627\u0637\u0631\u0648\u062d\u0629 \u062a\u062d\u0636\u064a\u0631 \u0648\u062a\u0634\u062e\u064a\u0635:<\/span><\/strong><\/p>\n

(A<\/span><\/strong> \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u0646 \u0642\u0627\u0639\u062f\u062a\u0627 \u0634\u0641 <\/span><\/strong>(HL1<\/sub>-HL<\/span><\/strong>2<\/span><\/sub><\/strong>)<\/span><\/strong> \u0645\u0634\u062a\u0642\u0629 \u0645\u0646 \u0645\u0636\u0627\u062f\u0627\u062a \u062d\u064a\u0648\u064a\u0629 \u0645\u062e\u062a\u0627\u0631\u0629 <\/span><\/strong>β-lactam<\/span><\/strong> <\/span><\/strong>Amoxcilline <\/span><\/strong>trihydrate<\/span><\/strong>]<\/span><\/strong>  <\/span><\/strong>(AmoxH)<\/span><\/strong> \u0648 <\/span><\/strong>Ampicillin <\/span><\/strong>trihydrate<\/span><\/strong> <\/span><\/strong>[ <\/span><\/strong>(AmpiH)<\/span><\/strong> \u0645\u0639  <\/span><\/strong><\/p>\n

                                   <\/span><\/strong>4-<\/span><\/strong>chlorobenz<\/span><\/strong>ophenone<\/span><\/strong>.<\/span><\/strong><\/p>\n

 <\/span><\/strong><\/p>\n

B<\/span><\/strong>) \u0644\u064a\u0643\u0627\u0646\u062f \u0642\u0627\u0639\u062f\u0629 \u0634\u0641 <\/span><\/strong>HL3<\/span><\/strong> \u0645\u0634\u062a\u0642 \u0645\u0646 \u062f\u0648\u0627\u0621 <\/span><\/strong>Methyl dopa<\/span><\/strong> <\/span><\/strong>  <\/span><\/strong>(M-dopa)<\/span><\/strong> \u0645\u0639  <\/span><\/strong>4-(dimethylaminobezaldehyde<\/span><\/strong>)<\/span><\/strong><\/p>\n

  \u0648\u0627\u0644\u064a\u0643\u0646\u062f\u0627\u062a \u0645\u062a\u0636\u0645\u0646\u0647 (<\/span><\/strong>N,O,O<\/span><\/strong>) \u0643\u0630\u0631\u0627\u062a \u0648\u0627\u0647\u0628\u0629 \u0645\u0646 \u0646\u0648\u0639 <\/span><\/strong>(O N O) <\/span><\/strong>  \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646<\/span><\/strong>(<\/span><\/strong>HL1<\/sub><\/span><\/strong> \u0648<\/span><\/strong>(HL2<\/sub><\/span><\/strong> \u0648<\/span><\/strong>(N,O)<\/span><\/strong> \u0644\u0644\u064a\u0643\u0627\u0646\u062f<\/span><\/strong>. <\/span><\/strong>HL3<\/sub><\/span><\/strong> <\/span><\/strong><\/p>\n

 <\/span><\/strong><\/p>\n

       <\/span><\/strong>\u062a\u0645 \u062a\u0634\u062e\u064a\u0635 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a<\/span><\/strong> <\/span><\/strong>(HL1<\/sub>-HL3<\/sub>)<\/span><\/strong> <\/span><\/strong> \u0628\u0627\u0633\u062a<\/span><\/strong>\u0639\u0645\u0627\u0644<\/span><\/strong> \u0637\u064a\u0641 <\/span><\/strong> (<\/span><\/strong> ( 1<\/sup>H-NMR<\/span><\/strong>\u0648(<\/span><\/strong>13<\/span><\/sup><\/strong>C-NMR<\/span><\/strong>)<\/span><\/strong> <\/span><\/strong>\u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621<\/span><\/strong> FT-IR <\/span><\/strong> <\/span><\/strong> \u0648\u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629<\/span><\/strong> U.V–Vis <\/span><\/strong> <\/span><\/strong>\u060c<\/span><\/strong>\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062f\u0642\u064a\u0642 \u0644\u0644\u0639\u0646\u0627\u0635\u0631<\/span><\/strong> (C.H.N.S)<\/span><\/strong> \u060c \u062f\u0631\u062c\u0629 \u0627\u0644\u0627\u0646\u0635\u0647\u0627\u0631 \u0648\u0627\u0644\u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u062d\u0631\u0627\u0631\u064a \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u064a\u0646 <\/span><\/strong> HL1<\/sub>) <\/span><\/strong>\u0648 <\/span><\/strong>( HL2<\/sub><\/span><\/strong> \u0648\u0643\u0645\u0627 \u062a\u0645 \u0631\u0633\u0645 \u0623\u0634\u0643\u0627\u0644 \u0627\u0644\u0645\u0642\u062a\u0631\u062d\u0629 \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a <\/span><\/strong>\u0628\u0627\u0633\u062a\u062e\u062f\u0627\u0645<\/span><\/strong> \u0627\u0644\u0628\u0631\u0646\u0627\u0645\u062c \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a \u0627\u0644\u062c\u0627\u0647\u0632 \u0643\u064a\u0645 \u0627\u0648\u0641\u064a\u0633 <\/span><\/strong><\/p>\n

Cs Chem 3D Ultra program package (2006)<\/span><\/strong><\/p>\n

     \u062a\u062d\u0636\u064a\u0631 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062e\u062a\u0644\u0637\u0629 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f<\/span><\/strong> <\/span><\/strong>:<\/span><\/strong><\/p>\n

1)\u0627\u0633\u062a<\/span><\/strong>\u0639\u0645\u0627\u0644<\/span><\/strong> \u0642\u0648\u0627\u0639\u062f \u0634\u0641 <\/span><\/strong>(HL1<\/sub>-HL2<\/sub>)<\/span><\/strong> \u0643\u0644\u064a\u0643\u0627\u0646\u062f<\/span><\/strong>\u0627\u062a <\/span><\/strong> \u0627\u0648\u0644\u064a\u0629 \u0645\u0639  <\/span><\/strong>Nicotinamide<\/span><\/strong> (NAm)<\/span><\/strong> <\/span><\/strong> <\/span><\/strong> \u0643\u0644\u064a\u0643\u0627\u0646\u062f \u062b\u0627\u0646\u0648\u064a \u0645\u0639 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a<\/span><\/strong> <\/span><\/strong>M(II)<\/span><\/strong> \u0648<\/span><\/strong>M(III)<\/span><\/strong> . <\/span><\/strong><\/p>\n

2) \u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0642\u0627\u0639\u062f\u0629 \u0634\u0641 <\/span><\/strong>HL3<\/sub><\/span><\/strong>  <\/span><\/sub><\/strong>\u0643\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0648\u0644\u064a \u0645\u0639 <\/span><\/strong>Anthranilic acid<\/span><\/strong> <\/span><\/strong>(AnthH) <\/span><\/strong> \u0643\u0644\u064a\u0643\u0627\u0646\u062f \u062b\u0627\u0646\u0648\u064a \u0645\u0639 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a <\/span><\/strong>M(II)<\/span><\/strong> \u0648<\/span><\/strong>M(III)<\/span><\/strong>.<\/span><\/strong><\/p>\n

3) \u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0645\u0636\u0627\u062f \u0627\u0644\u062d\u064a\u0648\u064a  <\/span><\/strong>Trimethoprim<\/span><\/strong> \u0643\u0644\u064a\u0643\u0627\u0646\u062f \u0627\u0648\u0644\u064a \u0645\u0639 <\/span><\/strong>Anthranilic acid<\/span><\/strong> <\/span><\/strong>AnthH)<\/span><\/strong>)<\/span><\/strong>,<\/span><\/strong> <\/span><\/strong>(ProH) L-Proline<\/span><\/strong> \u0648 <\/span><\/strong>L-Alanine<\/span><\/strong> <\/span><\/strong>(AlanH) <\/span><\/strong> <\/span><\/strong>,<\/span><\/strong> \u0643\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u062b\u0627\u0646\u0648\u064a\u0629 \u0645\u0639 \u0627\u0644\u0627\u064a\u0648\u0646\u0627\u062a <\/span><\/strong>M(II)<\/span><\/strong>.<\/span><\/strong><\/p>\n

\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0628\u0644\u0648\u0631\u0627\u062a \u0635\u0644\u0628\u0629 \u062f\u0631\u0633\u062a \u0645\u0646 \u0627\u0644\u0646\u0648\u0627\u062d\u064a \u0627\u0644\u0622\u062a\u064a\u0629: \u0627\u0644\u062a\u0648\u0635\u064a\u0644\u064a\u0629 \u0627\u0644\u0645\u0648\u0644\u0627\u0631\u064a\u0629\u060c \u0627\u0644\u062f\u0631\u0627\u0633\u0627\u062a \u0627\u0644\u0637\u064a\u0641\u064a\u0629 (\u0627\u0644\u0623\u0634\u0639\u0629 \u062a\u062d\u062a \u0627\u0644\u062d\u0645\u0631\u0627\u0621\u060c \u0627\u0644\u0623\u0634\u0639\u0629 \u0641\u0648\u0642 \u0627\u0644\u0628\u0646\u0641\u0633\u062c\u064a\u0629– \u0627\u0644\u0645\u0631\u0626\u064a\u0629 \u0648 \u0645\u0637\u064a\u0627\u0641\u064a\u0629 \u0627\u0644\u0627\u0645\u062a\u0635\u0627\u0635 \u0627\u0644\u0630\u0631\u064a) \u0641\u0636\u0644\u0627 \u0639\u0646 \u0642\u064a\u0627\u0633 \u0627\u0644\u062d\u0633\u0627\u0633\u064a\u0629 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0645\u0639 \u0627\u0633\u062a\u0639\u0645\u0627\u0644 \u0627\u0644\u0628\u0631\u0646\u0627\u0645\u062c <\/span><\/strong> \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a                                           <\/span><\/strong> <\/span><\/strong><\/p>\n

 <\/span><\/strong>(Chem Office– Cs. chem– 3D pro 2006)<\/span><\/strong> \u0641\u064a \u0631\u0633\u0645 \u0627\u0634\u0643\u0627\u0644 \u0627\u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a \u0648\u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a.<\/span><\/strong><\/p>\n

 \u0642\u064a\u0645 \u0627\u0644\u0639\u0632\u0648\u0645 \u0627\u0644\u0645\u063a\u0646\u0627\u0637\u064a\u0633\u064a\u0629 \u0648\u0627\u0644\u0623\u0637\u064a\u0627\u0641 \u0627\u0644\u0627\u0644\u0643\u062a\u0631\u0648\u0646\u064a\u0629 \u0644\u062c\u0645\u064a\u0639 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u062f\u0644\u062a \u0639\u0644\u0649 \u0623\u0646 \u062c\u0645\u064a\u0639 \u0627\u0644\u0645\u0639\u0642\u062f\u0627\u062a \u0644\u0647\u0627 \u0628\u0646\u064a\u0629 \u062b\u0645\u0627\u0646\u064a \u0627\u0644\u0633\u0637\u0648\u062d.<\/span><\/strong>\u0643\u0645\u0627 \u062a\u0645 \u0623\u062e\u062a\u0628\u0627\u0631 \u0627\u0644\u0641\u0639\u0627\u0644\u064a\u0629 \u0627\u0644\u0628\u0627\u064a\u0648\u0644\u0648\u062c\u064a\u0629 \u0627\u0644\u0645\u0636\u0627\u062f\u0629 \u0644\u0644\u0628\u0643\u062a\u0631\u064a\u0627  \u0644\u0644\u064a\u0643\u0627\u0646\u062f\u0627\u062a  \u0627\u0644\u062d\u0631\u0629 \u0645\u0639  \u0645\u0639\u0642\u062f\u0627\u062a\u0647\u0627 <\/span><\/strong>\u0627\u0644\u0645\u062d\u0636\u0631\u0629 \u0628\u062a\u0642\u0646\u064a\u0629 \u0642\u064a\u0627\u0633 \u0645\u0646\u0637\u0642\u0629 \u0627\u0644\u062a\u062b\u0628\u064a\u0637 <\/span><\/strong>(ZI)<\/span><\/strong> <\/span><\/strong>. <\/span><\/strong><\/p>\n

 <\/span><\/strong><\/p>\n

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 <\/p>\n<\/p><\/div>\n","protected":false},"excerpt":{"rendered":"

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